46 research outputs found

    The characteristics analysis of strain variation associated with Wenchuan earthquake using principal component analysis

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    Borehole strainmeters that are installed deeply into bedrock are capable of recording both continuous stress and strain measurements, and have consequently become an important tool for monitoring crustal deformation. A YRY-4 borehole strainmeter installed at the Guza Station recorded anomalous changes in borehole strain data preceding the Wenchuan earthquake on May 12, 2008 (UTC) (=8.0). We apply principal component analysis (PCA) to analyze borehole strain data from the Guza Station. The first principal component eigenvalues and eigenvectors are calculated. The fitted results of the cumulative number of anomalous eigenvalues demonstrate that an acceleration occurred approximately 4 months before the earthquake (from January 2008). The results of the combined eigenvalue and eigenvector analyses show that the spatial distribution of eigenvectors and accelerated occurrence of eigenvalue anomalies represents the stress evolution characteristics of the fault from a steady state to a sub-instability state in rock experiments. We tentatively infer that this process may also be linked to the preparation phase of a large earthquake

    TfOH- and HBF<sub>4</sub>‑Mediated Formal Cycloisomerizations and [4+3] Cycloadditions of Allene-alkynylbenzenes

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    A metal-free, TfOH (1.1 equiv)-mediated formal cycloisomerization of easily prepared allene-alkynylbenzenes to give pyrrolidines and cyclopentanes derivatives was developed. This reaction is initiated by the generation of allylic cation from allene, followed by alkyne’s reaction with the allylic cation, to give a vinyl cation, which is finally intercepted by the triflate (TfO) anion. This cycloisomerization can be further tuned to become an acid-mediated intramolecular formal [4+3] cycloaddition by using 10 equiv of TfOH (The excess acid was used to promote the Friedel–Crafts reaction of the acid-mediated cycloisomerization products). The present system can also be applied to synthesized F-incorporated products by using HBF<sub>4</sub> or Me<sub>3</sub>OBF<sub>4</sub> as the fluoro source

    TfOH- and HBF<sub>4</sub>‑Mediated Formal Cycloisomerizations and [4+3] Cycloadditions of Allene-alkynylbenzenes

    No full text
    A metal-free, TfOH (1.1 equiv)-mediated formal cycloisomerization of easily prepared allene-alkynylbenzenes to give pyrrolidines and cyclopentanes derivatives was developed. This reaction is initiated by the generation of allylic cation from allene, followed by alkyne’s reaction with the allylic cation, to give a vinyl cation, which is finally intercepted by the triflate (TfO) anion. This cycloisomerization can be further tuned to become an acid-mediated intramolecular formal [4+3] cycloaddition by using 10 equiv of TfOH (The excess acid was used to promote the Friedel–Crafts reaction of the acid-mediated cycloisomerization products). The present system can also be applied to synthesized F-incorporated products by using HBF<sub>4</sub> or Me<sub>3</sub>OBF<sub>4</sub> as the fluoro source

    Extracting borehole strain precursors associated with the Lushan earthquake through principal component analysis

    No full text
    A YRY-4 borehole strainmeter installed at the Guza Station recorded anomalous changes in borehole strain data preceding the Lushan earthquake on April 20, 2013 (UTC) ( =7.0). To identify earthquake-induced abnormal strain changes, we apply principal component analysis (PCA) for the first time to analyse the borehole strain data from the Guza Station. The first principal component eigenvalues and eigenvectors demonstrate that the anomalous days are mainly concentrated within two time periods:1) October 25-December 30, 2012, and 2) April 15-19,2013. A combined eigenvalue and eigenvector analysis reveals that the abnormal days exhibit a clustered distribution that is aggregated in the same location for both periods, intuitively indicating that there is a forceful correlation between the two anomalies. We infer that a similar process contributed to the formation of both anomalies and that these two anomalies are both earthquake precursors associated with the Lushan earthquake. These findings also indicate that the PCA approach exhibits potential for the extraction of earthquake precursor anomalies

    Evaluation of Pre-Earthquake Anomalies of Borehole Strain Network by Using Receiver Operating Characteristic Curve

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    In order to monitor temporal and spatial crustal activities associated with earthquakes, ground- and satellite-based monitoring systems have been installed in China since the 1990s. In recent years, the correlation between monitoring strain anomalies and local major earthquakes has been verified. In this study, we further evaluate the possibility of strain anomalies containing earthquake precursors by using Receiver Operating Characteristic (ROC) prediction. First, strain network anomalies were extracted in the borehole strain data recorded in Western China during 2010–2017. Then, we proposed a new prediction strategy characterized by the number of network anomalies in an anomaly window, Nano, and the length of alarm window, Talm. We assumed that clusters of network anomalies indicate a probability increase of an impending earthquake, and consequently, the alarm window would be the duration during which a possible earthquake would occur. The Area Under the ROC Curve (AUC) between true predicted rate, tpr, and false alarm rate, fpr, is measured to evaluate the efficiency of the prediction strategies. We found that the optimal strategy of short-term forecasts was established by setting the number of anomalies greater than 7 within 14 days and the alarm window at one day. The results further show the prediction strategy performs significantly better when there are frequent enhanced network anomalies prior to the larger earthquakes surrounding the strain network region. The ROC detection indicates that strain data possibly contain the precursory information associated with major earthquakes and highlights the potential for short-term earthquake forecasting

    Emission Spectral Stability Modification of Tandem Organic Light-Emitting Diodes through Controlling Charge-Carrier Migration and Outcoupling Efficiency at Intermediate/Emitting Unit Interface

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    An intermediate unit (IMU) of tandem organic light-emitting diode (TOLED) can affect the emission spectral stability because of the different charge-carrier migration and outcoupling efficiency at intermediate/emitting unit interface. In this work, an IMU consisting of carbon 60 and copper­(II) phthalocyanine, inserted between red-emitting unit and blue-emitting unit, were constructed and fabricated. We focus on the effect of the relative location of the red-emitting unit and blue-emitting unit in the device configuration on the emission spectral stability of TOLED. In the color-tunable TOLED, a maximum current efficiency of 20.4 cd/A, along with light-emitting spectra tuning from red emission at (0.63, 0.31) according to Commission Internationale de L’Eclairage coordinates at a bias of 10 V to white emission at (0.34, 0.27) at 22 V, is realized. Meanwhile, in the color-stable TOLED, a maximum current efficiency of 15.5 cd/A and a stable white emission at (0.31, 0.27) in a wide range of biases from 12 to 22 V are also obtained. This work might inspire a promising approach for the fabrication of color-tunable and color-stable OLEDs for both information display and solid-state lighting

    In Silico Comparative Transcriptome Analysis of Two Color Morphs of the Common Coral Trout (<i>Plectropomus Leopardus</i>)

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    <div><p>The common coral trout is one species of major importance in commercial fisheries and aquaculture. Recently, two different color morphs of <i>Plectropomus leopardus</i> were discovered and the biological importance of the color difference is unknown. Since coral trout species are poorly characterized at the molecular level, we undertook the transcriptomic characterization of the two color morphs, one black and one red coral trout, using Illumina next generation sequencing technologies. The study produced 55162966 and 54588952 paired-end reads, for black and red trout, respectively. <i>De novo</i> transcriptome assembly generated 95367 and 99424 unique sequences in black and red trout, respectively, with 88813 sequences shared between them. Approximately 50% of both trancriptomes were functionally annotated by BLAST searches against protein databases. The two trancriptomes were enriched into 25 functional categories and showed similar profiles of Gene Ontology category compositions. 34110 unigenes were grouped into 259 KEGG pathways. Moreover, we identified 14649 simple sequence repeats (SSRs) and designed primers for potential application. We also discovered 130524 putative single nucleotide polymorphisms (SNPs) in the two transcriptomes, supplying potential genomic resources for the coral trout species. In addition, we identified 936 fast-evolving genes and 165 candidate genes under positive selection between the two color morphs. Finally, 38 candidate genes underlying the mechanism of color and pigmentation were also isolated. This study presents the first transcriptome resources for the common coral trout and provides basic information for the development of genomic tools for the identification, conservation, and understanding of the speciation and local adaptation of coral reef fish species.</p></div

    Venn diagram showing the difference and overlap in terms of the number of putative SNPs for the transcriptome of black and red common coral trout.

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    <p>Venn diagram showing the difference and overlap in terms of the number of putative SNPs for the transcriptome of black and red common coral trout.</p

    Summary of microsatellites repeat motifs and its richness across whole transcriptome of common coral trout.

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    <p>Summary of microsatellites repeat motifs and its richness across whole transcriptome of common coral trout.</p
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