Bounds on Slow Roll at the Boundary of the Landscape

We present strong evidence that the tree level slow roll bounds of arXiv:1807.05193 and arXiv:1810.05506 are valid, even when the tachyon has overlap with the volume of the cycle wrapped by the orientifold. This extends our previous results in the volume-dilaton subspace to a semi-universal modulus. Emboldened by this and other observations, we investigate what it means to have a bound on (generalized) slow roll in a multi-field landscape. We argue that for $any$ point $\phi_0$ in an $N$-dimensional field space with $V(\phi_0) > 0$, there exists a path of monotonically decreasing potential energy to a point $\phi_1$ within a path length $\lesssim {\cal O}(1)$, such that $\sqrt{N}\ln \frac{V(\phi_1)}{V(\phi_0)} \lesssim - {\cal O} (1)$. The previous de Sitter swampland bounds are specific ways to realize this stringent non-local constraint on field space, but we show that it also incorporates (for example) the scenario where both slow roll parameters are intermediate-valued and the Universe undergoes a small number of e-folds, as in the Type IIA set up of arXiv:1310.8300. Our observations are in the context of tree level constructions, so we take the conservative viewpoint that it is a characterization of the classical "boundary" of the string landscape. To emphasize this, we argue that these bounds can be viewed as a type of Dine-Seiberg statement.Comment: v4: one more referenc

Variability of the Conductance Changes Associated with the Change in the Spin State in Molecular Spin Crossover Complexes

Here, we examine the conductance changes associated with the change in spin state in a variety of different structures, using the example of the spin crossover complex [Fe(H2B(pz)2)2(bipy)] (pz = (pyrazol-1-yl)-borate and bipy = 2,2′-bipyridine) and [Fe(Htrz)2(trz)](BF4)] (Htrz = 1H-1,2,4-triazole) thin films. This conductance change is highly variable depending on the mechanism driving the change in spin state, the substrate, and the device geometry. Simply stated, the choice of spin crossover complex used to build a device is not the only factor in determining the change in conductance with the change in spin state

Electronic transport properties of spin-crossover polymer plus polyaniline composites with Fe3O4 nanoparticles

Adding Fe3O4 nanoparticles to composites of [Fe(Htrz)2(trz)](BF4) spin-crossover polymer and polyaniline (PANI) drives a phase separation of both and restores the molecular structure and cooperative effects of the spin-crossover polymer without compromising the increased conductivity gained through the addition of PANI. We observe an increased on-off ratio for the DC conductivity owing to an enlarged off state resistivity and a 20 times larger AC conductivity of the on state compared with DC values. The Fe3O4 nanoparticles, primarily confined to the [Fe(Htrz)2(trz)](BF4) phase, are ferromagnetically coupled to the local moment of the spin-crossover molecule suggesting the existence of an exchange interaction between both components

Perturbing the spin state and conduction of Fe (II) spin crossover complexes with TCNQ

We investigated modifications driven by 7,7,8,8-tetracyanoquinodimethane (TCNQ) to the spin state configuration of [Fe(3-bpp)2](TCNQ)2 co-crystal and both spin state and electric conductivity of [Fe{H2B(pz)2}2(bipy)] and TCNQ mixtures. The Fe2+ site in the [Fe(3-bpp)2](TCNQ)2 co-crystal has a sizable orbital moment. During X-ray absorption measurements, the iron ion is partially excited to the high spin state and strong surface effects are indicated. Mixing TCNQ with the [Fe{H2B(pz)2}2(bipy)] spin crossover complex leads to a molecular combination with increased conductivity and drift carrier lifetimes. [Fe{H2B(pz)2}2(bipy)] thin films with TCNQ, grown using dimethylformamide (DMF), are to great extent locked mainly in the low spin (LS) state across a broad temperature range and exhibit drift carrier lifetimes approaching 0.5 s. When deposited onto a ferroelectric polyvinylidenefluoride-hexafluoropropylene thin film substrate, [Fe{H2B(pz)2}2(bipy)], shows enhanced transistor carrier mobility, likely associated with the increasing cationic character of [Fe{H2B(pz)2}2(bipy)] thin films with TCNQ