1 research outputs found
Cobalt-Catalyzed Aerobic Cross-Dehydrogenative Coupling of C–H and Thiols in Water for C–S Formation
Organosulfides have great significance
and value in synthetic and
biological chemistry. To establish a versatile and green methodology
for C–S bond generation, we successfully developed a new aerobic
cross-dehydrogenative coupling of C–H and S–H to synthesize
aryl sulfides in water, utilizing CoPcS as the catalyst and O<sub>2</sub> as the oxidant. This protocol shows great tolerance of a
wide range of substrates. A large variety of organosulfur compounds
were produced in modest to excellent yields