Two-phase flow and oxygen transport in the perforated gas diffusion layer of proton exchange membrane fuel cell

Liquid water transport in perforated gas diffusion layers (GDLs)is numerically investigated using a three-dimensional (3D)two-phase volume of fluid (VOF)model and a stochastic reconstruction model of GDL microstructures. Different perforation depths and diameters are investigated, in comparison with the GDL without perforation. It is found that perforation can considerably reduce the liquid water level inside a GDL. The perforation diameter (D = 100 μm)and the depth (H = 100 μm)show pronounced effect. In addition, two different perforation locations, i.e. the GDL center and the liquid water break-through point, are investigated. Results show that the latter perforation location works more efficiently. Moreover, the perforation perimeter wettability is studied, and it is found that a hydrophilic region around the perforation further reduces the water saturation. Finally, the oxygen transport in the partially-saturated GDL is studied using an oxygen diffusion model. Results indicate that perforation reduces the oxygen diffusion resistance in GDLs and improves the oxygen concentration at the GDL bottom up to 101% (D = 100 μm and H = 100 μm)

Alternative statistical-mechanical descriptions of decaying two-dimensional turbulence in terms of "patches" and "points"

Numerical and analytical studies of decaying, two-dimensional (2D) Navier-Stokes (NS) turbulence at high Reynolds numbers are reported. The effort is to determine computable distinctions between two different formulations of maximum entropy predictions for the decayed, late-time state. Both formulations define an entropy through a somewhat ad hoc discretization of vorticity to the "particles" of which statistical mechanical methods are employed to define an entropy, before passing to a mean-field limit. In one case, the particles are delta-function parallel "line" vortices ("points" in two dimensions), and in the other, they are finite-area, mutually-exclusive convected "patches" of vorticity which in the limit of zero area become "points." We use time-dependent, spectral-method direct numerical simulation of the Navier-Stokes equations to see if initial conditions which should relax to different late-time states under the two formulations actually do so.Comment: 21 pages, 24 figures: submitted to "Physics of Fluids

Sudden stoppage of rotor in a thermally driven rotary motor made from double-walled carbon nanotubes

In a thermally driven rotary motor made from double-walled carbon nanotubes, the rotor (inner tube) can be actuated to rotate within the stator (outer tube) when the environmental temperature is high enough. A sudden stoppage of the rotor can occur when the inner tube has been actuated to rotate at a stable high speed. To find the mechanisms of such sudden stoppages, eight motor models with the same rotor but different stators are built and simulated in the canonical NVT ensembles. Numerical results demonstrate that the sudden stoppage of the rotor occurs when the difference between radii is near 0.34 nm at a high environmental temperature. A smaller difference between radii does not imply easier activation of the sudden rotor stoppage. During rotation, the positions and electron density distribution of atoms at the ends of the motor show that a sp(1) bonded atom on the rotor is attracted by the sp(1) atom with the biggest deviation of radial position on the stator, after which they become two sp(2) atoms. The strong bond interaction between the two atoms leads to the loss of rotational speed of the rotor within 1 ps. Hence, the sudden stoppage is attributed to two factors: the deviation of radial position of atoms at the stator's ends and the drastic thermal vibration of atoms on the rotor in rotation. For a stable motor, sudden stoppage could be avoided by reducing deviation of the radial position of atoms at the stator's ends. A nanobrake can be, thus, achieved by adjusting a sp(1) atom at the ends of stator to stop the rotation of rotor quickly.The authors are grateful for financial support from the National Natural-Science-Foundation of China (Grant Nos. 50908190, 11372100)

Automated classification of coronary plaque calcification in OCT pullbacks with 3D deep neural networks

Significance: Detection and characterization of coronary atherosclerotic plaques often need reviews of a large number of optical coherence tomography (OCT) imaging slices to make a clinical decision. However, it is a challenge to manually review all the slices and consider the interrelationship between adjacent slices. Approach: Inspired by the recent success of deep convolutional network on the classification of medical images, we proposed a ResNet-3D network for classification of coronary plaque calcification in OCT pullbacks. The ResNet-3D network was initialized with a trained ResNet-50 network and a three-dimensional convolution filter filled with zeros padding and non-zeros padding with a convolutional filter. To retrain ResNet-50, we used a dataset of ∼4860 OCT images, derived by 18 entire pullbacks from different patients. In addition, we investigated a two-phase training method to address the data imbalance. For an improved performance, we evaluated different input sizes for the ResNet-3D network, such as 3, 5, and 7 OCT slices. Furthermore, we integrated all ResNet-3D results by majority voting. Results: A comparative analysis proved the effectiveness of the proposed ResNet-3D networks against ResNet-2D network in the OCT dataset. The classification performance (F1-scores  =  94  %   for non-zeros padding and F1-score  =  96  %   for zeros padding) demonstrated the potential of convolutional neural networks (CNNs) in classifying plaque calcification. Conclusions: This work may provide a foundation for further work in extending the CNN to voxel segmentation, which may lead to a supportive diagnostic tool for assessment of coronary plaque vulnerability

Response of internal solitary waves to tropical storm Washi in the northwestern South China Sea

Based on in-situ time series data from an array of temperature sensors and an acoustic Doppler current profiler on the continental shelf of the northwestern South China Sea, a sequence of internal solitary waves (ISWs) were observed during the passage of tropical storm Washi in the summer of 2005, which provided a unique opportunity to investigate the ISW response to the tropical cyclone. The passing tropical storm is found to play an important role in affecting the stratification structure of the water column, and consequently leading to significant variability in the propagating features of the ISWs, such as the polarity reversal and amplitude variations of the waves. The response of the ISWs to Washi can be divided into two stages, direct forcing by the strong wind (during the arrival of Washi) and remote forcing via the near-inertial internal waves induced by the tropical storm (after the passage of Washi). The field observations as well as a theoretical analysis suggest that the variations of the ISWs closely coincide with the changing stratification structure and shear currents in accompanied by the typhoon wind and near-inertial waves. This study presents the first observations and analysis of the ISW response to the tropical cyclone in the South China Sea