Purification of Curcumin from Ternary Extract-Similar Mixtures of Curcuminoids in a Single Crystallization Step

Crystallization-based separation of curcumin from ternary mixtures of curcuminoids having compositions comparable to commercial extracts was studied experimentally. Based on solubility and supersolubility data of both, pure curcumin and curcumin in presence of the two major impurities demethoxycurcumin (DMC) and bis(demethoxy)curcumin (BDMC), seeded cooling crystallization procedures were derived using acetone, acetonitrile and 50/50 (wt/wt) mixtures of acetone/2-propanol and acetone/acetonitrile as solvents. Starting from initial curcumin contents of 67–75% in the curcuminoid mixtures single step crystallization processes provided crystalline curcumin free of BDMC at residual DMC contents of 0.6–9.9%. Curcumin at highest purity of 99.4% was obtained from a 50/50 (wt/wt) acetone/2-propanol solution in a single crystallization step. It is demonstrated that the total product yield can be significantly enhanced via addition of water, 2-propanol and acetonitrile as anti-solvents at the end of a cooling crystallization process

Optical spectroscopy study on single crystalline LaFeAsO

Millimeter-sized single crystals of LaFeAsO were grown from NaAs flux and the in-plane optical properties were studied over a wide frequency range. A sizable electronic correlation effect was indicated from the analysis of the free-carrier spectral weight. With decreasing temperature from 300 K, we observed a continuous suppression of the spectral weight near 0.6 eV. But a spin-density-wave gap formation at lower energy scale was seen only in the broken-symmetry state. We elaborate that both the itinerancy and local spin interactions of Fe\emph{3d} electrons are present for the FeAs-based systems; however, the establishment of the long-range magnetic order at low temperature has a dominantly itinerant origin.Comment: 4 figures, 5 page

New Production Mechanism of Neutral Higgs Bosons with Right scalar tau neutrino as the LSP

Motived by the neutrino oscillation data, we consider the lightest tau sneutrino $\tilde \nu_{\tau_1}$ (which is mostly the right tau sneutrino) to be the lightest supersymmetric particle (LSP) in the framework of the minimal supersymmetric Standard Model. Both the standard and the non-standard trilinear scalar coupling terms are included for the right tau sneutrino interactions. The decay branching ratio of $\tilde \nu_{\tau_2} \to \tilde \nu_{\tau_1}+ h^0$ can become so large that the production rate of the lightest neutral Higgs boson ($h^0$) can be largely enhanced at electron or hadron colliders, either from the direct production of $\tilde \nu_{\tau_2}$ or from the decay of charginos, neutralinos, sleptons, and the cascade decay of squarks and gluinos, etc. Furthermore, because of the small LSP annihilation rate, $\tilde \nu_{\tau_1}$ can be a good candidate for cold dark matter.Comment: 11 pages, RevTex, 3 eps figures. We clarify the theoretical framework of this study, with a note added in the end, and correct an equation, with updated figure

The magnetoresistance and Hall effect in CeFeAsO: a high magnetic field study

The longitudinal electrical resistivity and the transverse Hall resistivity of CeFeAsO are simultaneously measured up to a magnetic field of 45T using the facilities of pulsed magnetic field at Los Alamos. Distinct behaviour is observed in both the magnetoresistance Rxx({\mu}0H) and the Hall resistance Rxy({\mu}0H) while crossing the structural phase transition at Ts \approx 150K. At temperatures above Ts, little magnetoresistance is observed and the Hall resistivity follows linear field dependence. Upon cooling down the system below Ts, large magnetoresistance develops and the Hall resistivity deviates from the linear field dependence. Furthermore, we found that the transition at Ts is extremely robust against the external magnetic field. We argue that the magnetic state in CeFeAsO is unlikely a conventional type of spin-density-wave (SDW).Comment: 4 pages, 3 figures SCES2010, To appear in J. Phys.: Conf. Ser. for SCES201

A comparative study of optical/ultraviolet variability of narrow-line Seyfert 1 and broad-line Seyfert 1 active galactic nuclei

The ensemble optical/ultraviolet variability of narrow-line Seyfert 1 (NLS1) type active galactic nuclei (AGNs) is investigated, based on a sample selected from the Sloan Digital Sky Survey (SDSS) Stripe-82 region with multi-epoch photometric scanning data. As a comparison a control sample of broad-line Seyfert 1 (BLS1) type AGNs is also incorporated. To quantify properly the intrinsic variation amplitudes and their uncertainties, a novel method of parametric maximum-likelihood is introduced, that has, as we argued, certain virtues over previously used methods. The majority of NLS1-type AGNs exhibit significant variability on timescales from about ten days to a few years with, however, on average smaller amplitudes compared to BLS1-type AGNs. About 20 NLS1- type AGNs showing relatively large variations are presented, that may deserve future monitoring observations, for instance, reverberation mapping. The averaged structure functions of variability, constructed using the same maximumlikelihood method, show remarkable similarity in shape for the two types of AGNs on timescales longer than about 10 days, which can be approximated by a power-law or an exponential function. This, along with other similar properties, such as the wavelength-dependent variability, are indicative of a common dominant mechanism responsible for the long-term optical/UV variability of both NLS1- and BLS1-type AGNs. Towards the short timescales, however, there is tentative evidence that the structure function of NLS1-type AGNs continues declining, whereas that of BLS1-type AGNs flattens with some residual variability on timescales of days. If this can be confirmed, it may suggest that an alternative mechanism, such as X-ray reprocessing, starts to become dominating in BLS1-type AGNs, but not in NLS1-, on such timescales.Comment: 53 pages, 13 figures, 3 tables, accepted for pulication in A