2 research outputs found
Visible-Light-Activated Suzuki–Miyaura Coupling Reactions of Aryl Chlorides over the Multifunctional Pd/Au/Porous Nanorods of CeO<sub>2</sub> Catalysts
Activation of aryl chlorides for
Suzuki–Miyaura coupling
(SMC) reactions is particularly challenging for heterogeneous catalysts
due to the chemically inert nature of the C–Cl bond. Herein,
the multifunctional Pd/Au/porous nanorods of CeO<sub>2</sub> (<i>PN</i>-CeO<sub>2</sub>) catalysts with a well-defined spatial
configuration deliver the first example of heterogeneous catalysts
to activate the strong C–Cl bond under the irradiation of visible
light (>400 nm) at room temperature. <i>PN</i>-CeO<sub>2</sub> with strong basicity not only provides the photogenerated
electrons
to enrich the electron density of metal nanoparticles but also generates
holes for activation of arylboronic acids. Meanwhile, due to the strong
local surface plasma resonance, the hot electrons from Au nanoparticles
excited by visible light can be injected into Pd nanocatalysts that
are spatially contacted with Au nanoparticles. Thus, Pd nanocatalysts
with significantly enriched electron density efficiently activate
the aryl chlorides under the visible light irradiation at room temperature.
The high catalytic activity and reusability of multifunctional photocatalysts
associated with full use of the photogenerated electrons and holes
inspire the future exploitation for the activation of unreactive chemical
bonds under mild conditions
Design of N‑Coordinated Dual-Metal Sites: A Stable and Active Pt-Free Catalyst for Acidic Oxygen Reduction Reaction
We develop a host-guest strategy
to construct an electrocatalyst
with Fe-Co dual sites embedded on N-doped porous carbon and demonstrate
its activity for oxygen reduction reaction in acidic electrolyte.
Our catalyst exhibits superior oxygen reduction reaction performance,
with comparable onset potential (<i>E</i><sub>onset</sub>, 1.06 vs 1.03 V) and half-wave potential (<i>E</i><sub>1/2</sub>, 0.863 vs 0.858 V) than commercial Pt/C. The fuel cell
test reveals (Fe,Co)/N-C outperforms most reported Pt-free catalysts
in H<sub>2</sub>/O<sub>2</sub> and H<sub>2</sub>/air. In addition,
this cathode catalyst with dual metal sites is stable in a long-term
operation with 50 000 cycles for electrode measurement and
100 h for H<sub>2</sub>/air single cell operation. Density functional
theory calculations reveal the dual sites is favored for activation
of O-O, crucial for four-electron oxygen reduction