2 research outputs found

    Cu(II)-Catalyzed Synthesis of Naphthalene-1,3-diamine Derivatives from Haloalkynes and Amines

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    An efficient procedure for the preparation of naphthalene-1,3-diamine derivatives by copper-catalyzed haloalkynes with amines has been reported. The reaction was supposed to proceed through a coupling reaction followed by the dimerization of ynamines

    Metal-Free–Catalyzed Oxidative Trimerization of Indoles Using NaNO<sub>2</sub> to Construct Quaternary Carbon Centers: Synthesis of 2-(1<i>H</i>-Indol-3-yl)-2,3′-biindolin-3-ones

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    <div><p></p><p>A simple, convenient, and efficient synthesis of 2-(1<i>H</i>-indol-3-yl)-2,3′-biindolin-3-one derivatives via a transition-metal-free-catalyzed oxidative trimeric reaction of indoles has been developed. This transformation may have occurred through a tandem oxidative homocoupling reaction by using NaNO<sub>2</sub> in pyridine as oxidant. This methodology provides an alternative approach for the direct generation of all-carbon quaternary centers at the C2 position of indoles.</p> </div
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