Porous LSCF/Dense 3YSZ Interface Fracture Toughness Measured by Single Cantilever Beam Wedge Test

Sandwich specimens were prepared by firing a thin inter-layer of porous La0.6Sr0.4Co0.2Fe0.8O3-d (LSCF) to bond a thin tetragonal yttria-stabilised zirconia (YSZ) beam to a thick YSZ substrate. Fracture of the joint was evaluated by introducing a wedge between the two YSZ adherands so that the stored energy in the thin YSZ cantilever beam drives a stable crack in the adhesive bond and allows the critical energy release rate for crack extension (fracture toughness) to be measured. The crack path in most specimens showed a mixture of adhesive failure (at the YSZ-LSCF interface) and cohesive failure (within the LSCF). It was found that the extent of adhesive fracture increased with firing temperature and decreased with LSCF layer thickness. The adhesive failures were mainly at the interface between the LSCF and the thin YSZ beam and FEM modelling revealed that this is due to asymmetric stresses in the LSCF. Within the firing temperature range of 1000-1150C, the bonding fracture toughness appears to have a strong dependence on firing temperature. However, the intrinsic adhesive fracture toughness of the LSCF/YSZ interface was estimated to be 11 Jm2 and was not firing temperature dependent within the temperature range investigated.Comment: 13 figures, 1 table, journal paper publishe

Microbial network for waste activated sludge cascade utilization in an integrated system of microbial electrolysis and anaerobic fermentation

Background: Bioelectrochemical systems have been considered a promising novel technology that shows an enhanced energy recovery, as well as generation of value-added products. A number of recent studies suggested that an enhancement of carbon conversion and biogas production can be achieved in an integrated system of microbial electrolysis cell (MEC) and anaerobic digestion (AD) for waste activated sludge (WAS). Microbial communities in integrated system would build a thorough energetic and metabolic interaction network regarding fermentation communities and electrode respiring communities. The characterization of integrated community structure and community shifts is not well understood, however, it starts to attract interest of scientists and engineers. Results: In the present work, energy recovery and WAS conversion are comprehensively affected by typical pre-treated biosolid characteristics. We investigated the interaction of fermentation communities and electrode respiring communities in an integrated system of WAS fermentation and MEC for hydrogen recovery. A high energy recovery was achieved in the MECs feeding WAS fermentation liquid through alkaline pretreatment. Some anaerobes belonging to Firmicutes (Acetoanaerobium, Acetobacterium, and Fusibacter) showed synergistic relationship with exoelectrogens in the degradation of complex organic matter or recycling of MEC products (H-2). High protein and polysaccharide but low fatty acid content led to the dominance of Proteiniclasticum and Parabacteroides, which showed a delayed contribution to the extracellular electron transport leading to a slow cascade utilization of WAS. Conclusions: Efficient pretreatment could supply more short-chain fatty acids and higher conductivities in the fermentative liquid, which facilitated mass transfer in anodic biofilm. The overall performance of WAS cascade utilization was substantially related to the microbial community structures, which in turn depended on the initial pretreatment to enhance WAS fermentation. It is worth noting that species in AD and MEC communities are able to build complex networks of interaction, which have not been sufficiently studied so far. It is therefore important to understand how choosing operational parameters can influence reactor performances. The current study highlights the interaction of fermentative bacteria and exoelectrogens in the integrated system

Research on Control Technologies for a High-Precision Multi-Source Vibration Simulation System

Vehicles commonly suffer from the narrow-band noises and vibrations, usually a superposition of multiple sinusoidal signals, due to the excitations of engines, electrical motors, gear boxes, and other rotating mechanical parts. These excitations are transmitted to a reference point of some structure with certain transmission paths. The vibration signal measured at the reference point can be used for power system monitoring, fault diagnosis, modal analysis, noise analysis, etc. For convenience, researchers in a laboratory usually use shakers to generate expected narrow-band vibration signals acting on the vehicle structure reference points to simulate the vibration signals. However, there is a prominent difficulty in ensuring the amplitude and phase accuracy of each sub-frequency component simultaneously. In order to improve the accuracy of generating the expected vibration signal, this paper presents a multi-source vibration simulation control technology based on the tracking filter method. The main idea is to use the tracking filter to estimate the amplitude and phase of the target sub-frequency component accurately. Further, on the target sub-frequency, the drive signal of shakers is then corrected based on the amplitude and phase errors to achieve a more accurate target vibration signal. The amplitude and phase of each sub-frequency component in the excitation signal can be controlled independently. Compared with other Fast Fourier Transform (FFT)-based frequency domain analysis algorithms and numerical methods by solving the equations, the tracking filter method has a higher frequency resolution and higher accuracy. It can be easily realized in real time applications due to its simplicity. Finally, verification experiments are completed. The experimental results show that the multi-source vibration simulation control technology presented in this paper can achieve high-precision amplitude and phase on each sub-frequency component of the target vibration signals, which contain up to eight sub-frequency components

An investigation on the impact of blue and green spatial pattern alterations on the urban thermal environment: A case study of Shanghai

Consistent urbanization and global warming escalates the summer temperatures of the urban, significantly impacting daily lives and endangering well-being. It is difficult to balance urban construction and increasing the blue-green space. Hence, understanding the impact of changes in the blue-green spatial patterns in different spaces on the urban thermal environment is beneficial to the rational layout of urban patterns. Drawing from the case study of Shanghai, by employing bivariate spatial autocorrelation and multiscale geographically weighted regression, the spatial interplay between changes in the blue-green spatial distribution and modifications in land surface temperature grades is scrutinized, thus unraveling the underlying mechanisms of their mutual influence. The findings reveal the following: (1) The transformation of the blue-green spatial pattern exhibited substantial discrepancies between the northern and southern sectors. (2) The alteration of the thermal environment in Shanghai varies significantly spatially and is characterized by a decrease in temperature grade in the southwestern suburbs, an increase in the east, and almost no change in the central urban region. (3) Furthermore, the correlation between the extent of the change in the blue-green spatial pattern and the change in land surface temperature manifested spatial unevenness. (4) Finally, the mechanism underlying the changes of alterations in the blue-green spatial pattern on the thermal environment of the city emanates primarily from the influence of heat exchange areas. The spatial instability of the influence of blue-green spatial pattern on land surface temperature can provide implications for urban planners

Mathematical-morphology-based edge detection of retinal vessels in retinal images

Of all the important small and medium-sized blood vessels of the human body, retinal blood vessels are the only deep capillary that can be directly observed by a non-traumatic method. Retinal vascular morphology, such as vessel diameter, shape and distribution, is influenced by systemic diseases (Martinez-Perez, Hughes, Thom and Parker 2007). We can use digital fundus photography and analysis of retinal vascular morphology to find the relationship between the changes in vascular morphology and diabetes for the diagnosis of diseases. We aim at developing a retinal image processing system, that can analyze retinal images and provide helpful information for diagnosis. © 2013 Springer-Verlag

Bismuth Complex Controlled Morphology Evolution and CuSCN-Induced Transport Improvement Enable Efficient BiI3 Solar Cells

Bismuth triiodide (BiI3) is a particularly promising absorber material for inorganic thin-film solar cells due to its merits of nontoxicity and low cost. However, one key factor that limits the efficiency of BiI3 solar cells is the film morphology, which is strongly correlated with the trap states of the BiI3 film. Herein, we report a coordination engineering strategy by using Lewis base dimethyl sulfoxide (DMSO) to induce the formation of a stable BiI3(DMSO)2 complex for controlling the morphology of BiI3 films. Density functional theory calculations further provide a theoretical framework for understanding the interaction of the BiI3(DMSO)2 complex with BiI3. The obtained BiI3(DMSO)2 complex could assist the fabrication of highly uniform and pinhole-free films with preferred crystallographic orientation. This high-quality film enables reduced trap densities, a suppressed charge recombination, and improved carrier mobility. In addition, the use of copper(I) thiocyanate (CuSCN) as a hole transport layer improves the charge transport, enabling the realization of solar cells with a record power conversion efficiency of 1.80% and a champion fill factor of 51.5%. Our work deepens the insights into controlling the morphology of BiI3 thin films through the coordination engineering strategy and paves the way toward further improving the photovoltaic performances of BiI3 solar cells