Synthesis and Properties of La1−x_{1-x}Srx_xNiO3_3 and La1−x_{1-x}Srx_xNiO2_2

Superconductivity has been realized in films of La$_{1-x}$Sr$_x$NiO$_2$. Here we report synthesis and characterization of polycrystalline samples of La$_{1-x}$Sr$_x$NiO$_3$ and La$_{1-x}$Sr$_x$NiO$_2$ ($0\le x\le 0.2$). Magnetization and resistivity measurements reveal that La$_{1-x}$Sr$_x$NiO$_3$ are paramagnetic metals and La$_{1-x}$Sr$_x$NiO$_2$ exhibit insulating behavior. Superconductivity is not detected in bulk samples of La$_{1-x}$Sr$_x$NiO$_2$. The absence of superconductivity in bulk La$_{1-x}$Sr$_x$NiO$_2$ may be due to the generation of hydroxide during reduction or a small amount of nickel impurities. The effect of interface in films of La$_{1-x}$Sr$_x$NiO$_2$ may also play a role for superconductivity.Comment: 9 pages, 4 figure

Coexistence of ferromagnetism, antiferromagnetism, and superconductivity in magnetically anisotropic (Eu,La)FeAs2

Materials with exceptional magnetism and superconductivity usually conceive emergent physical phenomena. Here, we investigate the physical properties of the (Eu,La)FeAs2 system with double magnetic sublattices. The parent EuFeAs2 shows anisotropy-associated magnetic behaviors, such as Eu-related moment canting and exchange bias. Through La doping, the magnetic anisotropy is enhanced with ferromagnetism of Eu2+ realized in the overdoped region, and a special exchange bias of the superposed ferromagnetic/superconducting loop revealed in Eu0.8La0.2FeAs2. Meanwhile, the Fe-related antiferromagnetism shows unusual robustness against La doping. Theoretical calculation and 57Fe M\"ossbauer spectroscopy investigation reveal a doping-tunable dual itinerant/localized nature of the Fe-related antiferromagnetism. Coexistence of the Eu-related ferromagnetism, Fe-related robust antiferromagnetism, and superconductivity is further revealed in Eu0.8La0.2FeAs2, providing a platform for further exploration of potential applications and emergent physics. Finally, an electronic phase diagram is established for (Eu,La)FeAs2 with the whole superconducting dome adjacent to the Fe-related antiferromagnetic phase, which is of benefit for seeking underlying clues to high-temperature superconductivity.Comment: 13 pages, 6 figures for the main tex

Single crystal growth and superconductivity in RbNi2_2Se2_2

We report the synthesis and characterization of RbNi$_2$Se$_2$, an analog of the iron chalcogenide superconductor Rb$_x$Fe$_2$Se$_2$, via transport, angle resolved photoemission spectroscopy, and density functional theory calculations. A superconducting transition at $T_{c}$ = 1.20 K is identified. In normal state, RbNi$_2$Se$_2$ shows paramagnetic and Fermi liquid behaviors. A large Sommerfeld coefficient yields a heavy effective electron mass of $m^{*}\approx6m_{e}$. In the superconducting state, zero-field electronic specific-heat data $C_{es}$ can be described by a two-gap BCS model, indicating that RbNi$_2$Se$_2$ is a multi-gap superconductor. Our density functional theory calculations and angle resolved photoemission spectroscopy measurements demonstrate that RbNi$_2$Se$_2$ exhibits relatively weak correlations and multi-band characteristics, consistent with the multi-gap superconductivity.Comment: 7 pages, 4 figure

Responses of photosynthesis, chlorophyll fluorescence, and grain yield of maize to controlled-release urea and irrigation after anthesis

Controlled-release urea (CRU) is a new type of urea, which may increase crop nitrogen (N)-use efficiency compared with conventional urea (CU), but the conditions where it outperforms urea are not well defined. A field experiment assessing responses of plant growth and grain yield of maize to CRU and irrigation was conducted on a typical agricultural farm in Shandong, China. Five treatments of the two types of urea (75, 150kg N ha(-1), 0kg N ha(-1)) were applied as basal fertilizer when sowing maize, and two water treatments (W-0 and W-1) were used 23 d after anthesis. Net photosynthetic rate (P-N) and chlorophyll concentration as well as leaf-area index (LAI) increased significantly by both CRU and CU application, with the increases being larger in CRU-treated plants than in CU-treated plants at grain filling and maturing stages. CRU significantly enhanced the maximum photochemical efficiency (F-v/F-m), PSII coefficient of photochemical fluorescence quenching (q(P)), and actual quantum yield of PSII electron transformation (phi(PSII)) but decreased the nonphotochemical quenching (NPQ). Cob-leaf N concentration of CRU-treated plants was significantly higher than that of CU-treated plants under no irrigation, but not in the irrigation treatment 30 d after anthesis. Significant positive correlations were found between cob-leaf N concentration and P-N both with and without irrigation. Grain yield of maize was significantly higher in the CRU treatment than in the CU treatment under both irrigation conditions. In conclusion, CRU as a basal application appeared to increase the N-use efficiency for maize relative to CU especially by maintaining N supply after anthesis

Lubricating Oil Pollution Detection Sensor Design

Metal abrasive particle content in lubricating oil is an important index to judge the degree of deterioration of lubricating oil. Established a spiral electrode capacitance sensor by the finite element software ANSYS, the simulation result shows that the sensor is sensitive to the content of metal abrasive particle in lubricating oil, not affect by the metal abrasive particle itself. According to the simulation optimization model to make the real sensor, and designed lubricating oil pollution degree measurement system with the MS3110 capacitance detection circuit and MCU. Experiments show that it can distinguish metal abrasive particle from the change of 0.1 %-0.5 % content, this change can determine the degree of pollution of metal abrasive particle in lubricating oil, provides a simple and feasible method for the oil pollution detection