20,067 research outputs found
Achieving Information Integration in Supply Chain Management Through E-Hubs: Concepts and Analysis
While supply chain integration is achieved at three levels: information, resources and organization, the emphasis of the paper is placed on how information integration can be achieved through B2B e-hubs. After reviewing how e-hubs have evolved since its inception, we examine three groups of e-hubs classified by supply chain processes, namely procurement, transportation and customer relationship management, then a value-gap analysis is performed to identify the values added by the e-hubs and their potential gaps and limitations. Finally, we present a framework for integrating existing e-hubs in order to expand their functionality to provide a better solution to supply chain integration
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Long-term stability studies of a semiconductor photoelectrode in three-electrode configuration
Improving the stability of semiconductor materials is one of the major challenges for sustainable and economic photoelectrochemical water splitting. N-terminated GaN nanostructures have emerged as a practical protective layer for conventional high efficiency but unstable Si and III-V photoelectrodes due to their near-perfect conduction band-alignment, which enables efficient extraction of photo-generated electrons, and N-terminated surfaces, which protects against chemical and photo-corrosion. Here, we demonstrate that Pt-decorated GaN nanostructures on an n+-p Si photocathode can exhibit an ultrahigh stability of 3000 h (i.e., over 500 days for usable sunlight ∼5.5 h per day) at a large photocurrent density (>35 mA cm-2) in three-electrode configuration under AM 1.5G one-sun illumination. The measured applied bias photon-to-current efficiency of 11.9%, with an excellent onset potential of ∼0.56 V vs. RHE, is one of the highest values reported for a Si photocathode under AM 1.5G one-sun illumination. This study provides a paradigm shift for the design and development of semiconductor photoelectrodes for PEC water splitting: stability is no longer limited by the light absorber, but rather by co-catalyst particles
On the Toda Lattice Equation with Self-Consistent Sources
The Toda lattice hierarchy with self-consistent sources and their Lax
representation are derived. We construct a forward Darboux transformation (FDT)
with arbitrary functions of time and a generalized forward Darboux
transformation (GFDT) for Toda lattice with self-consistent sources (TLSCS),
which can serve as a non-auto-Backlund transformation between TLSCS with
different degrees of sources. With the help of such DT, we can construct many
type of solutions to TLSCS, such as rational solution, solitons, positons,
negetons, and soliton-positons, soliton-negatons, positon-negatons etc., and
study properties and interactions of these solutions.Comment: 20 page
Classical Poisson structures and r-matrices from constrained flows
We construct the classical Poisson structure and -matrix for some finite
dimensional integrable Hamiltonian systems obtained by constraining the flows
of soliton equations in a certain way. This approach allows one to produce new
kinds of classical, dynamical Yang-Baxter structures. To illustrate the method
we present the -matrices associated with the constrained flows of the
Kaup-Newell, KdV, AKNS, WKI and TG hierarchies, all generated by a
2-dimensional eigenvalue problem. Some of the obtained -matrices depend only
on the spectral parameters, but others depend also on the dynamical variables.
For consistency they have to obey a classical Yang-Baxter-type equation,
possibly with dynamical extra terms.Comment: 16 pages in LaTe
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Development of Materials Resistant to Metal Dusting Degradation.
Metal dusting corrosion has been a serious problem in the petroleum and petrochemical industries, such as reforming and syngas production systems. This form of deterioration has led to worldwide material loss for 50 years. For the past three years, we have studied the mechanism of metal dusting for Fe- and Ni-base alloys. In this report, we present a correlation between the weight loss and depth of pits that form in Ni-base alloys. Nickel-base alloys were also tested at 1 and 14.8 atm (210 psi), in a high carbon activity environment. Higher system pressure was found to accelerate corrosion in most Ni-base alloys. To reduce testing time, a pre-pitting method was developed. Mechanical scratches on the alloy surface led to fast metal dusting corrosion. We have also developed preliminary data on the performance of weldments of several Ni-base alloys in a metal dusting environment. Finally, Alloy 800 tubes and plates used in a reformer plant were examined by scanning electron microscopy, energy dispersive X-ray, and Raman spectroscopy. The oxide scale on the surface of the Alloy 800 primarily consists of Fe{sub 1+x}Cr{sub 2-X}O{sub 4} spinel phase with high Fe content. Carbon can diffuse through this oxide scale. It was discovered that the growth of metal dusting pits could be stopped by means of a slightly oxidized alloy surface. This leads to a new way to solve metal dusting problem
Spatial Features of Urban Expansion in Vietnam Based on Long-Term Nighttime Lights Data
As a developing country, Vietnam has experienced rapid economic development since the 21st century. It is therefore becoming increasingly important to understand its spatial pattern of urban expansion. However, the key challenge in this endeavor lies in the lack of national accounting data for the sub-administrative divisions of Vietnam at the national level, especially longitudinal data over a long time series. The nighttime lights (NTL) data can objectively reflect the scope and intensity of human development and construction in urban built-up areas, which can effectively support the empirical analysis of the urban expansion process in Vietnam. This paper uses the intercalibration model to correct and fit the long time series of DMSP/OLS and VIIRS/NPP NTL data. Based on this, the data for the urban built areas of Vietnam from 2000 to 2018 are further extracted. The results are as follows. (1) The main urban expansion in Vietnam is concentrated in the southern Mekong Delta and the northern Red River Delta, represented by Ho Chi Minh City and Hanoi City, respectively. (2) Vietnam’s urban NTL has significant high–high clustering characteristics in the north-south delta regions. The main urban expansion hotspots were concentrated around Ho Chi Minh City before 2012, the northern region represented by Hanoi City was gradually transformed into a critical area that gathering urban expansion hotspots after 2012. (3) The cities with significant influence and high coupling degree of industrialization and globalization on the urbanization of Vietnam are concentrated in Ho Chi Minh City, Hanoi, and some northern delta provinces, showing that the impact of industrialization and globalization on urbanization in Vietnam is still limited to some regions. In addition, the results show that the size of the population and the level of industrialization are the main drivers of urban expansion in Vietnam, while the level of foreign investment shows little significance. The results are helpful for promoting the application of long time series NTL data in urban expansion and for further analyzing the urban pattern changes in Vietnam and the influencing factors behind them
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Study of metal dusting phenomenon and development of materials resistant to metal dusting. Final report.
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