Some recent theoretical results on amorphous packings of hard spheres

The aim of this paper is to review and discuss qualitatively some results on the properties of amorphous packings of hard spheres that were recently obtained by means of the replica method. The theory gives predictions for the equation of state of the glass, the complexity of the metastable states, the scaling of the pressure close to jamming, the coordination of the packing and the pair correlation function in any space dimension d. The predictions compare very well with numerical simulations in d=3 and somehow also in d=2. The asymptotic predictions for d->oo are within the rigorous bounds. The theory can be extended to binary mixtures and to hard core potentials with an attractive tail or square well.Comment: 7 pages, 6 figures; proceedings of the X International Workshop on Disordered Systems, Molveno (TN), Italy, March 200

The ideal glass transition of Hard Spheres

We use the replica method to study the ideal glass transition of a liquid of identical Hard Spheres. We obtain estimates of the configurational entropy in the liquid phase, of the Kauzmann packing fraction, in the range 0.58--0.62, and of the random close packing density, in the range 0.64--0.67, depending on the approximation we use for the equation of state of the liquid. We also compute the pair correlation function in the glassy states (i.e., dense amorphous packings) and we find that the mean coordination number at random close packing is equal to 6. All these results compare well with numerical simulations and with other existing theories.Comment: 13 pages, 8 figure

Amorphous packings of hard spheres in large space dimension

In a recent paper (cond-mat/0506445) we derived an expression for the replicated free energy of a liquid of hard spheres based on the HNC free energy functional. An approximate equation of state for the glass and an estimate of the random close packing density were obtained in d=3. Here we show that the HNC approximation is not needed: the same expression can be obtained from the full diagrammatic expansion of the replicated free energy. Then, we consider the asymptotics of this expression when the space dimension d is very large. In this limit, the entropy of the hard sphere liquid has been computed exactly. Using this solution, we derive asymptotic expressions for the glass transition density and for the random close packing density for hard spheres in large space dimension.Comment: 11 pages, 1 figure, includes feynmf diagram

Fragility in p-spin models

We investigate the relation between fragility and phase space properties - such as the distribution of states - in the mean field p-spin model, a solvable model that has been frequently used in studies of the glass transition. By direct computation of all the relevant quantities, we find that: i) the recently observed correlation between fragility and vibrational properties at low temperature is present in this model; ii) the total number of states is a decreasing function of fragility, at variance of what is currently believed. We explain these findings by taking into account the contribution to fragility coming from the transition paths between different states. Finally, we propose a geometric picture of the phase space that explains the correlation between properties of the transition paths, distribution of states and their vibrational properties. However, our analysis may not apply to strong systems where inflection points in the configurational entropy as a function of the temperature are found

Fluctuation Relation beyond Linear Response Theory

The Fluctuation Relation (FR) is an asymptotic result on the distribution of certain observables averaged over time intervals T as T goes to infinity and it is a generalization of the fluctuation--dissipation theorem to far from equilibrium systems in a steady state which reduces to the usual Green-Kubo (GK) relation in the limit of small external non conservative forces. FR is a theorem for smooth uniformly hyperbolic systems, and it is assumed to be true in all dissipative ``chaotic enough'' systems in a steady state. In this paper we develop a theory of finite time corrections to FR, needed to compare the asymptotic prediction of FR with numerical observations, which necessarily involve fluctuations of observables averaged over finite time intervals T. We perform a numerical test of FR in two cases in which non Gaussian fluctuations are observable while GK does not apply and we get a non trivial verification of FR that is independent of and different from linear response theory. Our results are compatible with the theory of finite time corrections to FR, while FR would be observably violated, well within the precision of our experiments, if such corrections were neglected.Comment: Version accepted for publication on the Journal of Statistical Physics; minor changes; two references adde

Fluctuation theorem for non-equilibrium relaxational systems driven by external forces

We discuss an extension of the fluctuation theorem to stochastic models that, in the limit of zero external drive, are not able to equilibrate with their environment, extending results presented by Sellitto (cond-mat/9809186). We show that if the entropy production rate is suitably defined, its probability distribution function verifies the Fluctuation Relation with the ambient temperature replaced by a (frequency-dependent) effective temperature. We derive modified Green-Kubo relations. We illustrate these results with the simple example of an oscillator coupled to a nonequilibrium bath driven by an external force. We discuss the relevance of our results for driven glasses and the diffusion of Brownian particles in out of equilibrium media and propose a concrete experimental strategy to measure the low frequency value of the effective temperature using the fluctuations of the work done by an ac conservative field. We compare our results to related ones that appeared in the literature recently.Comment: 39 pages, 6 figure

Fluctuations of entropy production in the isokinetic ensemble

We discuss the microscopic definition of entropy production rate in a model of a dissipative system: a sheared fluid in which the kinetic energy is kept constant via a Gaussian thermostat. The total phase space contraction rate is the sum of two statistically independent contributions: the first one is due to the work of the conservative forces, is independent of the driving force and does not vanish at zero drive, making the system non-conservative also in equilibrium. The second is due to the work of the dissipative forces, and is responsible for the average entropy production; the distribution of its fluctuations is found to verify the Fluctuation Relation of Gallavotti and Cohen. The distribution of the fluctuations of the total phase space contraction rate also verify the Fluctuation Relation. It is compared with the same quantity calculated in the isoenergetic ensemble: we find that the two ensembles are equivalent, as conjectured by Gallavotti. Finally, we discuss the implication of our results for experiments trying to verify the validity of the FR.Comment: 8 pages, 4 figure

Fluctuations relation and external thermostats: an application to granular materials

In this note we discuss a paradigmatic example of interacting particles subject to non conservative external forces and to the action of thermostats consisting of external (finite) reservoirs of particles. We then consider a model of granular materials of interest for experimental tests that had recently attracted lot of attentions. This model can be reduced to the previously discussed example under a number of assumptions, in particular that inelasticity due to internal collisions can be neglected for the purpose of measuring the large deviation functional for entropy production rate. We show that if the restitution coefficient in the granular material model is close to one, then the required assuptions are verified on a specific time scale and we predict a fluctuation relation for the entropy production rate measured on the same time scale.Comment: 7 pages; updated to take into account comments received on the first version; to appear on J.Stat.Mech.(2006

A note on rattlers in amorphous packings of binary mixtures of hard spheres

It has been recently pointed out by Farr and Groot (arXiv:0912.0852) and by Kyrylyuk and Philipse (Prog. Colloid Polym. Sci., 2010, in press) that our theoretical result for the jamming density of a binary mixture of hard spheres (arXiv:0903.5099) apparently violates an upper bound that is obtained by considering the limit where the diameter ratio r = DA/DB goes to infinity. We believe that this apparent contradiction is the consequence of a misunderstanding, which we try to clarify here.Comment: 2 pages, 2 figures; final version published on J.Chem.Phy

Jamming Criticality Revealed by Removing Localized Buckling Excitations

Recent theoretical advances offer an exact, first-principle theory of jamming criticality in infinite dimension as well as universal scaling relations between critical exponents in all dimensions. For packings of frictionless spheres near the jamming transition, these advances predict that nontrivial power-law exponents characterize the critical distribution of (i) small inter-particle gaps and (ii) weak contact forces, both of which are crucial for mechanical stability. The scaling of the inter-particle gaps is known to be constant in all spatial dimensions $d$ -- including the physically relevant $d=2$ and 3, but the value of the weak force exponent remains the object of debate and confusion. Here, we resolve this ambiguity by numerical simulations. We construct isostatic jammed packings with extremely high accuracy, and introduce a simple criterion to separate the contribution of particles that give rise to localized buckling excitations, i.e., bucklers, from the others. This analysis reveals the remarkable dimensional robustness of mean-field marginality and its associated criticality.Comment: 12 pages, 4 figure