105 research outputs found

    Characterizations of distality via weak equicontinuity

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    For an infinite discrete group GG acting on a compact metric space XX, we introduce several weak versions of equicontinuity along subsets of GG and show that if a minimal system (X,G)(X,G) admits an invariant measure then (X,G)(X,G) is distal if and only if it is pairwise IP∗^*-equicontinuous; if the product system (X×X,G)(X\times X,G) of a minimal system (X,G)(X,G) has a dense set of minimal points, then (X,G)(X,G) is distal if and only if it is pairwise IP∗^*-equicontinuous if and only if it is pairwise central∗^*-equicontinuous; if (X,G)(X,G) is a minimal system with GG being abelian, then (X,G)(X,G) is a system of order ∞\infty if and only if it is pairwise FIP∗^*-equicontinuous.Comment: 20 pages. To appear in Discrete and Continuous Dynamical Systems. arXiv admin note: text overlap with arXiv:2108.0127

    Probing the interaction of nanoparticles with small molecules in real time via quartz crystal microbalance monitoring

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    Y. Y. acknowledges University College London (UCL) for the Overseas Research Scholarship and the Graduate Research Scholarship. The project received funding from the European Unions Horizon 2020 research and innovation programme under grant agreement no. 633635 (DIACHEMO) and the EPSRC (grant number EP/J500549/1).Despite extensive advances in the field of molecular recognition, the real-time monitoring of small molecule binding to nanoparticles (NP) remains a challenge. To this end, we report on a versatile approach, based on quartz crystal microbalance with dissipation monitoring, for the stepwise in situ quantification of gold nanoparticle (AuNPs) immobilisation and subsequent uptake and release of binding partners. AuNPs stabilised by thiol-bound ligand shells of prescribed chemical composition were densely immobilised onto gold surfaces via dithiol linkers. The boronate ester formation between salicylic acid derivatives in solution and boronic acids in the AuNP ligand shell was then studied in real time, revealing a drastic effect of both ligand architecture and Lewis base concentration on the interaction strength. The binding kinetics were analysed with frequency response modelling for a thorough comparison of binding parameters including relaxation time as well as association rate constant. The results directly mirror those from previously reported in-depth studies using nuclear magnetic resonance spectroscopy. By achieving quantitative characterisation of selective binding of analytes with molecular weight below 300 Da, this new method enables rapid, low cost, rational screening of AuNP candidates for molecular recognition.Publisher PDFPeer reviewe

    Predicting the response of three common subtropical tree species in China to climate change

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    IntroductionClimate is crucial factor influencing species distribution, and with global climate change, the potential geographic distribution of species will also alter. In this study, three subtropical tree species (Cunninghamia lanceolata, Pinus taiwanensis, and Quercus glauca) of great ecological values were selected as research objects.MethodsWe applied a maximum entropy (MaxEnt) to predict their potential distributions under different climate scenarios in both present and future conditions based on 37 environmental factors. Jackknife test was used in key factors affecting species distribution. In addition, we explored the key environmental variables that affect their distributions and revealed the evolutionary patterns and migration trends of these tree species under future climate.ResultsThe main findings are as follows: (1) Winter temperature, winter precipitation, and annual temperature range are identified as the key environmental variables affecting the potential geographic distribution of the three tree species; moreover, precipitation-related factors have a greater impact than temperature-related factors; (2) Currently suitable habitats for these three tree species are primarily located in subtropical China with decreasing suitability from south to north; (3) Under future climate conditions, the area of potentially suitable habitat for C. lanceolata continues to expand, while P. taiwanensis and Q. glauca tend to experience a reduction due to increasing greenhouse gas emissions over time; and (4) The centroid of suitable habitat for C. lanceolata shifts northward under future climate change, while the centroid of P. taiwanensis and Q. glauca move southward along with shrinking suitable habitat area.DiscussionOur predictions highlight a high risk of habitat loss of Q. glauca under climate change, recommending management and conservation references for these three commonly used afforestation species under current and future climate change scenarios in China
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