1,457 research outputs found

    Neutrino mu-tau reflection symmetry and its breaking in the minimal seesaw

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    In this paper, we attempt to implement the neutrino μ\mu-τ\tau reflection symmetry (which predicts θ23=π/4\theta^{}_{23} = \pi/4 and δ=±π/2\delta = \pm \pi/2 as well as trivial Majorana phases) in the minimal seesaw (which enables us to fix the neutrino masses). For some direct (the preliminary experimental hints towards θ23π/4\theta^{}_{23} \neq \pi/4 and δπ/2\delta \neq - \pi/2) and indirect (inclusion of the renormalization group equation effect and implementation of the leptogenesis mechanism) reasons, we particularly study the breakings of this symmetry and their phenomenological consequences.Comment: 20 pages, 7 figures, accepted for publication in JHE

    Electroneutrality Breakdown and Specific Ion Effects in Nanoconfined Aqueous Electrolytes Observed by NMR

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    Ion distribution in aqueous electrolytes near the interface plays critical roles in electrochemical, biological and colloidal systems and is expected to be particularly significant inside nanoconfined regions. Electroneutrality of the total charge inside nanoconfined regions is commonly assumed a priori in solving ion distribution of aqueous electrolytes nanoconfined by uncharged hydrophobic surfaces with no direct experimental validation. Here, we use a quantitative nuclear magnetic resonance approach to investigate the properties of aqueous electrolytes nanoconfined in graphitic-like nanoporous carbon. Substantial electroneutrality breakdown in nanoconfined regions and very asymmetric responses of cations and anions to the charging of nanoconfining surfaces are observed. The electroneutrality breakdown is shown to depend strongly on the propensity of anions toward the water-carbon interface and such ion-specific response follows generally the anion ranking of the Hofmeister series. The experimental observations are further supported by numerical evaluation using the generalized Poisson-Boltzmann equationComment: 26 pages, 3 figure

    Methyl 3-methyl-5-oxo-4-(phenyl­hydrazono)-4,5-dihydro-1H-pyrazole-1-carbodithio­ate

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    The title compound, C12H11N4OS2, has been synthesized by the condensation reaction of 3-oxo-2-(phenyl­hydrazono)butanate and S-methyl­dithio­carbazate. The hydrazine unit and the pyrazole ring are coplanar [dihedral angle 3.8 (4)°] due to extensive conjugation and the N—H⋯O=C intra­molecular hydrogen bond. Two adjacent mol­ecules form dimers due to short C—H⋯O=C [R 2 2 (18)] and C—H⋯S=C [R 2 2 (22)] inter­molecular inter­actions. C—H⋯S—C [R 2 2 (14)] inter­actions link these dimers into ribbons in the [011] direction
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