Shock-induced structures in copper

Shock loading of M3 copper within strain rate range of 5·10 6-5,7·10 6 s -1 reveals a nucleation of structural objects of 5-30 µm in diameter, which present the three dimensional frameworks composed from shear bands of 50-200 nm spacing. The structures are shown to be nucleated by means of interference of longitudinal and periphery release waves. Transition of the material into structure unstable state responsible for the shear banding happens when rate of change of the velocity variance at the mesoscale becomes higher than the rate of change of the mean particle velocity. The sites of nucleation of 3D-structures are speculated to be the staking faults generated under action of chaotic velocity pulsations relevant to dynamic deformation. The physical model for formation of 3D-structures takes into account the intersection of the partial dislocations and Lomer - Cottrell barriers

The Dual Function of PhOH Included in the Coordination Sphere of the Nickel Complexes in the Processes of Oxidation with Dioxygen

The role of ligands in the regulation of the catalytic activity of Ni-complexes (Ni(acac)2) in green process-selective ethylbenzene oxidation with O2 into α-phenyl ethyl hydroperoxide is considered in this article. The dual function of phenol (PhOH) included in the coordination sphere of the nickel complex as an antioxidant or catalyst depends on the ligand environment of the metal. The role of intermolecular H-bonds and supramolecular structures (AFM method) in the mechanisms of selective catalysis by nickel complexes in chemical and biological oxidation reactions is analyzed