3 research outputs found
Competition-Induced Macroscopic Superlubricity of Ionic Liquid Analogues by Hydroxyl Ligands Revealed by in Situ Raman
High load-bearing capacity is one of the crucial indicators
for
liquid superlubricants to move toward practicality. However, some
of the current emerging systems not only have low contact pressures
but also are highly susceptible to further degradation due to water
adsorption and even superlubricity failure. Herein, a novel choline
chloride-based ionic liquid analogues (ILAs) of a superlubricant with
triethanolamine (TEOA) as the H-bond donor is reported for the first
time; it obtains an ultralow coefficient of friction (0.005) and high
load-bearing capacity (360 MPa, more than 2 times that of similar
systems) due to adsorption of a small amount of water (<5 wt %)
from the air. In situ Raman combined with 1H NMR and FTIR
techniques reveals that adsorbed water competes with the hydroxyl
group of TEOA for coordination with Cl–, leading
to the conversion of some strong H-bonds to weak H-bonds in ILAs;
the localized strong H-bonds and weak H-bonds endow the ILAs with
high load-bearing capacity and the formation of ultralow shear-resistance
sliding interfaces, respectively, under the shear motion. This study
proposes a strategy to modulate the interactions between liquid species
using adsorbed water from air as a competing ligand, which provides
new insights into the design of ILA-based macroscopic liquid superlubricants
with a high load-bearing capacity
Alloyed Co–Mo Nitride as High-Performance Electrocatalyst for Oxygen Reduction in Acidic Medium
Exploring
cheap and stable electrocatalysts to replace Pt for the
oxygen reduction reaction (ORR) is now the key issue for the large-scale
application of fuel cells. Herein, we report an alloyed Co–Mo
nitride electrocatalyst supported on nitrogen-doped carbon nanocages
(NCNCs) which combines the merits of cobalt nitride and molybdenum
nitride, showing high activity comparable to that of cobalt nitride
and progressively enhanced stability with the increase in the Mo ratio.
The typical Co<sub>0.5</sub>Mo<sub>0.5</sub>N<sub><i>y</i></sub>/NCNCs catalyst demonstrates excellent ORR performance in acidic
medium with a high onset potential of 808 mV vs RHE, superior stability
(>80% retention after 100 h of continuous testing in 0.5 mol L<sup>–1</sup> H<sub>2</sub>SO<sub>4</sub>), a dominant four-electron
catalytic process, and good immunity to methanol crossover. Together
with the convenient and scalable preparation as well as the low cost,
the alloyed Co–Mo nitride electrocatalyst shows great potential
in application for fuel cells. This study also suggests a promising
strategy to develop non-precious-metal ORR electrocatalysts in acidic
medium: i.e., to construct the alloyed compounds by combining substances
with respective high activity and high stability
Alcohol-Tolerant Platinum Electrocatalyst for Oxygen Reduction by Encapsulating Platinum Nanoparticles inside Nitrogen-Doped Carbon Nanocages
Pt-based electrocatalysts
are the most popular for direct alcohol fuel cells, but their performances
easily deteriorate for the oxygen reduction reaction (ORR) at the
cathode because of the alcohol crossover effect. Herein, we report
the novel Pt electrocatalyst encapsulated inside nitrogen-doped carbon
nanocages (Pt@NCNC), which presents excellent alcohol-tolerant ORR
activity and durability in acidic media, far superior to the Pt counterpart
immobilized outside the nanocages (Pt/NCNC). The superb performance
is correlated with the molecule-sieving effect of the micropores penetrating
through the shells of the nanocages, which admit the small-sized oxygen
and ions but block the large-sized alcohols into the nanocages. This
mechanism is confirmed by examining the size dependence of ORR and
alcohol oxidation activities by regulating the micropores sizes. This
study provides a promising strategy to develop the superior alcohol-tolerant
Pt-based ORR electrocatalyst in acidic media