Stability of monolayers and bilayers in a copolymer-homopolymer blend model

We study the stability of layered structures in a variational model for diblock copolymer-homopolymer blends. The main step consists of calculating the first and second derivative of a sharp-interface Ohta-Kawasaki energy for straight mono- and bilayers. By developing the interface perturbations in a Fourier series we fully characterise the stability of the structures in terms of the energy parameters. In the course of our computations we also give the Green's function for the Laplacian on a periodic strip and explain the heuristic method by which we found it.Comment: 40 pages, 34 Postscript figures; second version has some minor corrections; to appear in "Interfaces and Free Boundaries

Copolymer-homopolymer blends: global energy minimisation and global energy bounds

We study a variational model for a diblock-copolymer/homopolymer blend. The energy functional is a sharp-interface limit of a generalisation of the Ohta-Kawasaki energy. In one dimension, on the real line and on the torus, we prove existence of minimisers of this functional and we describe in complete detail the structure and energy of stationary points. Furthermore we characterise the conditions under which the minimisers may be non-unique. In higher dimensions we construct lower and upper bounds on the energy of minimisers, and explicitly compute the energy of spherically symmetric configurations.Comment: 31 pages, 6 Postscript figures; to be published in Calc. Var. Partial Differential Equations. Version history: Changes in v2 w.r.t v1 only concern metadata. V3 contains some minor revisions and additions w.r.t. v2. V4 corrects a confusing typo in one of the formulas of the appendix. V5 is the definitive version that will appear in prin

The weakening relationship between the Impact Factor and papers' citations in the digital age

Historically, papers have been physically bound to the journal in which they were published but in the electronic age papers are available individually, no longer tied to their respective journals. Hence, papers now can be read and cited based on their own merits, independently of the journal's physical availability, reputation, or Impact Factor. We compare the strength of the relationship between journals' Impact Factors and the actual citations received by their respective papers from 1902 to 2009. Throughout most of the 20th century, papers' citation rates were increasingly linked to their respective journals' Impact Factors. However, since 1990, the advent of the digital age, the strength of the relation between Impact Factors and paper citations has been decreasing. This decrease began sooner in physics, a field that was quicker to make the transition into the electronic domain. Furthermore, since 1990, the proportion of highly cited papers coming from highly cited journals has been decreasing, and accordingly, the proportion of highly cited papers not coming from highly cited journals has also been increasing. Should this pattern continue, it might bring an end to the use of the Impact Factor as a way to evaluate the quality of journals, papers and researchers.Comment: 14 pages, 5 figure

Coarse-grained simulation of polymer translocation through an artificial nanopore

The translocation of a macromolecule through a nanometer-sized pore is an interesting process with important applications in the development of biosensors for single--molecule analysis and in drug delivery and gene therapy. We have carried out a molecular dynamics simulation study of electrophoretic translocation of a charged polymer through an artificial nanopore to explore the feasibility of semiconductor--based nanopore devices for ultra--fast DNA sequencing. The polymer is represented by a simple bead--spring model designed to yield an appropriate coarse-grained description of the phosphate backbone of DNA in salt--free aqueous solution. A detailed analysis of single translocation event is presented to assess whether the passage of individual ions through the pore can be detected by a nanoscale field--effect transistor by measuring variations in electrostatic potential during polymer translocation. We find that it is possible to identify single events corresponding to the passage of counterions through the pore, but that discrimination of individual ions on the polymer chain based on variations in electrostatic potential is problematic. Several distinct stages in the translocation process are identified, characterized by changes in polymer conformation and by variations in the magnitude and direction of the internal electric field induced by the fluctuating charge distribution. The dependence of the condensed fraction of counterions on Bjerrum length leads to significant changes in polymer conformation, which profoundly affect the dynamics of electrophoresis and translocation.Comment: 37 pages Revtex, 11 postscript figure

The effect of dark strings on semilocal strings

Dark strings have recently been suggested to exist in new models of dark matter that explain the excessive electronic production in the galaxy. We study the interaction of these dark strings with semilocal strings which are solutions of the bosonic sector of the Standard Model in the limit $\sin^2\theta_{\rm w}=1$, where $\theta_{\rm w}$ is the Weinberg angle. While embedded Abelian-Higgs strings exist for generic values of the coupling constants, we show that semilocal solutions with non-vanishing condensate inside the string core exist only above a critical value of the Higgs to gauge boson mass ratio when interacting with dark strings. Above this critical value, which is greater than unity, the energy per unit length of the semilocal-dark string solutions is always smaller than that of the embedded Abelian-Higgs-dark string solutions and we show that Abelian-Higgs-dark strings become unstable above this critical value. Different from the non-interacting case, we would thus expect semilocal strings to be stable for values of the Higgs to gauge boson mass ratio larger than unity. Moreover, the one-parameter family of solutions present in the non-interacting case ceases to exist when semilocal strings interact with dark strings.Comment: 16 pages including 6 figures; stability analysis adde