Highly Efficient Synthesis of Functionalizable Polymers from a CO₂/1,3-Butadiene-Derived Lactone

Making polymers from CO₂ and olefins has been long sought and is of particular significance for chemical utilizations of CO₂. Herein, high molecular-weight polymers with 29 wt % CO₂ were obtained by polymerizing a δ-lactone (<i><b>L</b></i>) synthesized from a C–C coupling reaction between CO₂ and 1,3-butadiene, an economical large-volume chemical that can also be derived from top biomass platform chemicals. Although <i><b>L</b></i> has been known for many years, little was investigated in its polymerization. We found that <i><b>L</b></i>’s polymerizability can be vitalized upon simply heating in the presence of O₂. The polymerization is additive/solvent-free with abundant preserved olefins and up to full monomer conversion, providing a convenient, economical, and scalable avenue to obtain CO₂-derived polymers with potentially tailorable properties via the readily modifiable olefins

Additional file 7 of Systematic comparation of the biological and transcriptomic landscapes of human amniotic mesenchymal stem cells under serum-containing and serum-free conditions

Additional file 7. Table S5. Genetic variations in hAMSCs under SC and SF conditions

Additional file 6 of Systematic comparation of the biological and transcriptomic landscapes of human amniotic mesenchymal stem cells under serum-containing and serum-free conditions

Additional file 6. Table S4. FPKM values of DEGs in hAMSCs under SC and SF conditions

Additional file 3 of Systematic comparation of the biological and transcriptomic landscapes of human amniotic mesenchymal stem cells under serum-containing and serum-free conditions

Additional file 3. Figure S3. Comparation of the inhibitory effects of hAMSCs pretreated in SC and SF conditions upon T cells

Additional file 5 of Systematic comparation of the biological and transcriptomic landscapes of human amniotic mesenchymal stem cells under serum-containing and serum-free conditions

Additional file 5. The details accompanied with the main manuscript including Additional Figure Legends for Figure S1-S4, Additional Table S1-S3, Additional References were listed

Additional file 1 of Uncovering the cellular and omics characteristics of natural killer cells in the bone marrow microenvironment of patients with acute myeloid leukemia

Additional file 1: Table S1. The detail data of AML. Table S2. The cytokines used in this study. Table S3. Antibodies for flow cytometry assay in the study