Jamming Criticality Revealed by Removing Localized Buckling Excitations

Recent theoretical advances offer an exact, first-principle theory of jamming criticality in infinite dimension as well as universal scaling relations between critical exponents in all dimensions. For packings of frictionless spheres near the jamming transition, these advances predict that nontrivial power-law exponents characterize the critical distribution of (i) small inter-particle gaps and (ii) weak contact forces, both of which are crucial for mechanical stability. The scaling of the inter-particle gaps is known to be constant in all spatial dimensions $d$ -- including the physically relevant $d=2$ and 3, but the value of the weak force exponent remains the object of debate and confusion. Here, we resolve this ambiguity by numerical simulations. We construct isostatic jammed packings with extremely high accuracy, and introduce a simple criterion to separate the contribution of particles that give rise to localized buckling excitations, i.e., bucklers, from the others. This analysis reveals the remarkable dimensional robustness of mean-field marginality and its associated criticality.Comment: 12 pages, 4 figure

Labour activism and social movement unionism in the gig economy. Food delivery workers' struggles in Italy

This article aims to explore the forms of collective actions that are emerging in new sectors of digital capitalism. In particular, it enquires into the mobilisation of food delivery workers that has been de-veloping since 2016 in four Italian cities: Milan, Turin, Bologna and Florence. Despite the high level of pre-carisation and atomisation that characterise this subset of gig economy jobs, the so-called riders were able to organise into self-organised workers' collectives, which not only gave rise to many protest events, but also drew the attention of the institutions and the media. What are the conditions and the strategies that made this possible? And, more broadly, what does this case tell us about the possibility of labour activism in gig economy work? We argue that the high level of activation of food delivery workers is to be related to their capability to provide resources for reconstructing social ties among workers and, in turn, for translat-ing them into political engagement and contentious action. This is realised through the combination of three factors that will be scrutinised in the paper. The analysis points out that although precarisation cre-ates significant obstacles to organisation and mobilisation, collective action does actually take place also in the gig economy, in certain conditions

Low-frequency vibrational spectrum of mean-field disordered systems

We study a recently introduced and exactly solvable mean-field model for the density of vibrational states D(ω) of a structurally disordered system. The model is formulated as a collection of disordered anharmonic oscillators, with random stiffness κ drawn from a distribution p(κ), subjected to a constant field h and interacting bilinearly with a coupling of strength J. We investigate the vibrational properties of its ground state at zero temperature. When p(κ) is gapped, the emergent D(ω) is also gapped, for small J. Upon increasing J, the gap vanishes on a critical line in the (h, J) phase diagram, whereupon replica symmetry is broken. At small h, the form of this pseudogap is quadratic, D(ω) ~ ω2, and its modes are delocalized, as expected from previously investigated mean-field spin glass models. However, we determine that for large enough h, a quartic pseudogap D(ω) ~ ω4, populated by localized modes, emerges, the two regimes being separated by a special point on the critical line. We thus uncover that mean-field disordered systems can generically display both a quadratic-delocalized and a quartic-localized spectrum at the glass transition.</p

Environmental impacts and risk assessment in the re-use of Cr-bearing pyrolyzed tannery wastes: A case study in a residential area

Increasing concern has been raised on the environmental impacts of chromium -tanning wastes recycling. In particular, the pyrolytic conversion of leather industry sludges into Cr(VI)-free carbonized residues is believed to represent a viable route for a sustainable re -use of this type of wastes. The aim of this study was to determine the impact of recycled Cr-bearing pyrolyzed char (named KEU) as backfilling material for road construction in an urban area in Tuscany (Italy). Geochemical and chromium -isotope data, together with microstructural analyses (HR-TEM and XAS), indicate that the presence of KEU results in a significant enhancement of the natural Cr background. The results support the hypothesis that, in environmental conditions, the Cr (III) hosted in KEU is converted into Cr(VI), which is leached out by rainwater. Indeed, Cr(VI) is dispersed in surface water, reaching concentrations up to 18 mg/L and it also occurs in coatings on the surface gravel of unpaved roads. The 53 Cr/ 52 Cr ratio measured in KEU, reported in delta 53 Cr notation, was in the restricted range delta 53 Cr = - 0.031 +/- 0.057 %o ; on the contrary, the delta 53 Cr in water varied between + 1.581 +/- 0.038 %o and + 3.261 +/- 0.191 %o , indicating the reduction of Cr(VI) after the pristine oxidative mobilization. The risk -based soil screening levels (SSLs) for total Cr are well above the concentration measured in soil for all the exposure pathways. On the contrary, the SSL for Cr(VI)indicates that soil contamination poses health hazards for residents

Cysteine String Protein Regulates G Protein Modulation of N-Type Calcium Channels

AbstractCysteine string proteins (CSPs) are secretory vesicle proteins bearing a “J domain” and a palmitoylated cysteine-rich “string” region that are critical for neurotransmitter release. The precise role of CSP in neurotransmission is controversial. Here, we demonstrate a novel interaction between CSP, receptor-coupled trimeric GTP binding proteins (G proteins), and N-type Ca2+ channels. Gα subunits interact with the J domain of CSP in an ATP-dependent manner; in contrast, Gβγ subunits interact with the C terminus of CSP in both the presence and absence of ATP. The interaction of CSP with both G proteins and N-type Ca2+ channels results in a tonic G protein inhibition of the channels. In view of the crucial importance of N-type Ca2+ channels in presynaptic vesicle release, our data attribute a key role to CSP in the fine tuning of neurotransmission

Fluctuation relations in non-equilibrium stationary states of Ising models

Fluctuation relations for the entropy production in non equilibrium stationary states of Ising models are investigated by Monte Carlo simulations. Systems in contact with heat baths at two different temperatures or subject to external driving will be studied. In the first case, by considering different kinetic rules and couplings with the baths, the behavior of the probability distributions of the heat exchanged in a time $\tau$ with the thermostats, both in the disordered and in the low temperature phase, are discussed. The fluctuation relation is always verified in the large $\tau$ limit and deviations from linear response theory are observed. Finite-$\tau$ corrections are shown to obey a scaling behavior. In the other case the system is in contact with a single heat bath but work is done by shearing it. Also for this system the statistics collected for the mechanical work shows the validity of the fluctuation relation and preasymptotic corrections behave analogously to the case with two baths.Comment: 9 figure

Scanning mutagenesis of the I-II loop of the Cav2.2 calcium channel identifies residues Arginine 376 and Valine 416 as molecular determinants of voltage dependent G protein inhibition

Direct interaction with the β subunit of the heterotrimeric G protein complex causes voltage-dependent inhibition of N-type calcium channels. To further characterize the molecular determinants of this interaction, we performed scanning mutagenesis of residues 372-387 and 410-428 of the N-type channel α1 subunit, in which individual residues were replaced by either alanine or cysteine. We coexpressed wild type Gβ1γ2 subunits with either wild type or point mutant N-type calcium channels, and voltage-dependent, G protein-mediated inhibition of the channels (VDI) was assessed using patch clamp recordings. The resulting data indicate that Arg376 and Val416 of the α1 subunit, residues which are surface-exposed in the presence of the calcium channel β subunit, contribute significantly to the functional inhibition by Gβ1. To further characterize the roles of Arg376 and Val416 in this interaction, we performed secondary mutagenesis of these residues, coexpressing the resulting mutants with wild type Gβ1γ2 subunits and with several isoforms of the auxiliary β subunit of the N-type channel, again assessing VDI using patch clamp recordings. The results confirm the importance of Arg376 for G protein-mediated inhibition and show that a single amino acid substitution to phenylalanine drastically alters the abilities of auxiliary calcium channel subunits to regulate G protein inhibition of the channel

Chaotic Hypothesis, Fluctuation Theorem and singularities

The chaotic hypothesis has several implications which have generated interest in the literature because of their generality and because a few exact predictions are among them. However its application to Physics problems requires attention and can lead to apparent inconsistencies. In particular there are several cases that have been considered in the literature in which singularities are built in the models: for instance when among the forces there are Lennard-Jones potentials (which are infinite in the origin) and the constraints imposed on the system do not forbid arbitrarily close approach to the singularity even though the average kinetic energy is bounded. The situation is well understood in certain special cases in which the system is subject to Gaussian noise; here the treatment of rather general singular systems is considered and the predictions of the chaotic hypothesis for such situations are derived. The main conclusion is that the chaotic hypothesis is perfectly adequate to describe the singular physical systems we consider, i.e. deterministic systems with thermostat forces acting according to Gauss' principle for the constraint of constant total kinetic energy (``isokinetic Gaussian thermostats''), close and far from equilibrium. Near equilibrium it even predicts a fluctuation relation which, in deterministic cases with more general thermostat forces (i.e. not necessarily of Gaussian isokinetic nature), extends recent relations obtained in situations in which the thermostatting forces satisfy Gauss' principle. This relation agrees, where expected, with the fluctuation theorem for perfectly chaotic systems. The results are compared with some recent works in the literature.Comment: 7 pages, 1 figure; updated to take into account comments received on the first versio

Tuning the Correlation Decay in the Resistance Fluctuations of Multi-Species Networks

A new network model is proposed to describe the $1/f^\alpha$ resistance noise in disordered materials for a wide range of $\alpha$ values ($0< \alpha < 2$). More precisely, we have considered the resistance fluctuations of a thin resistor with granular structure in different stationary states: from nearly equilibrium up to far from equilibrium conditions. This system has been modelled as a network made by different species of resistors, distinguished by their resistances, temperature coefficients and by the energies associated with thermally activated processes of breaking and recovery. The correlation behavior of the resistance fluctuations is analyzed as a function of the temperature and applied current, in both the frequency and time domains. For the noise frequency exponent, the model provides $0< \alpha < 1$ at low currents, in the Ohmic regime, with $\alpha$ decreasing inversely with the temperature, and $1< \alpha <2$ at high currents, in the non-Ohmic regime. Since the threshold current associated with the onset of nonlinearity also depends on the temperature, the proposed model qualitatively accounts for the complicate behavior of $\alpha$ versus temperature and current observed in many experiments. Correspondingly, in the time domain, the auto-correlation function of the resistance fluctuations displays a variety of behaviors which are tuned by the external conditions.Comment: 26 pages, 16 figures, Submitted to JSTAT - Special issue SigmaPhi200