25,383 research outputs found
Phase Separation Dynamics in Isotropic Ion-Intercalation Particles
Lithium-ion batteries exhibit complex nonlinear dynamics, resulting from
diffusion and phase transformations coupled to ion intercalation reactions.
Using the recently developed Cahn-Hilliard reaction (CHR) theory, we
investigate a simple mathematical model of ion intercalation in a spherical
solid nanoparticle, which predicts transitions from solid-solution radial
diffusion to two-phase shrinking-core dynamics. This general approach extends
previous Li-ion battery models, which either neglect phase separation or
postulate a spherical shrinking-core phase boundary, by predicting phase
separation only under appropriate circumstances. The effect of the applied
current is captured by generalized Butler-Volmer kinetics, formulated in terms
of diffusional chemical potentials, and the model consistently links the
evolving concentration profile to the battery voltage. We examine sources of
charge/discharge asymmetry, such as asymmetric charge transfer and surface
"wetting" by ions within the solid, which can lead to three distinct phase
regions. In order to solve the fourth-order nonlinear CHR
initial-boundary-value problem, a control-volume discretization is developed in
spherical coordinates. The basic physics are illustrated by simulating many
representative cases, including a simple model of the popular cathode material,
lithium iron phosphate (neglecting crystal anisotropy and coherency strain).
Analytical approximations are also derived for the voltage plateau as a
function of the applied current
Broad-line and Multi-wave Band Emission from Blazars
We study the correlations of the flux of the broad-line emission ()
with the X-ray emission flux, optical emission flux at 5500 \AA and radio
emission flux at 5 GHz, respectively, for a large sample of 50 Blazars (39
flat-spectrum radio quasars (FSRQs) and 11 BL Lac objects). Our main results
are as follows. There are very strong correlations between and
and between and in both states for 39 FSRQs and the
slopes of the linear regression equations are almost equal to 1. There are weak
correlations between and and between and
for 11 BL Lac objects in both states, and the slopes of the linear regression
equations are close to 1. There are significant correlations between
and and between and for 50 blazars in both states,
the slopes of both the linear regression equations are also close to 1. These
results support a close link between relativistic jets and accretion on to the
central Kerr black hole. On the other hand, we find that BL Lac objects have
low accretion efficiency , whereas FSRQs have high accretion efficiency
. The unified model of FSRQs and BL Lac objects is also discussed.Comment: 15 pages, 8 figure
Topological quantum phase transitions and edge states in spin-orbital coupled Fermi gases
We study the superconducting state in the presence of spin-orbital coupling
and the Zeeman field. It is found that a phase transition from the
Fulde-Ferrell-Larkin-Ovchinnikov state to the topological superconducting state
occurs upon increasing the spin-orbital coupling. The nature of this
topological phase transition and its critical property are investigated
numerically. Physical properties of topological superconducting phase are also
explored. Moreover, the local density of states is calculated, through which
the topological feature may be tested experimentally.Comment: 11 pages, 8 figure
Morphology, structure, optical, and electrical properties of AgSbO₃
The morphology of defect pyrochlore-type, AgSbO₃ microparticle/nanoparticles obtained via solid state reaction evolve from irregular to Fullerene-like polyhedra before finally decomposing into metal-organic framework-5 like particles with increase in sintering temperature. The defect pyrochlore-type AgSbO₃ particles are slightly Ag deficient while the valence of the antimony ion is shown to be +5 giving rise to a probable stoichiometry of Ag₁ˍₓ SbVO₃ˍₓ/₂, with x∼0.01–0.04. A highly structured diffuse intensity distribution observed via electron diffraction is interpreted in terms of correlated displacements of one-dimensional (1D) silver ion chains along ⟨110⟩ directions. A redshifting in the absorption edges in UV-visible absorption spectra is observed for samples prepared at sintering temperatures higher than 1000 °C and attributed to the surface plasma resonance effect associated with small amounts of excess metallic Ag on the Ag₁ˍₓ SbVO₃ˍₓ/₂ particles. An electrical properties investigation of the silver antimonate samples via dielectric, conductivity, and electric modulus spectroscopy shows a prominent dielectric relaxation associated with grain boundaries. The silver ion conductivity is associated with correlated displacements of 1D silver ion chains along ⟨110⟩ directions.Z.G.Y., Y.L., and R.L.W. acknowledge financial support
from the Australian Research Council ARC in the form of
ARC Discovery Grants
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