Performance of barium titanate@ carbon nanotube nanocomposite as an electromagnetic wave absorber

Barium titanate (BT) nanoparticles were fabricated using sol–gel method, and then immobilized onto the surface of carbon nanotubes (CNTs) to fabricate heterogeneous barium titanate@carbon nanotube (BT@CNT) nanocomposites. The electromagnetic (EM) wave absorption ability increased as the weight fraction of BT@CNT increased. The BT@CNT 30 wt.% nanocomposites with thickness of 1.1 mm showed a minimum reflection loss (R.L.) of ∼ − 37.2 dB (> 99.98% absorption) at 13.9 GHz with a response bandwidth of 1.6 GHz (12.3 ∼ 13.9 GHz), and were the best absorber when compared to similar nanocomposites with different thicknesses. The relationship between conductivity and EM wave absorption properties was also discussed. Appropriate conductivity also plays an important role to obtain optimum absorption performance. BT@CNT nanocomposites exhibited significant absorption ability, and this indicates that they can be utilized as an effective EM wave absorber material

Pressure-Controlled Motion of Single Polymers through Solid-State Nanopores

Voltage-biased solid-state nanopores are well established in their ability to detect and characterize single polymers, such as DNA, in electrolytes. The addition of a pressure gradient across the nanopore yields a second molecular driving force that provides new freedom for studying molecules in nanopores. In this work, we show that opposing pressure and voltage bias enables nanopores to detect and resolve very short DNA molecules, as well as to detect near-neutral polymers.Engineering and Applied SciencesPhysic

The short-lived inhibitory effect of Brachiaria humidicola on nitrous oxide emissions following sheep urine application in a highly nitrifying soil

Background: Brachiaria humidicola (Bh) has the ability to produce biological nitrification inhibitors (NIs) and release NIs from the root to the soil. Aims: To compare the effects of growing Bh with Brachiaria ruziziensis (Br, which is not able to produceNIs) on soil nitrogen (N) dynamics,Ngases and carbon dioxide (CO2) emissions and nitrifiers and denitrifiers following sheep urine application, a laboratory incubation was conducted in a He/O2 continuous flow denitrification system (DENIS). This incubation was conducted in the absence of light. Hence themeasured effects of Bh and Br on N cycling were the residual effect of biological NIs released into the soil prior to the incubation and released via root death. Methods: The treatmentswere: (1) Bhwith water application (Bh+W); (2) Bh with sheep urine (Bh + U); (3) Br with water application (Br + W); (4) Br with sheep urine (Br + U). Results: Results showed that soil NO3– concentration increased significantly in the soil with sheep urine application after the incubation. Soil nitrous oxide (N2O) and nitric oxide (NO) emissions increased immediately after the sheep urine application and peaked twice during the incubation. Cumulative emissions for the first peak were significantly lower from the Bh + U treatment (0.054 kg N ha–1) compared with the Br + U treatment (0.111 kg N ha–1), but no significant differences were observed in the total cumulative N2O and NO emissions between the Bh + U and Br + U treatment at the end of the incubation. Sheep urine addition did not affect the AOA, nirS and nosZ gene copies, but significantly increased the AOB gene copies after the incubation. Conclusions: We conclude that the residual effect of Bh to mitigate N2O emissions in a highly nitrifying soil is short-lived

Ag/CNT nanocomposites and their single-and double-layer electromagnetic wave absorption properties

The electromagnetic wave absorption properties of single- and double-layer silver nanoparticle/carbon nanotube (Ag/CNT) nanocomposites were evaluated. The reflection loss (R.L.) of the samples was calculated based on the measured complex permittivity and permeability. The double-layer composites constructed from CNT 30 wt.% and Ag/CNT 30 wt.% with total thickness of 3.3 mm showed a minimum R.L. of ~-52.9 dB (over 99.999% absorption) at 6.3 GHz. The bandwidth of reflection loss less than -10 dB was observed at 3 regions, with wideness of 3.5, 0.8, and 1.5 GHz. Thin absorber with large R.L. and wide response bandwidth at low and high frequency regions can be obtained with double-layer composites. The capability to modulate the absorption and bandwidth of these samples to suit various applications in different frequency bands indicates that these nanocomposites could be an excellent electromagnetic wave absorber

Constructing Synergistic Triazine and Acetylene Cores in Fully Conjugated Covalent Organic Frameworks for Cascade Photocatalytic H2O2 Production

Covalent organic frameworks (COFs) are an ideal template for photocatalytic H2O2 synthesis because of the tunable chemical structures and semiconductor properties. However, the photoactivity for COFs is still under-improved due to the inefficient intrinsic charge generation, fast recombination of photogenerated charges, and limited electron transport along the frameworks. Herein, spatially separated and synergistic triazine and acetylene units are first integrated into COFs (EBA-COF and BTEA-COF) for photocatalytic H2O2 production. The spatial separation of triazine and acetylene cores leads to efficient charge separation and suppressed charge recombination, and C═C linkage facilitates electrons transport over the skeletons. Both experimental and computational results suggested that triazine and acetylene units synergistically promote H2O2 synthesis in a two-electron pathway. The EBA-COF showed an attractive activity with a H2O2 production rate of 1830 μmol h-1 gcat-1, superior to that of most other COF-based catalysts. This study provides a method for designing photocatalysts with synergistic photocatalytic active sites based on vinylene-linked COFs

The gut microbiome in atherosclerotic cardiovascular disease

The gut microbiota may play a role in cardiovascular diseases. Here, the authors perform a metagenome-wide association study on stools from individuals with atherosclerotic cardiovascular disease and healthy controls, identifying microbial strains and functions associated with the disease

Robust estimation of bacterial cell count from optical density

Optical density (OD) is widely used to estimate the density of cells in liquid culture, but cannot be compared between instruments without a standardized calibration protocol and is challenging to relate to actual cell count. We address this with an interlaboratory study comparing three simple, low-cost, and highly accessible OD calibration protocols across 244 laboratories, applied to eight strains of constitutive GFP-expressing E. coli. Based on our results, we recommend calibrating OD to estimated cell count using serial dilution of silica microspheres, which produces highly precise calibration (95.5% of residuals <1.2-fold), is easily assessed for quality control, also assesses instrument effective linear range, and can be combined with fluorescence calibration to obtain units of Molecules of Equivalent Fluorescein (MEFL) per cell, allowing direct comparison and data fusion with flow cytometry measurements: in our study, fluorescence per cell measurements showed only a 1.07-fold mean difference between plate reader and flow cytometry data

Dynamically self-organized service composition in wireless ad hoc networks

Service composition is a powerful tool to create new services rapidly by reusing existing ones. Previous research mainly focuses on the wired infrastructure-based environment. With the developments in mobile devices and wireless communication technology in recent years, mobile ad hoc network has received an increasing attention as a new communication paradigm. However, the existing service composition techniques do not work any longer in an ad hoc environment. In this paper, we present the service composition problem in wireless ad hoc network with full consideration of the characteristics of an ad hoc environment. To solve this problem, we develop two service composition routing algorithms, Simple Broadcasting Service Composition and Behavior Evolution Service Composition. The main contribution of our algorithms is that the whole process of service composition is done by the cooperation of nodes on-the-fly instead of a centralized broker to meet the peculiarity of ad hoc networks. Finally, we describe an initial implementation architecture for service composition in wireless ad hoc networks