206,867 research outputs found
Femtosecond electron and spin dynamics probed by nonlinear optics
A theoretical calculation is performed for the ultrafast spin dynamics in
nickel using an exact diagonalization method. The present theory mainly focuses
on a situation where the intrinsic charge and spin dynamics is probed by the
nonlinear (magneto-)optical responses on the femtosecond time scale, i.e.
optical second harmonic generation (SHG) and the nonlinear magneto-optical Kerr
effect (NOLIMOKE). It is found that the ultrafast charge and spin dynamics are
observable on the time scale of 10 fs. The charge dynamics proceeds ahead of
the spin dynamics, which indicates the existence of a spin memory time. The
fast decay results from the loss of coherence in the initial excited state.
Both the material specific and experimental parameters affect the dynamics. We
find that the increase of exchange interaction mainly accelerates the spin
dynamics rather than the charge dynamics. A reduction of the hopping integrals,
such as present at interfaces, slows down the spin dynamics significantly.
Besides, it is found that a spectrally broad excitation yields the intrinsic
speed limit of the charge (SHG) and spin dynamics (NOLIMOKE) while a narrower
width prolongs the dynamics. This magnetic interface dynamics then should
become accessible to state of art time resolved nonlinear-optical experiments.Comment: 5 pages with 3 figures, to appear in Applied. Phys. B 68, (1999
Physics of the Pseudogap State: Spin-Charge Locking
The properties of the pseudogap phase above Tc of the high-Tc cuprate
superconductors are described by showing that the Anderson-Nambu SU(2) spinors
of an RVB spin gap 'lock' to those of the electron charge system because of the
resulting improvement of kinetic energy. This enormously extends the range of
the vortex liquid state in these materials. As a result it is not clear that
the spinons are ever truly deconfined. A heuristic description of the
electrodynamics of this pseudogap-vortex liquid state is proposed.Comment: Submitted to Phys Rev Letter
Arsenic(III) remediation from contaminated water by oxidation and Fe/Al co-precipitation
Battery grade γ-MnO2 powder was investigated as an oxidant and an adsorbent in combination with Fe/Al coagulants for removal of arsenic from contaminated water. Simultaneous oxidation of As(III) and removal by coprecipitation/adsorption (one step process) was compared with pre-oxidation and subsequent removal by coprecipitation/adsorption (two step process). The rate of As(III) oxidation with MnO2 is completed in two stages: rapid initially followed by a first order reaction. As(III) is oxidised to As(V) by the MnO2 with a release of approximately 1:1 molar Mn(II) into the solution. No significant pH effect on oxidation of As(III) was observed in the pH range 4 - 6. The rate showed a decreasing trend above pH 6. The removal of As(V) by adsorption on the MnO2 decreased significantly with increasing pH from 4 to 8. The adsorption capacity of the γ-MnO2 with particle size 90% passing 10 µm was determined to be 1.5 mg/g at pH 7. MnO2 was found to be more effective as an oxidant for As(III) in the two step process than in the one step process
Octupole degree of freedom for the critical-point candidate nucleus Sm in a reflection-asymmetric relativistic mean-field approach
The potential energy surfaces of even-even Sm are investigated in
the constrained reflection-asymmetric relativistic mean-field approach with
parameter set PK1. It is shown that the critical-point candidate nucleus
Sm marks the shape/phase transition not only from U(5) to SU(3)
symmetry, but also from the octupole-deformed ground state in Sm to the
quadrupole-deformed ground state in Sm. By including the octupole
degree of freedom, an energy gap near the Fermi surface for single-particle
levels in Sm with is found, and the
important role of the octupole deformation driving pair and is demonstrated.Comment: 11 pages, 3 figure
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