The catalytic reduction of NO by H-2 on Ru(0001): Observation of NHads species

Adsorption of NO and the reaction between NO and H-2 were investigated on the Ru(0001) surface by X-ray photoelectron spectroscopy (XPS). Surface composition was measured after NO adsorption and after the selective catalytic reduction of nitric oxide with hydrogen in steady-state conditions at 320 K and 390 K in a 30:1 mixture of H-2 and NO (total pressure = 10(-4) mbar). After steady-state NO reduction, molecularly adsorbed NO in both the linear on-top and threefold coordinations, NHads and N-ads species were identified by XPS. The coverage of the NHads and N-ads species was higher after the reaction at 390 K than the corresponding values at 320 K Strong destabilisation of N-ads by O-ads was detected. A possible reaction mechanism is discussed. (c) 2005 Elsevier B.V. All rights reserved

Evidence for an energy scale for quasiparticle dispersion in Bi_2Sr_2CaCu_2O_8

Quasiparticle dispersion in $Bi_{2}Sr_{2}CaCu_{2}O_{8}$ is investigated with improved angular resolution as a function of temperature and doping. Unlike the linear dispersion predicted by the band calculation, the data show a sharp break in dispersion at $50\pm10$ $meV$ binding energy where the velocity changes by a factor of two or more. This change provides an energy scale in the quasiparticle self-energy. This break in dispersion is evident at and away from the d-wave node line, but the magnitude of the dispersion change decreases with temperature and with increasing doping.Comment: 4 figure

Multiple filamentation of laser beams with different diameters in the air at a 100-meter path

Results of experiments on controlling the position and length of the filamentation zone of femtosecond laser pulses in atmospheric path length 110 m using different initial spatial focusing and defocusing. The obtained distribution of filaments along the filamentation zone, measured dependence the length of the filamentation zone of the numerical aperture of the beam, its initial radius and pulse power

Global self-focusing and features of multiple filamentation of radiation of a subterawatt Ti:sapphire laser with a centimeter output aperture along a 150-m path

The formation and propagation of postfilamentation channels along a controllable path 150 m long are studied experimentally for collimated beams of different diameters. During multiple filamentation, a laser beam is compressed into a global focus, after passing which its angular divergence is much greater than the divergence of postfilamentation channels generated during the filamentation. It is shown that the intensity of the postfilamentation channels is sufficient for starting multiple filamentation in optical elements at distances much longer than the filamentation region length

Multiple filamentation of laser beams with different diameters in the air at a 150-meter path

Results of experiments on controlling the position and length of the filamentation zone of femtosecond laser pulses in atmospheric path length 150 m using different initial spatial focusing and defocusing. The obtained distribution of filaments along the filamentation zone, measured dependence the length of the filamentation zone of the numerical aperture of the beam, its initial radius and pulse power

Filamentation of terawatt laser pulses along hundred-meter atmospheric paths

Results of the experimental study of filamentation of terawatt femtosecond pulses of a Ti:Sapphire laser along an atmospheric path 106 m long using different spatial focusing and pulse power are presented. The control of filamentation region position and length by means of changing the initial laser beam focusing is shown to be highly effective. Dependencies are derived of filamentation region position and length on the initial degree of focusing, pulse power, and the number of filaments along the filamentation region. The obtained data on the filamentation region length and the number of filaments are compared with the results of our previous experiments and data from other authors

Localized high-intensity light structures during multiple filamentation of Ti:sapphire-laser femtosecond pulses along an air path

The results of experimental studies of the transverse structure of a laser beam after multiple filamentation are presented. A ring structure of radiation is formed around individual filaments in a beam cross section inside the multiple filamentation domain, and at a dozen meters from it a common ring structure starts forming surrounding postfilamentation light channels (PFC). It is shown that the spectra of the PFC, rings, and beam are significantly different. The ring spectrum broadens asymmetrically relative to the carrier wavelength and is mainly concentrated in the short wavelength region. The PFC spectrum has a significant and more symmetrical broadening and covers the range 630–1000 nm

Modeling of multiple filamentation of terawatt laser pulses on a hundred-meter air path

The results of numerical simulation of multiple filamentation of terawatt femtosecond pulse Ti:Sapphire laser performed on the experimental data obtained in the airway of a length of 106 m when changing the initial spatial focusing and laser power

Multiple filamentation Ti:Sapphire-laser pulses in water

The results of experimental studies of the spatial characteristics of multiple filamentation terawatt femtosecond Ti:Salaser in water are presented. With an increase in initial power laser pulses increases the number of filaments, the length of the field is increased filamentation and reducing the length of the filaments have been shown. The distribution of the filaments in the longitudinal direction of the field of multiple filamentation has a maximum cross-sectional filament is shifted from the center to the periphery of the beam at the end region of filamentation. The minimum diameter of the beam on the track corresponds to the position of the maximum number of filaments. After the point of maximum impulse essentially loses energy in the initial direction of propagation. Upon reaching the pulse power 2 104 Pcr of multiple filamentation area is formed of a hollow cone, the apex directed to the radiation source