50,829 research outputs found
Purification of Curcumin from Ternary Extract-Similar Mixtures of Curcuminoids in a Single Crystallization Step
Crystallization-based separation of curcumin from ternary mixtures of curcuminoids having compositions comparable to commercial extracts was studied experimentally. Based on solubility and supersolubility data of both, pure curcumin and curcumin in presence of the two major impurities demethoxycurcumin (DMC) and bis(demethoxy)curcumin (BDMC), seeded cooling crystallization procedures were derived using acetone, acetonitrile and 50/50 (wt/wt) mixtures of acetone/2-propanol and acetone/acetonitrile as solvents. Starting from initial curcumin contents of 67–75% in the curcuminoid mixtures single step crystallization processes provided crystalline curcumin free of BDMC at residual DMC contents of 0.6–9.9%. Curcumin at highest purity of 99.4% was obtained from a 50/50 (wt/wt) acetone/2-propanol solution in a single crystallization step. It is demonstrated that the total product yield can be significantly enhanced via addition of water, 2-propanol and acetonitrile as anti-solvents at the end of a cooling crystallization process
Optical spectroscopy study on single crystalline LaFeAsO
Millimeter-sized single crystals of LaFeAsO were grown from NaAs flux and the
in-plane optical properties were studied over a wide frequency range. A sizable
electronic correlation effect was indicated from the analysis of the
free-carrier spectral weight. With decreasing temperature from 300 K, we
observed a continuous suppression of the spectral weight near 0.6 eV. But a
spin-density-wave gap formation at lower energy scale was seen only in the
broken-symmetry state. We elaborate that both the itinerancy and local spin
interactions of Fe\emph{3d} electrons are present for the FeAs-based systems;
however, the establishment of the long-range magnetic order at low temperature
has a dominantly itinerant origin.Comment: 4 figures, 5 page
New Production Mechanism of Neutral Higgs Bosons with Right scalar tau neutrino as the LSP
Motived by the neutrino oscillation data, we consider the lightest tau
sneutrino (which is mostly the right tau sneutrino) to be
the lightest supersymmetric particle (LSP) in the framework of the minimal
supersymmetric Standard Model. Both the standard and the non-standard trilinear
scalar coupling terms are included for the right tau sneutrino interactions.
The decay branching ratio of
can become so large that the production rate of the lightest neutral Higgs
boson () can be largely enhanced at electron or hadron colliders, either
from the direct production of or from the decay of
charginos, neutralinos, sleptons, and the cascade decay of squarks and gluinos,
etc. Furthermore, because of the small LSP annihilation rate, can be a good candidate for cold dark matter.Comment: 11 pages, RevTex, 3 eps figures. We clarify the theoretical framework
of this study, with a note added in the end, and correct an equation, with
updated figure
The magnetoresistance and Hall effect in CeFeAsO: a high magnetic field study
The longitudinal electrical resistivity and the transverse Hall resistivity
of CeFeAsO are simultaneously measured up to a magnetic field of 45T using the
facilities of pulsed magnetic field at Los Alamos. Distinct behaviour is
observed in both the magnetoresistance Rxx({\mu}0H) and the Hall resistance
Rxy({\mu}0H) while crossing the structural phase transition at Ts \approx 150K.
At temperatures above Ts, little magnetoresistance is observed and the Hall
resistivity follows linear field dependence. Upon cooling down the system below
Ts, large magnetoresistance develops and the Hall resistivity deviates from the
linear field dependence. Furthermore, we found that the transition at Ts is
extremely robust against the external magnetic field. We argue that the
magnetic state in CeFeAsO is unlikely a conventional type of spin-density-wave
(SDW).Comment: 4 pages, 3 figures SCES2010, To appear in J. Phys.: Conf. Ser. for
SCES201
A comparative study of optical/ultraviolet variability of narrow-line Seyfert 1 and broad-line Seyfert 1 active galactic nuclei
The ensemble optical/ultraviolet variability of narrow-line Seyfert 1 (NLS1)
type active galactic nuclei (AGNs) is investigated, based on a sample selected
from the Sloan Digital Sky Survey (SDSS) Stripe-82 region with multi-epoch
photometric scanning data. As a comparison a control sample of broad-line
Seyfert 1 (BLS1) type AGNs is also incorporated. To quantify properly the
intrinsic variation amplitudes and their uncertainties, a novel method of
parametric maximum-likelihood is introduced, that has, as we argued, certain
virtues over previously used methods. The majority of NLS1-type AGNs exhibit
significant variability on timescales from about ten days to a few years with,
however, on average smaller amplitudes compared to BLS1-type AGNs. About 20
NLS1- type AGNs showing relatively large variations are presented, that may
deserve future monitoring observations, for instance, reverberation mapping.
The averaged structure functions of variability, constructed using the same
maximumlikelihood method, show remarkable similarity in shape for the two types
of AGNs on timescales longer than about 10 days, which can be approximated by a
power-law or an exponential function. This, along with other similar
properties, such as the wavelength-dependent variability, are indicative of a
common dominant mechanism responsible for the long-term optical/UV variability
of both NLS1- and BLS1-type AGNs. Towards the short timescales, however, there
is tentative evidence that the structure function of NLS1-type AGNs continues
declining, whereas that of BLS1-type AGNs flattens with some residual
variability on timescales of days. If this can be confirmed, it may suggest
that an alternative mechanism, such as X-ray reprocessing, starts to become
dominating in BLS1-type AGNs, but not in NLS1-, on such timescales.Comment: 53 pages, 13 figures, 3 tables, accepted for pulication in A
- …