1 research outputs found
Immobilizing Water into Crystal Lattice of Calcium Sulfate for its Separation from Water-in-Oil Emulsion
This work report
a facile approach to efficiently separate surfactant-stabilized
water (droplet diameter of around 2.0 ÎĽm) from water-in-oil
emulsion via converting liquid water into solid crystal water followed
by removal with centrifugation. The liquid–solid conversion
is achieved through the solid-to-solid phase transition of calcium
sulfate hemihydrate (CaSO<sub>4</sub>. 0.5H<sub>2</sub>O, HH) to dihydrate
(CaSO<sub>4</sub>·2H<sub>2</sub>O, DH), which could immobilize
the water into crystal lattice of DH. For emulsion of 10 mg mL<sup>–1</sup> water, the immobilization-separation process using
polycrystalline HH nanoellipsoids could remove 95.87 wt % water at
room temperature. The separation efficiency can be further improved
to 99.85 wt % by optimizing the HH dosage, temperature, HH size and
crystalline structure. Property examination of the recycled oil confirms
that our method has neglectable side-effect on oil quality. The byproduct
DH was recycled to alpha-HH (a valuable cemetitious material widely
used in construction and binding field), which minimizes the risk
of secondary pollution and promotes the practicality of our method.
With the high separation efficiency, the “green” feature
and the recyclability of DH byproduct, the HH-based immobilization-separation
approach is highly promising in purifying oil with undesired water
contamination