2 research outputs found
Amine-Ligated Approach for the Synthesis of Extra-Large-Pore Zinc Phosphites with qtz‑h and bnn Topologies
No full textPresented here are two open-framework
zinc phosphites, namely, ZnÂ(dabco)<sub>0.5</sub>(HPO<sub>3</sub>)
(SCU-18) and Zn<sub>4</sub>(Hdabco)<sub>2</sub>(CH<sub>3</sub>COO)<sub>2</sub>(HPO<sub>3</sub>)<sub>4</sub> (SCU-20), where dabco = 1,4-diazabicyclo[2.2.2]Âoctane.
SCU-18 features a rare 3-connected inorganic skeleton with a chiral
qtz-h topology. It contains 18-membered-ring (18 MR) channels displaying
porosity and second-harmonic-generation response. SCU-20 has a bnn
topology containing large 20 MR channels that shows a strong blue
emission as a result of excitation at 375 nm
Amine-Ligated Approach for the Synthesis of Extra-Large-Pore Zinc Phosphites with qtz‑h and bnn Topologies
No full textPresented here are two open-framework
zinc phosphites, namely, ZnÂ(dabco)<sub>0.5</sub>(HPO<sub>3</sub>)
(SCU-18) and Zn<sub>4</sub>(Hdabco)<sub>2</sub>(CH<sub>3</sub>COO)<sub>2</sub>(HPO<sub>3</sub>)<sub>4</sub> (SCU-20), where dabco = 1,4-diazabicyclo[2.2.2]Âoctane.
SCU-18 features a rare 3-connected inorganic skeleton with a chiral
qtz-h topology. It contains 18-membered-ring (18 MR) channels displaying
porosity and second-harmonic-generation response. SCU-20 has a bnn
topology containing large 20 MR channels that shows a strong blue
emission as a result of excitation at 375 nm
