1 research outputs found
Enhanced Biomass-Derived Glycerol Conversion to Syngas in the CO<sub>2</sub> Reforming Process: Influence of the Nickel Loading Method on Physicochemical Properties and Catalytic Performance
In
the current study, renewable syngas production from
glycerol
has been investigated through a catalytic dry reforming process using
the Ni/CaO·Al2O3 catalyst. Calcium aluminate
support has been synthesized via a one-step sol–gel technique.
The active metal of Ni attached to the CaO·Al2O3 is supported by wet impregnation, simultaneous sol–gel,
and EDTA-assisted impregnation. Investigation of different methods’
impact on Ni species attachment onto carrier revealed that the EDTA-assisted
impregnation method improves the reducibility catalytic activity (57%
at 750 °C) of the catalyst in the dry reforming of glycerol (dry-RG)
process. It also affects carbon formation on the catalyst surface.
Besides, the impact of Ni content (5–20 wt %) in the catalyst
has been evaluated. Increasing the nickel loading amount increased
the active phase’s reducibility and reduced the pore size.
Ni loading experiments’ results indicate that glycerol conversion
improves with increasing Ni loading up to 10 wt %, impregnated by
chelated Ni species [Ni (EDTA)2–] onto calcium aluminate
support. Based on the characterization results, the impact of the
nickel loading method and amount on the dry-RG reaction was discussed