Synthesis of silver nanowires for highly transparent conductive films and electrochemical reduction of carbon dioxide

The traditional ITO-based transparent conductive films and electrodes have been widely applied in many fields and used in various electronics in the past decades. However, its brittle property and costly manufacturing process limit the development of ITO for next-generation electronic devices, which need the features of light weight, flexibility, and low cost. Silver nanowires have attracted considerable attention from researchers among many candidates due to their outstanding electrical, mechanical, and optical properties. Many synthesis methods of AgNWs have been demonstrated recently, but there are still some parameters that are unclear and need further investigations. In this thesis, one-step solvothermal synthesis of AgNWs has been studied and explored. AgNWs with a high aspect ratio (~2000) were successfully obtained by using this method. The morphology of AgNWs was significantly affected when tuning the different factors, including the heating temperature of PVP dissolution, the molar ratio of PVP/AgNO3, the molecular rate of PVP, and the concentration of ionic assistants. Moreover, another latest modified polyol method, the Maillard reaction process, has also been introduced and researched in this thesis. The ultra-long AgNWs (~100 μm) were successfully generated through the Millard reaction method using ammonium chloride and glucose as reacting agents of MRPs. Effects of experimental parameters such as reaction time and pressure environment on the morphology of AgNWs have also been investigated. Besides, the extra salt additive (NaBr) was employed to see if the NW diameter would become thinner to achieve the high aspect ratio AgNWs. The NW diameter was greatly reduced when the molar ratio of NH4Cl/ NaBr was at 40:1; however, a large amount of Ag nanoparticles were generated, which could significantly affect the overall performance of AgNWs. The AgNWs-based TCFs were fabricated in this project. With the help of annealing post-treatment, TCFs with low sheet resistance (~22 Ω/sq) and high transmittance (86%) were prepared using the high aspect ratio AgNWs. In addition, the AgNWs were applied to the electrochemical reduction of CO2 to syngas and showed the potential of syngas production. Nevertheless, more factors and studies need to be carried out to improve the Faradic efficiency of syngas production

Resolving Regular Polysemy in Named Entities

Word sense disambiguation primarily addresses the lexical ambiguity of common words based on a predefined sense inventory. Conversely, proper names are usually considered to denote an ad-hoc real-world referent. Once the reference is decided, the ambiguity is purportedly resolved. However, proper names also exhibit ambiguities through appellativization, i.e., they act like common words and may denote different aspects of their referents. We proposed to address the ambiguities of proper names through the light of regular polysemy, which we formalized as dot objects. This paper introduces a combined word sense disambiguation (WSD) model for disambiguating common words against Chinese Wordnet (CWN) and proper names as dot objects. The model leverages the flexibility of a gloss-based model architecture, which takes advantage of the glosses and example sentences of CWN. We show that the model achieves competitive results on both common and proper nouns, even on a relatively sparse sense dataset. Aside from being a performant WSD tool, the model further facilitates the future development of the lexical resource

Acute kidney disease: an overview of the epidemiology, pathophysiology, and management

Acute kidney injury (AKI) increases the risk of chronic kidney disease (CKD), and AKI and CKD are seen as interconnected syndromes. Acute kidney disease (AKD) is defined as subacute damage and/or loss of kidney function occurring 7 to 90 days after AKI, during which period key interventions may be initiated to hinder the development of CKD. While AKD is usually under-recognized, it is associated with high morbidity and mortality globally. This review article aims to summarize the current knowledge concerning the epidemiology, pathophysiology, and management of AKD with the aim to develop monitoring strategies and therapeutic agents of AKD. Generally, AKD tends to occur more frequently in the elderly and those with chronic diseases, such as hypertension, diabetes mellitus, and metabolic syndrome. In addition, the severity, duration, and frequency of AKI are independent risk factors for AKD. Investigations of several mechanisms of AKD, such as renal tubular epithelium cell-cycle arrest, epigenetic change, chronic inflammation, mitochondria dysfunction, failed regeneration of tubular cells, metabolic reprogramming, and renin-angiotensin system (RAS) activation, have identified additional potential pharmacotherapy targets. Management of AKD includes prevention of repeated AKI, early and regular follow-up by a nephrologist, resumption and adjustment of essential medication, optimization of blood pressure control and nutrition management, and development of new pharmaceutical agents including RAS inhibitors. Finally, we outline a care bundle for AKD patients based on important lessons learned from studies and registries and identify the need for clinical trials of RAS inhibitors or other novel agents to impede ensuing CKD development

Metastatic Gallbladder Cancer Presenting as a Gingival Tumor and Deep Neck Infection

Gallbladder cancer has an extremely poor prognosis because it is often diagnosed at an advanced stage. We describe a 63-year-old woman who was treated 4 years previously for gallbladder cancer, with laparoscopic cholecystectomy and secondary hepatectomy after presenting with acute cholecystitis and gallbladder rupture. At her second presentation, she had a left lower gingival tumor and deep neck infection. Incision and drainage and tumor biopsies were performed, and pathology at both sites revealed adenocarcinoma. Positron emission tomography revealed other tumors in the left breast and left lower lung field, which were both proven to be adenocarcinoma by biopsy. The patient's presentation with a metastatic oral tumor was rare. Although the incidence is very low, physicians should consider the possibility of metastatic cancer in a patient with a history of cancer, who presents with new oral tumor or deep neck infection

Lexical Retrieval Hypothesis in Multimodal Context

Multimodal corpora have become an essential language resource for language science and grounded natural language processing (NLP) systems due to the growing need to understand and interpret human communication across various channels. In this paper, we first present our efforts in building the first Multimodal Corpus for Languages in Taiwan (MultiMoco). Based on the corpus, we conduct a case study investigating the Lexical Retrieval Hypothesis (LRH), specifically examining whether the hand gestures co-occurring with speech constants facilitate lexical retrieval or serve other discourse functions. With detailed annotations on eight parliamentary interpellations in Taiwan Mandarin, we explore the co-occurrence between speech constants and non-verbal features (i.e., head movement, face movement, hand gesture, and function of hand gesture). Our findings suggest that while hand gestures do serve as facilitators for lexical retrieval in some cases, they also serve the purpose of information emphasis. This study highlights the potential of the MultiMoco Corpus to provide an important resource for in-depth analysis and further research in multimodal communication studies

Exploring Affordance and Situated Meaning in Image Captions: A Multimodal Analysis

This paper explores the grounding issue regarding multimodal semantic representation from a computational cognitive-linguistic view. We annotate images from the Flickr30k dataset with five perceptual properties: Affordance, Perceptual Salience, Object Number, Gaze Cueing, and Ecological Niche Association (ENA), and examine their association with textual elements in the image captions. Our findings reveal that images with Gibsonian affordance show a higher frequency of captions containing 'holding-verbs' and 'container-nouns' compared to images displaying telic affordance. Perceptual Salience, Object Number, and ENA are also associated with the choice of linguistic expressions. Our study demonstrates that comprehensive understanding of objects or events requires cognitive attention, semantic nuances in language, and integration across multiple modalities. We highlight the vital importance of situated meaning and affordance grounding in natural language understanding, with the potential to advance human-like interpretation in various scenarios.Comment: 10 pages, 9 figure

SEISMIC ANALYSIS OF WATER SUPPLY SYSTEMS BY EARTHQUAKE SCENARIO SIMULATION

In the past decade, scenario simulation has played a more and more important role in urban earthquake hazard mitigation and emergency response. Both public and private sectors can be enhanced in terms of their seismic preparedness and operation if adequate implementation of seismic scenario simulation can be employed. Regarding water utilities, system-wide retrofit and emergency planning can be conducted to reduce the likely damage and losses prior to the occurrence of a devastating earthquake. Post-earthquake repair personnel and material dispatching, temporary water supply for affected people, emergency water supply for hospitals and fire fighting, strategies for restoration and recovery can all benefit from scenario-based analyses. In this research work, efforts were made to study and integrate pivotal technologies essential to the earthquake damage and serviceability analysis of water systems, such as seismic hazard analysis, empirical formulae for pipe repair rates, hydraulic analysis of water network system in terms of pressurized pipe flow simulation, hydraulic models for various types of pipe damages, and Monte Carlo method for the performance analysis of large and complicated systems. The water system in Yi-lan County, Taiwan was selected as a test bed for the demonstration of its seismic serviceability analysis under an M7.1 earthquake scenario

RISK OF SLEEP DISORDERS IN PATIENTS WITH DECOMPRESSION SICKNESS: A NATIONWIDE, POPULATION-BASED STUDY IN TAIWAN

Background: Decompression sickness (DCS) primarily manifests musculoskeletal pain, cutaneous manifestations, lymphatic symptoms, and neurological symptoms. DCS might affect the central nervous system and induce the stress in the patients, but few studies about the psychiatric morbidity after DCS have been conducted. This study aimed to investigate the association between DCS and the risk of developing psychiatric disorders. Subjects and methods: This study was a population-based, matched cohort design. A total of 738 enrolled patients, with 123 study subjects who had suffered from DCS, and 615 controls matched for sex and age, from the Longitudinal Health Insurance Databank from 2000-2010 in Taiwan, and selected from the National Health Insurance Research Database. After adjusting for the confounding factors, Cox proportional hazards analysis was used to compare the risk of developing psychiatric disorders during the 10 years of follow-up period. Results: Of the study subjects, 10 (8.13%) developed psychiatric disorders when compared to 35 (5.69%) in the control group. The study subjects were more likely to develop psychiatric disorders (crude hazard ratio [HR]: 2.79 (95% CI=1.37-5.69, P<0.01). After adjusting for sex, age, monthly income, urbanization level, geographic region, and comorbidities, the adjusted HR was 3.83 (95% CI=1.60-9.16, P<0.01). Sleep disorders was associated with DCS with the adjusted HR as 5.74 (95% CI=1.04-31.56, P<0.01). Hyperbaric oxygenation therapy was not associated with a lower risk of psychiatric disorders. Conclusions: Patients who suffered from DCS have a 3.8-fold risk of developing psychiatric disorders, and a 5.7-fold risk of sleep disorders. This finding is a reminder for the clinicians that a regular psychiatric follow-up might well be needed for these patients