7 research outputs found
Relocation of Cobalt Ions in Electrochemically Delithiated LiCoPO<sub>4</sub> Cathode Materials
Relocation of Cobalt
Ions in Electrochemically Delithiated
LiCoPO<sub>4</sub> Cathode Material
Total Synthesis and Evaluation of Vinblastine Analogues Containing Systematic Deep-Seated Modifications in the Vindoline Subunit Ring System: Core Redesign
The total synthesis of a systematic series of vinblastine
analogues
that contain deep-seated structural modifications to the core ring
system of the lower vindoline subunit is described. Complementary
to the vindoline 6,5 DE ring system, compounds with 5,5, 6,6, and
the reversed 5,6 membered DE ring systems were prepared. Both the
natural <i>cis</i> and unnatural <i>trans</i> 6,6-membered
ring systems proved accessible, with the latter representing a surprisingly
effective class for analogue design. Following FeÂ(III)-promoted coupling
with catharanthine and in situ oxidation to provide the corresponding
vinblastine analogues, their evaluation provided unanticipated insights
into how the structure of the vindoline subunit contributes to activity.
Two potent analogues (<b>81</b> and <b>44</b>) possessing
two different unprecedented modifications to the vindoline subunit
core architecture were discovered that matched the potency of the
comparison natural products and both lack the 6,7-double bond whose
removal in vinblastine leads to a 100-fold drop in activity
Exfoliated MoS<sub>2</sub> and MoSe<sub>2</sub> Nanosheets by a Supercritical Fluid Process for a Hybrid Mg–Li-Ion Battery
The ultrathin two-dimensional nanosheets
of layered transition-metal
dichalcogenides (TMDs) have attracted great interest as an important
class of materials for fundamental research and technological applications.
Solution-phase processes are highly desirable to produce a large amount
of TMD nanosheets for applications in energy conversion and energy
storage such as catalysis, electronics, rechargeable batteries, and
capacitors. Here, we report a rapid exfoliation by supercritical fluid
processing for the production of MoS<sub>2</sub> and MoSe<sub>2</sub> nanosheets. Atomic-resolution high-angle annular dark-field imaging
reveals high-quality exfoliated MoS<sub>2</sub> and MoSe<sub>2</sub> nanosheets with hexagonal structures, which retain their 2H stacking
sequence. The obtained nanosheets were tested
for their electrochemical performance in a hybrid Mg–Li-ion
battery as a proof of functionality. The MoS<sub>2</sub> and MoSe<sub>2</sub> nanosheets exhibited the specific capacities of 81 and 55
mA h g<sup>–1</sup>, respectively, at a current rate of 20
mA g<sup>–1</sup>
Unravelling the Surface Structure of MgMn<sub>2</sub>O<sub>4</sub> Cathode Materials for Rechargeable Magnesium-Ion Battery
The spinel MgMn<sub>2</sub>O<sub>4</sub>, a cathode material with
theoretical capacity of 272 mA h g<sup>–1</sup>, holds promise
for future application in high volumetric magnesium-ion batteries.
Atomic-resolution imaging of the structure of the spinel and its surface
composition would advance our understanding on its electrochemical
properties, mass, and charge transport behavior in electrodes. We
observe directly, by aberration-corrected scanning transmission electron
microscopy (STEM), the atomic structure of cubic spinel MgMn<sub>2</sub>O<sub>4</sub> for the first time. More importantly, we find that
a thin stable surface layer of rocksalt MgMnO<sub>2</sub> was grown
on a bulk cubic spinel phase. The formation of a rocksalt phase was
induced by reconstruction of the spinel phase, i.e., the insertion
of Mg into the spinel lattice together with Mg/Mn cation exchange
and Frenkel-defect-mediated relocation of Mg cations. This new structural
analysis provides a critical step toward understanding and tuning
the electrochemical performance of spinel oxide in rechargeable Mg-ion
batteries
Unravelling the Surface Structure of MgMn<sub>2</sub>O<sub>4</sub> Cathode Materials for Rechargeable Magnesium-Ion Battery
The spinel MgMn<sub>2</sub>O<sub>4</sub>, a cathode material with
theoretical capacity of 272 mA h g<sup>–1</sup>, holds promise
for future application in high volumetric magnesium-ion batteries.
Atomic-resolution imaging of the structure of the spinel and its surface
composition would advance our understanding on its electrochemical
properties, mass, and charge transport behavior in electrodes. We
observe directly, by aberration-corrected scanning transmission electron
microscopy (STEM), the atomic structure of cubic spinel MgMn<sub>2</sub>O<sub>4</sub> for the first time. More importantly, we find that
a thin stable surface layer of rocksalt MgMnO<sub>2</sub> was grown
on a bulk cubic spinel phase. The formation of a rocksalt phase was
induced by reconstruction of the spinel phase, i.e., the insertion
of Mg into the spinel lattice together with Mg/Mn cation exchange
and Frenkel-defect-mediated relocation of Mg cations. This new structural
analysis provides a critical step toward understanding and tuning
the electrochemical performance of spinel oxide in rechargeable Mg-ion
batteries
Disulfide-Bridged (Mo<sub>3</sub>S<sub>11</sub>) Cluster Polymer: Molecular Dynamics and Application as Electrode Material for a Rechargeable Magnesium Battery
Exploring
novel electrode materials is critical for the development of a next-generation
rechargeable magnesium battery with high volumetric capacity. Here,
we showed that a distinct amorphous molybdenum sulfide, being a coordination
polymer of disulfide-bridged (Mo<sub>3</sub>S<sub>11</sub>) clusters,
has great potential as a rechargeable magnesium battery cathode. This
material provided good reversible capacity, attributed to its unique
structure with high flexibility and capability of deformation upon
Mg insertion. Free-terminal disulfide moiety may act as the active
site for reversible insertion and extraction of magnesium
Disulfide-Bridged (Mo<sub>3</sub>S<sub>11</sub>) Cluster Polymer: Molecular Dynamics and Application as Electrode Material for a Rechargeable Magnesium Battery
Exploring
novel electrode materials is critical for the development of a next-generation
rechargeable magnesium battery with high volumetric capacity. Here,
we showed that a distinct amorphous molybdenum sulfide, being a coordination
polymer of disulfide-bridged (Mo<sub>3</sub>S<sub>11</sub>) clusters,
has great potential as a rechargeable magnesium battery cathode. This
material provided good reversible capacity, attributed to its unique
structure with high flexibility and capability of deformation upon
Mg insertion. Free-terminal disulfide moiety may act as the active
site for reversible insertion and extraction of magnesium