Spectroscopic Evidence for Interfacial Charge Separation and Recombination in Graphene-MoS2 Vertical Heterostructures

Vertical van der Waals (vdW) heterostructures consisting of graphene (Gr) and transition metal dichalcogenides (TMDs) have created a fascinating platform for exploring optical and electronic properties in the two-dimensional limit. Previous study has revealed the ultrafast formation of interfacial excitons and the exciton dynamics in the Gr/MoS2 heterostructure. However, a fully understanding of interfacial charge separation and the subsequent dynamics in graphene-based heterostructures remains elusive. Here, we investigate the carrier dynamics of Gr-MoS2 (including Gr/MoS2 and MoS2/Gr stacking sequences) heterostructures under different photoexcitation energies and stacking sequences by comprehensive ultrafast means, including time-resolved terahertz spectroscopy (TRTS), terahertz emission spectroscopy (TES) and transient absorption spectroscopy (TAS). We demonstrate that the Gr/MoS2 heterostructure generates hot electron injection from graphene into the MoS2 layer with photoexcitation of sub-A-exciton of MoS2, while the interfacial charge separation in the MoS2/Gr could be partially blocked by the electric field of substrate. Charge transfer (CT) occurs in same directions for the Gr-MoS2 heterostructures with opposite stacking order, resulting in the opposite orientations of the interfacial photocurrent, as directly demonstrated by the terahertz (THz) emission. Moreover, we demonstrate that the recombination time of interfacial charges after CT is on a timescale of 18 ps to 1 ns, depending on the density of defect states in MoS2 layer. This work provides a comprehensive and unambiguous picture of the interfacial charge dynamics of graphene-based heterostructures, which is essential for developing Gr/TMDs based optoelectronic devices.Comment: 23 pages, 5 Figure

AI-enabled soft sensing array for simultaneous detection of muscle deformation and mechanomyography for metaverse somatosensory interaction

Motion recognition (MR)-based somatosensory interaction technology, which interprets user movements as input instructions, presents a natural approach for promoting human-computer interaction, a critical element for advancing metaverse applications. Herein, this work introduces a non-intrusive muscle-sensing wearable device, that in conjunction with machine learning, enables motion-control-based somatosensory interaction with metaverse avatars. To facilitate MR, the proposed device simultaneously detects muscle mechanical activities, including dynamic muscle shape changes and vibrational mechanomyogram signals, utilizing a flexible 16-channel pressure sensor array (weighing ≈0.38 g). Leveraging the rich information from multiple channels, a recognition accuracy of ≈96.06% is achieved by classifying ten lower-limb motions executed by ten human subjects. In addition, this work demonstrates the practical application of muscle-sensing-based somatosensory interaction, using the proposed wearable device, for enabling the real-time control of avatars in a virtual space. This study provides an alternative approach to traditional rigid inertial measurement units and electromyography-based methods for achieving accurate human motion capture, which can further broaden the applications of motion-interactive wearable devices for the coming metaverse age

Wide‐bandwidth nanocomposite‐sensor integrated smart mask for tracking multiphase respiratory activities

Wearing masks has been a recommended protective measure due to the risks of coronavirus disease 2019 (COVID-19) even in its coming endemic phase. Therefore, deploying a “smart mask” to monitor human physiological signals is highly beneficial for personal and public health. This work presents a smart mask integrating an ultrathin nanocomposite sponge structure-based soundwave sensor (≈400 µm), which allows the high sensitivity in a wide-bandwidth dynamic pressure range, i.e., capable of detecting various respiratory sounds of breathing, speaking, and coughing. Thirty-one subjects test the smart mask in recording their respiratory activities. Machine/deep learning methods, i.e., support vector machine and convolutional neural networks, are used to recognize these activities, which show average macro-recalls of ≈95% in both individual and generalized models. With rich high-frequency (≈4000 Hz) information recorded, the two-/tri-phase coughs can be mapped while speaking words can be identified, demonstrating that the smart mask can be applicable as a daily wearable Internet of Things (IoT) device for respiratory disease identification, voice interaction tool, etc. in the future. This work bridges the technological gap between ultra-lightweight but high-frequency response sensor material fabrication, signal transduction and processing, and machining/deep learning to demonstrate a wearable device for potential applications in continual health monitoring in daily life

A Multiframes Integration Object Detection Algorithm Based on Time-Domain and Space-Domain

In order to overcome the disadvantages of the commonly used object detection algorithm, this paper proposed a multiframes integration object detection algorithm based on time-domain and space-domain (MFITS). At first, the consecutive multiframes were observed in time-domain. Then the horizontal and vertical four-direction extension neighborhood of each target pixel were selected in space-domain. Transverse and longitudinal sections were formed by fusing of the time-domain and space-domain. The mean and standard deviation of the pixels in transverse and longitudinal section were calculated. We also added an improved median filter to generate a new pixel in each target pixel position, eventually to generate a new image. This method is not only to overcome the RPAC method affected by lights, shadows, and noise, but also to reserve the object information to the maximum compared with the interframe difference method and overcome the difficulty in dealing with the high frequency noise compared with the adaptive background modeling algorithm. The experiment results showed that the proposed algorithm reserved the motion object information well and removed the background to the maximum

An Efficient End-to-End Obstacle Avoidance Path Planning Algorithm for Intelligent Vehicles Based on Improved Whale Optimization Algorithm

End-to-end obstacle avoidance path planning for intelligent vehicles has been a widely studied topic. To resolve the typical issues of the solving algorithms, which are weak global optimization ability, ease in falling into local optimization and slow convergence speed, an efficient optimization method is proposed in this paper, based on the whale optimization algorithm. We present an adaptive adjustment mechanism which can dynamically modify search behavior during the iteration process of the whale optimization algorithm. Meanwhile, in order to coordinate the global optimum and local optimum of the solving algorithm, we introduce a controllable variable which can be reset according to specific routing scenarios. The evolutionary strategy of differential variation is also applied in the algorithm presented to further update the location of search individuals. In numerical experiments, we compared the proposed algorithm with the following six well-known swarm intelligence optimization algorithms: Particle Swarm Optimization (PSO), Bat Algorithm (BA), Gray Wolf Optimization Algorithm (GWO), Dragonfly Algorithm (DA), Ant Lion Algorithm (ALO), and the traditional Whale Optimization Algorithm (WOA). Our method gave rise to better results for the typical twenty-three benchmark functions. In regard to path planning problems, we observed an average improvement of 18.95% in achieving optimal solutions and 77.86% in stability. Moreover, our method exhibited faster convergence compared to some existing approaches

3D Modeling of Transformer Substation Based on Mapping and 2D Images

A new method for building 3D models of transformer substation based on mapping and 2D images is proposed in this paper. This method segments objects of equipment in 2D images by using k-means algorithm in determining the cluster centers dynamically to segment different shapes and then extracts feature parameters from the divided objects by using FFT and retrieves the similar objects from 3D databases and then builds 3D models by computing the mapping data. The method proposed in this paper can avoid the complex data collection and big workload by using 3D laser scanner. The example analysis shows the method can build coarse 3D models efficiently which can meet the requirements for hazardous area classification and constructions representations of transformer substation

Strength and toughness of tissue adhesives depend on thickness

Adhesives are commonly assessed by two properties: strength and toughness. Here we study how strength and toughness are affected by adhesive thickness. We sandwich gelatin adhesives of various thicknesses between glass substrates. The transparency of the adhesives and substrates enables us to observe crack nucleation and growth. We measure strength by lap shear of samples without precrack, and measure toughness by lap shear of samples with precrack. Our data show a characteristic adhesive thickness, about 0.5 mm. For adhesives below the characteristic thickness, strength is independent of thickness, but toughness increases with thickness. For adhesives above the characteristic thickness, strength decreases as thickness increases, but toughness is a constant. Strength scatters narrowly for samples of a thin adhesive, but broadly for samples of a thick adhesive. By contrast, toughness scatters narrowly for samples of all thicknesses. This work shows the importance of assessing adhesives of various thicknesses

Polymerization of hydroxylated graphitic carbon nitride as an efficient flame retardant for epoxy resins

Graphitic carbon nitride (GCN) has been recognized as a potential flame retardant (FR) due to its high thermal stability and nitrogen richness. Previous work has been limited to hybridization without involving covalent modification. Here, we developed a facile covalent modification approach to polycondensation that can chelate with metal ions (PCNOH-CuCo) from GCN. Structural and mechanical property characterization confirmed the ability of PCNOH-CuCo to be uniformly dispersed in the epoxy resin (EP). Fire tests showed excellent fire resistance of EP with 10 wt% PCNOH-CuCo (EP/10PCNOH-CuCo), including a limiting oxygen index of EP/10PCNOH-CuCo up to 31.5%, and the reduction in the peak heat release rate, total heat release, peak smoke production, total smoke production peak CO production, and peak CO2 production of 47.9%, 37.5%, 20%, 44.5%, 30.9%, and 42.5%, respectively. This work provides a solution for the fabrication of GCN-based FRs and their derived metal-doped FRs

Nutrient supply controls the linkage between species abundance and ecological interactions in marine bacterial communities

Nutrient scarcity is pervasive for natural microbial communities, affecting species reproduction and co-existence. However, it remains unclear whether there are general rules of how microbial species abundances are shaped by biotic and abiotic factors. Here we show that the ribosomal RNA gene operon (rrn) copy number, a genomic trait related to bacterial growth rate and nutrient demand, decreases from the abundant to the rare biosphere in the nutrient-rich coastal sediment but exhibits the opposite pattern in the nutrient-scarce pelagic zone of the global ocean. Both patterns are underlain by positive correlations between community-level rrn copy number and nutrients. Furthermore, inter-species co-exclusion inferred by negative network associations is observed more in coastal sediment than in ocean water samples. Nutrient manipulation experiments yield effects of nutrient availability on rrn copy numbers and network associations that are consistent with our field observations. Based on these results, we propose a "hunger games" hypothesis to define microbial species abundance rules using the rrn copy number, ecological interaction, and nutrient availability