On the Common Envelope Efficiency

In this work, we try to use the apparent luminosity versus displacement (i.e., $L_{\rm X}$ vs. $R$) correlation of high mass X-ray binaries (HMXBs) to constrain the common envelope (CE) efficiency $\alpha_{\rm CE}$, which is a key parameter affecting the evolution of the binary orbit during the CE phase. The major updates that crucial for the CE evolution include a variable $\lambda$ parameter and a new CE criterion for Hertzsprung gap donor stars, both of which are recently developed. We find that, within the framework of the standard energy formula for CE and core definition at mass $X=10$\%, a high value of $\alpha_{\rm CE}$, i.e., around 0.8-1.0, is more preferable, while $\alpha_{\rm CE}< \sim 0.4$ likely can not reconstruct the observed $L_{\rm X}$ vs. $R$ distribution. However due to an ambiguous definition for the core boundary in the literature, the used $\lambda$ here still carries almost two order of magnitude uncertainty, which may translate directly to the expected value of $\alpha_{\rm CE}$. We present the detailed components of current HMXBs and their spatial offsets from star clusters, which may be further testified by future observations of HMXB populations in nearby star-forming galaxies.Comment: 14 pages, 10 figures, 7 tables, accepted for publication in MNRA

Beyond Wigner's isobaric multiplet mass equation: Effect of charge-symmetry-breaking interaction and Coulomb polarization

The quadratic form of the isobaric multiplet mass equation (IMME), which was originally suggested by Wigner and has been generally regarded as valid, is seriously questioned by recent high-precision nuclear mass measurements. The usual resolution to this problem is to add empirically the cubic and quartic $T_z$-terms to characterize the deviations from the IMME, but finding the origin of these terms remains an unsolved difficulty. Based on a strategy beyond the Wigner's first-order perturbation, we derive explicitly the cubic and quartic $T_z$-terms. These terms are shown to be generated by the effective charge-symmetry breaking and charge-independent breaking interactions in nuclear medium combined with the Coulomb polarization effect. Calculations for the $sd$- and lower $fp$-shells explore a systematical emergence of the cubic $T_z$-term, suggesting a general deviation from the original IMME. Intriguingly, the magnitude of the deviation exhibits an oscillation-like behavior with mass number, modulated by the shell effect.Comment: 13 pages, 4 figure

Direct Observation of Photoinduced Charge Separation in Ruthenium Complex/Ni(OH)\u3csub\u3e2\u3c/sub\u3e Nanoparticle Hybrid

Ni(OH)2 have emerged as important functional materials for solar fuel conversion because of their potential as cost-effective bifunctional catalysts for both hydrogen and oxygen evolution reactions. However, their roles as photocatalysts in the photoinduced charge separation (CS) reactions remain unexplored. In this paper, we investigate the CS dynamics of a newly designed hybrid catalyst by integrating a Ru complex with Ni(OH)2 nanoparticles (NPs). Using time resolved X-ray absorption spectroscopy (XTA), we directly observed the formation of the reduced Ni metal site (~60 ps), unambiguously demonstrating CS process in the hybrid through ultrafast electron transfer from Ru complex to Ni(OH)2 NPs. Compared to the ultrafast CS process, the charge recombination in the hybrid is ultraslow (≫50 ns). These results not only suggest the possibility of developing Ni(OH)2 as solar fuel catalysts, but also represent the first time direct observation of efficient CS in a hybrid catalyst using XTA

N,N′-Bis(2,5-dichloro­phen­yl)isophthalamide

The asymmetric unit of the title compound, C20H12Cl4N2O2, contains one half-mol­ecule with a center of symmetry along a C⋯C axis of the central benzene ring. The two C=O groups adopt an anti orientation and the two amide groups are twisted away from the central benzene ring by 27.38 (3) and 27.62 (4)°. The mean planes of the dichloro-substituted benzene rings are twisted by 7.95 (4)° with respect to the benzene ring. The crystal packing is stabilized by weak inter­molecular N—H⋯O inter­actions