Relationships among coking coals and related cokes characteristics: a statistical evaluation

From 61 coking coals, 36 coal blends were prepared. Using a pilot coke oven, cokes were prepared from both 61 coking coals (Type I cokes) and 36 coal blends (Type II cokes). Coals were characterized by 14 coal characteristics and cokes by Coke Reactivity Index CRI and Coke Strength after Reaction with CO2 CSR. For the study of mutual statistic relationships among experimentally determined characteristics of coals and cokes, the Factor (FA) and Regression Analyses (RA) were used. FA distributed characteristics of coals and Type I cokes into 4 factors while characteristics of coal blends and Type II cokes were distributed into 7 factors. In case of pure coals and Type I cokes, strong relationships with high correlation coefficients (R > vertical bar 0.60 vertical bar) were more abundant than in case of coal blends and Type II cokes. FA was used for the selection of coal characteristics that influence the coke quality the most significantly. These characteristics were then recalculated by RA for the predictions of CRI/CSR of Type I cokes. Predictions of CRI/CSR of Type II cokes were calculated from coal blends by the same procedure. The comparison of the predicted and experimentally determined CRI and CSR indexes showed much more reliable prediction of CRI/CSR indexes calculated from coals than calculated from coal blends. This study also explains the dominant reasons of this observation.Web of Science15332231

Crystallization and quantification of crystalline and non-crystalline phases in kaolin-based cordierites

Kaolin is most often used as traditional raw material in ceramic industry. The purpose of the study was to obtain understanding of the structural and chemical variability of cordierite ceramics influenced by chemical and mineralogical properties of six raw kaolins taken from different localities when they are applied in ceramics mixtures with vermiculite and sintered up to 1300 degrees C. The X-ray diffraction and simultaneous thermogravimetric and differential thermal analysis were used to identify and characterize crystalline mineral phases and the course of reactions during the heating. The percentages of the crystalline and non-crystalline phases were newly determined by recalculation of the bulk chemical analyses of kaolins and cordierite ceramics using Chemical Quantitative Mineral Analysis (CQMA) method. Varying amounts of minerals in kaolins: kaolinite from 73.3 to 85.0, muscovite from 4.2 to 9.9, and quartz from 6.0 to 19.5 (mass %) affected amount of cordierite/indialite from 75.2 to 85.1, enstatite from 5.8 to 8.9 (when are calculated as their maximal possible percentages), and non-crystalline phases from 8.8 to 15.1 (mass %) in cordierite ceramics. Regression analysis predicted high relationship between quantity of: (a) kaolinite in kaolins and crystalline cordierite and (b) quartz in kaolins and non-crystalline phases in the ceramics. The migration of potassium from muscovite into the cordierite structure, melting point and crystallization of cordierite/indialite phases and pore size variability in relation to impurity of kaolins are documented and discussed.Web of Science1219art. no. 310

Alkali-activated metakaolins: Mineral chemistry and quantitative mineral composition

The reaction products resulting from the alkali-activation of metakaolin are impacted by the composition of the initial kaolin, and amount of alkali-activated kaolinite and water. The present study focused on analyzing these parameters on the metakaolins calcined at 800 degrees C from three kaolins, and the metakaolins' alkali activation for 2, 3 and 28 days. The first objective was to evaluate the mineral chemistry and quantitative mineral phase composition from the bulk chemical analysis using the chemical quantitative mineral analysis (CQMA) procedure and conduct a comparison of the chemistry of the metakaolins after alkali activation for 28 days according to the elements Al, Si, Na and K, using the leaching test in distilled water. The second task was to search for possible relationships between the quantitative number of phases in alkali-activated metakaolins and compressive strength. The main methods used for the characterization of material were X-ray fluorescence, X-ray diffraction, thermal TG/DTA and infrared spectroscopy. Metakaolins alkali activated for 28 days contained crystalline quartz, muscovite, orthoclase, and unreacted metakaolinite contained zeolite A (Z-A), hydrosodalite (HS) and thermonatrite (TN) in the amorphous/weakly crystalline phase. The compressive strengths (CS) from 6.42 +/- 0.33 to 9.97 +/- 0.50 MPa are related positively to H2O+ and H2O bound in HS and TN.Web of Science1211art. no. 134

Quantitative Evaluation of Crystalline and Amorphous Phases in Clay-Based Cordierite Ceramic

An innovative chemical quantitative mineral analysis (CQMA) was successfully tested on a cordierite-based clay ceramic sample to quantify crystalline and amorphous components. The accuracy of this method was demonstrated on an added module to the CQMA program that used oxide formulas of amorphous phases obtained by energy dispersive X-ray spectroscopy (EDS) microprobe chemical analysis. This CQMA method was tested for three variants calculated using chemical analysis, i.e., X-ray diffraction (XRD) identification of crystalline (cordierite and enstatite) and amorphous phases by scanning electron microscopy (SEM)/EDS texture and microanalyses. The test results from CQMA suggest their application possibilities as well as the limits of their utilization

Studium chování iontového asociátu fluorboritanu s metylenovou modří při extrakčně fotometrickém stanovení boru v horninách

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