Fe-Ti-O based catalyst for large-chiral-angle single-walled carbon nanotube growth

International audienceCatalyst selection is very crucial for controlled growth of single-walled carbon nanotubes (SWNTs). Here we introduce a well-designed Fesingle bondTisingle bondO solid solution for SWNT growth with a high preference to large chiral angles. The Fesingle bondTisingle bondO catalyst was prepared by combining Ti layer deposition onto premade Fe nanoparticles with subsequent high-temperature air calcination, which favours the formation of a homogeneous Fesingle bondTisingle bondO solid solution. Using CO as the carbon feedstock, chemical vapour deposition growth of SWNTs at 800 °C was demonstrated on the Fesingle bondTisingle bondO catalyst. Nanobeam electron diffraction characterization on a number of individual SWNTs revealed that more than 94% of SWNTs have chiral angles larger than 15°. In situ environmental transmission electron microscopy study was carried out to reveal the catalyst dynamics upon reduction. Our results identify that the phase segregation through reducing Fesingle bondTisingle bondO catalyst leads to the formation of TiOx-supported small Fe nanoparticles for SWNT growth. The strong metal-support interactions induced by partial reduction of TiOx support promote the wettability of Fe nanoparticle, accounting for the preferential growth of large-chiral-angle SWNTs. This work opens a new avenue for chiral angle selective growth of SWNTs

Photon-pair generation with a 100 nm thick carbon nanotube film

Nonlinear optics based on bulk materials is the current technique of choice for quantum-state generation and information processing. Scaling of nonlinear optical quantum devices is of significant interest to enable quantum devices with high performance. However, it is challenging to scale the nonlinear optical devices down to the nanoscale dimension due to relatively small nonlinear optical response of traditional bulk materials. Here, correlated photon pairs are generated in the nanometer scale using a nonlinear optical device for the first time. The approach uses spontaneous four-wave mixing in a carbon nanotube film with extremely large Kerr-nonlinearity (≈100 000 times larger than that of the widely used silica), which is achieved through careful control of the tube diameter during the carbon nanotube growth. Photon pairs with a coincidence to accidental ratio of 18 at the telecom wavelength of 1.5 μm are generated at room temperature in a ≈100 nm thick carbon nanotube film device, i.e., 1000 times thinner than the smallest existing devices. These results are promising for future integrated nonlinear quantum devices (e.g., quantum emission and processing devices)

Broadband laser polarization control with aligned carbon nanotubes

We introduce a simple approach to fabricate aligned carbon nanotube (ACNT) device for broadband polarization control in fiber laser systems. The ACNT device was fabricated by pulling from as-fabricated vertically-aligned carbon nanotube arrays. Their anisotropic property is confirmed with optical and scanning electron microscopy, and with polarized Raman and absorption spectroscopy. The device was then integrated into fiber laser systems (at two technologically important wavelengths of 1 and 1.5 um) for polarization control. We obtained a linearly-polarized light output with the maximum extinction ratio of ~12 dB. The output polarization direction could be fully controlled by the ACNT alignment direction in both lasers. To the best of our knowledge, this is the first time that ACNT device is applied to polarization control in laser systems. Our results exhibit that the ACNT device is a simple, low-cost, and broadband polarizer to control laser polarization dynamics, for various photonic applications (such as material processing, polarization diversity detection in communications), where the linear polarization control is necessary.Comment: 5 pages, 6 figure

The Stability Criterion and Stability Analysis of Three-Phase Grid-Connected Rectifier System Based on Gerschgorin Circle Theorem

With the increasing maturity of new energy technologies, distributed power systems have been widely used in the field of new energy power generation. The grid-connected rectifier is an important device in the distributed power system. When the grid-connected rectifier operates in a weak power grid environment, its operating performance deviates from the design value, endangering the operation safety of the power system. In this paper, the small-signal impedance model of the three-phase LCL grid-connected rectifier in the DQ coordinate system is established. This model considers the influence of the phase-locked loop on the rectifier impedance characteristics and improves the accuracy of the model, and on this basis, the theoretical stability of the system is analyzed. The stability judgment of the system has important engineering guidance significance. The traditional generalized Nyquist stability criterion requires a lot of calculations and is difficult to use. Therefore, a system stability criterion based on the Gerschgorin circle theorem is proposed, which reduces the amount of calculation and provides a higher size for the system design. The simulation results are consistent with the theoretical analysis, which verifies the correctness of the method proposed in this paper

Quantitatively Computing the Influence of Vegetation Changes on Surface Discharge in the Middle-Upper Reaches of the Huaihe River, China

Changes in meteorology, hydrology, and vegetation will have significant impacts on the ecological environment of a basin, and the middle-upper reach of Huaihe River (MUHR) is one of the key regions for vegetation restoration in China. However, less studies have quantitatively accounted for the contribution of vegetation changes to land surface discharge in the MUHR. To quantitatively evaluate the influence of vegetation changes on land surface discharge in the MUHR, the Bernaola–Galavan (B–G) segmentation algorithm was utilized to recognize the mutation year of the Normalized Difference Vegetation Index (NDVI) time sequence data. Next, the functional relationship between the underlying surface parameter and the NDVI was quantitatively analyzed, and an adjusted Budyko formula was constructed. Finally, the effects of vegetation changes, climate factors, and mankind activities on the surface discharge in the MUHR were computed using the adjusted Budyko formula and elastic coefficient method. The results showed the following: (1) the surface runoff and precipitation from 1982 to 2015 in the MUHR presented a falling trend, yet the NDVI and potential evaporation presented an upward trend; (2) 2004 was the mutation year of the NDVI time series data, and the underlying surface parameter showed a significant linear regression relationship with the NDVI (p < 0.05); (3) the vegetation variation played a major role in the runoff variation during the changing period (2005–2015) in the MUHR. Precipitation, potential evaporation, and human activities accounted for −0.32%, −15.11%, and 18.24% of the surface runoff variation, respectively

Quantitatively Computing the Influence of Vegetation Changes on Surface Discharge in the Middle-Upper Reaches of the Huaihe River, China

Changes in meteorology, hydrology, and vegetation will have significant impacts on the ecological environment of a basin, and the middle-upper reach of Huaihe River (MUHR) is one of the key regions for vegetation restoration in China. However, less studies have quantitatively accounted for the contribution of vegetation changes to land surface discharge in the MUHR. To quantitatively evaluate the influence of vegetation changes on land surface discharge in the MUHR, the Bernaola&ndash;Galavan (B&ndash;G) segmentation algorithm was utilized to recognize the mutation year of the Normalized Difference Vegetation Index (NDVI) time sequence data. Next, the functional relationship between the underlying surface parameter and the NDVI was quantitatively analyzed, and an adjusted Budyko formula was constructed. Finally, the effects of vegetation changes, climate factors, and mankind activities on the surface discharge in the MUHR were computed using the adjusted Budyko formula and elastic coefficient method. The results showed the following: (1) the surface runoff and precipitation from 1982 to 2015 in the MUHR presented a falling trend, yet the NDVI and potential evaporation presented an upward trend; (2) 2004 was the mutation year of the NDVI time series data, and the underlying surface parameter showed a significant linear regression relationship with the NDVI (p &lt; 0.05); (3) the vegetation variation played a major role in the runoff variation during the changing period (2005&ndash;2015) in the MUHR. Precipitation, potential evaporation, and human activities accounted for &minus;0.32%, &minus;15.11%, and 18.24% of the surface runoff variation, respectively

Passively Mode-Locked Solid-State Laser with Absorption Tunable Graphene Saturable Absorber Mirror

| openaire: EC/H2020/820423/EU//S2QUIPTwo-dimensional layered materials have attracted huge interest in the generation of ultrafast laser for their excellent saturable absorption properties. However, it is still challenging to precisely control their saturable absorption properties. Here, by alternatively changing the electric field intensity on the surface of high-reflection mirror, we successfully control the nonlinear absorption properties (e.g., saturable fluence, modulation depth) of graphene-based saturable absorber mirrors (GSAM) at the optical telecommunication wavelength of 1.3 mu m and their applications in solid-state lasers for the first time. Modulation depth of 1.2% is obtained from a GSAM with deposition of a lambda/8 ( = 1.3 mu m) thick SiO2 layer between the monolayer graphene and a high-reflection mirror, while modulation depth is increased to 4.3% with a lambda/4 thick SiO2 layer insertion in another GSAM. Pulses with the duration of 20 ps (lambda/8 thick SiO2 insertion) and 7.4 ps (lambda/4 thick SiO2 insertion) are achieved, respectively, based on the two mirrors. Our results indicate that this method is easy and reliable to versatility modulate the saturable absorption properties of other two-dimensional layered materials beyond graphene for the generation of ultrafast solid-state lasers.Peer reviewe

Enhanced terahertz emission from mushroom-shaped InAs nanowire network induced by linear and nonlinear optical effects

| openaire: EC/H2020/820423/EU//S2QUIP | openaire: EC/H2020/834742/EU//ATOP | openaire: EC/H2020/965124/EU//FEMTOCHIPThe development of powerful terahertz (THz) emitters is the cornerstone for future THz applications, such as communication, medical biology, non-destructive inspection, and scientific research. Here, we report the THz emission properties and mechanisms of mushroom-shaped InAs nanowire (NW) network using linearly polarized laser excitation. By investigating the dependence of THz signal to the incidence pump light properties (e.g. incident angle, direction, fluence, and polarization angle), we conclude that the THz wave emission from the InAs NW network is induced by the combination of linear and nonlinear optical effects. The former is a transient photocurrent accelerated by the photo-Dember field, while the latter is related to the resonant optical rectification effect. Moreover, the p-polarized THz wave emission component is governed by the linear optical effect with a proportion of ∼85% and the nonlinear optical effect of ∼15%. In comparison, the s-polarized THz wave emission component is mainly decided by the nonlinear optical effect. The THz emission is speculated to be enhanced by the localized surface plasmon resonance absorption of the In droplets on top of the NWs. This work verifies the nonlinear optical mechanism in the THz generation of semiconductor NWs and provides an enlightening reference for the structural design of powerful and flexible THz surface and interface emitters in transmission geometry.Peer reviewe

Soliton metamorphosis dynamics in ultrafast fiber lasers

Funding Information: This work was supported by the National Key R&D Program of China (Grant No. 2017YFA0303800), the National Natural Science Foundation of China (Grants No. 11634010 and No. 11874300), and the Fundamental Research Funds for the Central Universities (Grants No. 3102019JC008 and No. 3102019PY002). Publisher Copyright: © 2021 American Physical Society.The transitions from the incoherent noise to the coherent soliton have been fully revealed in ultrafast lasers. However, the soliton transformation between different coherent states, termed as soliton metamorphosis, remains an attractive yet uncharted territory. Here, we reveal the ultrafast dynamics of the soliton metamorphosis via single-shot spectroscopy in a specially designed fiber laser capable of emitting fast-switchable dissipative solitons and stretched pulses. It is demonstrated that the soliton metamorphosis is a consecutive evolution process including the self-phase modulation stage, pulse split stage, and transient stretched pulse stage. Particularly, the long-period pulse breathing and the spectral period doubling appear in the forepart and middle part of the last stage. The metamorphosis dynamics and soliton properties are substantiated by numerical simulation based on a three-step model. This work not only unveils the transient evolution physics of the pulse in soliton metamorphosis, but also provides a simple and effective way to control operations of ultrafast lasers.Peer reviewe