22 research outputs found

    Prevalence of obesity and abdominal obesity according to eGFR stages.

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    <p>Prevalence of obesity and abdominal obesity according to eGFR stages.</p

    Factors associated with abdominal obesity in different models (A-OR = Adjusted Odd Ratios).

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    <p>Factors associated with abdominal obesity in different models (A-OR = Adjusted Odd Ratios).</p

    Health-related and clinical characteristics of the study participants.

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    <p>Health-related and clinical characteristics of the study participants.</p

    Addition, Substitution, and Ring-Contraction Reactions of Quinones with N‑Heterocyclic Carbenes

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    Despite the common use of quinones as oxidizing agents in N-heterocyclic carbene (NHC)-based organocatalysis and transition-metal catalysis, the direct reactivity of quinones with NHCs remains underexplored. In this paper, we report the reactivity of NHCs with common <i>p</i>- and <i>o</i>-quinones, uncovering three unreported reactions involving contractions of the quinone ring that lead to push–pull furanolactone chromophores, NHC fulvalenes, and α-acylimidazolium cyclopentenone derivatives. These experiments also provide a rationale for the superior compatibility of tetra-<i>tert</i>-alkylated diphenoquinones in NHC-based oxidative transformations

    Sociodemographic characteristics of the 37,002 study participants.

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    <p>Sociodemographic characteristics of the 37,002 study participants.</p

    Flow diagram showing the study participants.

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    <p>Flow diagram showing the study participants.</p

    Addition, Substitution, and Ring-Contraction Reactions of Quinones with N‑Heterocyclic Carbenes

    No full text
    Despite the common use of quinones as oxidizing agents in N-heterocyclic carbene (NHC)-based organocatalysis and transition-metal catalysis, the direct reactivity of quinones with NHCs remains underexplored. In this paper, we report the reactivity of NHCs with common <i>p</i>- and <i>o</i>-quinones, uncovering three unreported reactions involving contractions of the quinone ring that lead to push–pull furanolactone chromophores, NHC fulvalenes, and α-acylimidazolium cyclopentenone derivatives. These experiments also provide a rationale for the superior compatibility of tetra-<i>tert</i>-alkylated diphenoquinones in NHC-based oxidative transformations

    Addition, Substitution, and Ring-Contraction Reactions of Quinones with N‑Heterocyclic Carbenes

    No full text
    Despite the common use of quinones as oxidizing agents in N-heterocyclic carbene (NHC)-based organocatalysis and transition-metal catalysis, the direct reactivity of quinones with NHCs remains underexplored. In this paper, we report the reactivity of NHCs with common <i>p</i>- and <i>o</i>-quinones, uncovering three unreported reactions involving contractions of the quinone ring that lead to push–pull furanolactone chromophores, NHC fulvalenes, and α-acylimidazolium cyclopentenone derivatives. These experiments also provide a rationale for the superior compatibility of tetra-<i>tert</i>-alkylated diphenoquinones in NHC-based oxidative transformations

    Addition, Substitution, and Ring-Contraction Reactions of Quinones with N‑Heterocyclic Carbenes

    No full text
    Despite the common use of quinones as oxidizing agents in N-heterocyclic carbene (NHC)-based organocatalysis and transition-metal catalysis, the direct reactivity of quinones with NHCs remains underexplored. In this paper, we report the reactivity of NHCs with common <i>p</i>- and <i>o</i>-quinones, uncovering three unreported reactions involving contractions of the quinone ring that lead to push–pull furanolactone chromophores, NHC fulvalenes, and α-acylimidazolium cyclopentenone derivatives. These experiments also provide a rationale for the superior compatibility of tetra-<i>tert</i>-alkylated diphenoquinones in NHC-based oxidative transformations

    Addition, Substitution, and Ring-Contraction Reactions of Quinones with N‑Heterocyclic Carbenes

    No full text
    Despite the common use of quinones as oxidizing agents in N-heterocyclic carbene (NHC)-based organocatalysis and transition-metal catalysis, the direct reactivity of quinones with NHCs remains underexplored. In this paper, we report the reactivity of NHCs with common <i>p</i>- and <i>o</i>-quinones, uncovering three unreported reactions involving contractions of the quinone ring that lead to push–pull furanolactone chromophores, NHC fulvalenes, and α-acylimidazolium cyclopentenone derivatives. These experiments also provide a rationale for the superior compatibility of tetra-<i>tert</i>-alkylated diphenoquinones in NHC-based oxidative transformations
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