Spectacular Tentacular: Transmedial Tentacles and Their Hegemonic Struggles in Cthulhu and Godzilla

Tentacular cephalopods appear regularly in film. Inspired by Hugo and Hokusai, stories of ferocious octopus attacking primates were invented. This fantasy of the Kraken was incorporated into monster movies in the 1950s with the cult of Cthulhu. Lovecraft describes a vision of the resurrection of prehistoric cephalopod monsters and reinterprets fragments from worldwide mythology. With the film King Kong (1933) as their distant origin, Godzilla (1954) and It Came from Beneath the Sea (1955) describe returns of monsters as recorded in ancient times. The Japanese film King Kong vs. Godzilla (1962) is interesting to consider in this context. Here, in a scenario possibly inspired by Japanese folklore, a huge octopus attacks King Kong, in a struggle that can be interpreted as a battle for initiative in the world of Cthulhu. Cthulhan pseudo-mythology is widely appropriated in later monster movies, although the racism is a stumbling block. In the movie Kong: Skull Island (2017), the monkey god returns like Cthulhu, but bites off the attacking cephalopod's tentacles. This evokes impressive scenes from both King Kong vs. Godzilla and Oldboy (2003). Here, Kong, seeming to extract Cthulhan racism, incorporates the powers of Cthulhu's intense tentacles and pseudo-mythological method

The Mongolian Alexander's Tomb as a Heartland : Theosophy, the Naros Cycle, and Resurrection of Genghis Khan

”ТУРФА МАДАНИЯТЛАР, МИЛЛАТ, ТИЛЛАРНИ ҚИЁСИЙ-ТИПОЛОГИК ТАДҚИҚОТЛАР ОРҚАЛИ АНГЛАШ” халқаро илмий конференция 12 [6 November 2020

Silver-catalyzed coupling reactions of alkyl halides with indenyllithiums

Coupling reactions of tertiary and secondary alkyl halides with indenyllithiums proceeded effectively in the presence of a catalytic amount of silver bromide to provide tertiary- and secondary-alkyl-substituted indene derivatives in good yields

Asymmetric systematic synthesis, structures, and (chir)optical properties of a series of dihetero[8]helicenes

A series of dihetero[8]helicenes have been systematically synthesized in enantiomerically enriched forms by utilizing the characteristic transformations of the organosulfur functionality. The synthetic route begins with assembling a ternaphthyl common synthetic intermediate from 2-naphthol and bissulfinylnaphthalene through an extended Pummerer reaction followed by facile multi-gram-scale resolution. The subsequent cyclization reactions into dioxa- and dithia[8]helicenes take place with excellent axial-to-helical chirality conversion. Dithia[8]helicene is further transformed into the nitrogen and the carbon analogs by replacing the two endocyclic sulfur atoms via SNAr-based skeletal reconstruction. The efficient systematic synthesis has enabled comprehensive evaluation of physical properties, which has clarified the effect of the endocyclic atoms on their structures and (chir)optical properties as well as the unexpected conformational stability of the common helical framework

Generation of Organozinc Reagents from Arylsulfonium Salts Using a Nickel Catalyst and Zinc Dust

Readily available aryldimethylsulfonium triflates react with zinc powder under nickel catalysis via the selective cleavage of the sp2-hybridized carbon–sulfur bond to produce salt-free arylzinc triflates under mild conditions. This zincation displays superb chemoselectivity and thus represents a protocol that is complementary or orthogonal to existing methods. The generated arylzinc reagents show both high reactivity and chemoselectivity in palladium-catalyzed and copper-mediated cross-coupling reactions