Determination Of The Absolute Structure Factor For The Forbidden (222) Reflection In Silicon Using 0.12-γ Rays

A room-temperature determination of the absolute structure factor for the forbidden (222) reflection in silicon has been conducted at the University of Missouri Research Reactor with 103-keV gamma rays. The measured structure factor of F(222)=1.456 is in excellent agreement with five of the earlier intensity measurements and is significantly different from any value determined using Pendellösung techniques. An increase in accuracy over previous intensity measurements by a factor of between 2 and 10 has been achieved and is made possible through the use of monoenergetic, short-wavelength gamma rays, which allow absolute measurements to be made in Laue geometry on relatively thick crystals (∼1 mm) without encountering extinction problems. © 1982 The American Physical Society

Inelastic scattering in condensed matter with high intensity Moessbauer radiation

We give a progress report for the work which has been carried out in the last three years with DOE support. A facility for high-intensity Moessbauer scattering is now fully operational at the University of Missouri Research Reactor (MURR) as well as facility at Purdue, using special isotopes produced at MURR. High precision, fundamental Moessbauer effect studies have been carried out using scattering to filter the unwanted radiation. These have led to a new Fourier transform method for describing Moessbauer effect (ME) lineshape and a direct method of fitting ME data to the convolution integral. These methods allow complete correction for source resonance self absorption (SRSA) and the accurate representation of interference effects that add an asymmetric component to the ME lines. We have begun applying these techniques to attenuated ME sources whose central peak has been attenuated by stationary resonant absorbers, to more precisely determine interference parameters and line-shape behavior in the resonance asymptotic region. This analysis is important to both the fundamental ME studies and to scattering studies for which a deconvolution is essential for extracting the correct recoilless fractions and interference parameters. A number of scattering studies have been successfully carried out including a study of the thermal diffuse scattering in Si, which led to an analysis of the resolution function for gamma-ray scattering. Also studied was the anharmonic motion in Na and the satellite reflection Debye-Waller factor in TaS{sub 2}, which indicate phason rather than phonon behavior. We have begun quasielastic diffusion studies in viscous liquids and current results are summarized. These advances, coupled to our improvements in MIcrofoil Conversion Electron spectroscopy lay the foundation for the proposed research outlined in this request for a three-year renewal of DOE support

Search for instability-induced amorphization in deuterated ErFe2

Experimental evidence–in the form of a specific-heat anomaly–for instability-induced amorphization of ErFe2 by hydrogenation was recently reported by Fecht, Fu, and Johnson [Phys. Rev. Lett. 64, 1753 (1990)]. We have attempted to study this anomaly by in situ elastic neutron diffraction and differential-scanning-calorimetry (DSC) measurements of deuterated ErFe2 below and above the reversible, endothermic, λ-shaped enthalpy signal that they found at ∼200 °C. Our combined diffraction and DSC results reveal that the amorphization transition is irreversible, strongly exothermic and occurs only at a significantly higher temperature than that of the specific-heat anomaly. Rather than resulting from an underlying instability of the crystalline phase, amorphization occurs as a by-product of short-range clustering of the Er and Fe atoms, which is driven by the creation of energetically more favorable sites for the deuterium atoms

Inelastic scattering in condensed matter with high intensity Moessbauer radiation

The QUEGS facility at MURR has produced a number of new results and demonstrated the range of potential applications of high resolution, high intensity Moessbauer scattering. This work has been carried out by both MU and Purdue researchers and includes published results on Na, W, pentadecane, polydimethylsiloxane and other systems, manuscripts submitted on alkali halides (Phys. Rev. B) and accurate Moessbauer lineshape measurements (Phys. Rev. C), and manuscripts in preparation on glycerol, NiAl and Moessbauer spectra obtained by modulating a scattering crystal. Recently, new collaborations have been initiated which will substantially enhance our efforts. These are with W. Steiner (Vienna), G. Coddens (Saclay), and R. D. Taylor (Los Alamos). Steiner is experienced with Fe-57 Moessbauer scattering, while Coddens specializes in quasielastic neutron scattering; both of these areas naturally complement our work. R. D. Taylor has pioneered Moessbauer spectroscopy from the time of its discovery and has already made important contributions to our study of lattice dynamics and superconductivity for lead alloyed with small quantities of tin. At the same time, a significant instrument upgrade is underway, funded in part by the DOE-URIP program

The Relationship Between Magnetic Interactions and Near Neighbor Interatomic Distances in the Transition Metal Sublattice of R(Mn/Fe)6A6 (R=Nd or Sm, A=Ge or Sn)

The magnetic and crystallographic structures of R(Fe/Mn)6A6 (R=Nd or Sm and A=Ge or Sn) intermetallics have been investigated using x-ray and neutron diffraction techniques and superconducting quantum interference device magnetic measurements. For both stannides (A=Sn) and germanides (A=Ge), the lattice contracts with increasing iron content. In the case of the stannides, substitution of manganese by iron enhances the saturation magnetization and Curie temperature at low iron concentrations (x≤2) suggesting the presence of an extremely rare occurrence, positive coupling between iron and manganese magnetic moments. In contrast, the magnetic properties of the germanides deteriorate rapidly as manganese is replaced by iron. This difference in the dependence of magnetic properties on the iron content between the germanides and stannides is explained using the Bethe–Slater relationship between near neighbor exchange interactions and interatomic distances. Based on the observations described in this article, it is concluded that the critical near neighbor interatomic distance above which manganese/iron moments couple positively in these intermetallics is ∼2.614 Å

Sublattice Asymmetric Reductions of Spin Values on Stacked Triangular Lattice Antiferromagnet CsCoBr3_3

We study the reductions of spin values of the ground state on a stacked triangular antiferromagnet using the spin-wave approach. We find that the spin reductions have sublattice asymmetry due to the cancellation of the molecular field. The sublattice asymmetry qualitatively analyzes the NMR results of CsCoBr$_3$.Comment: 5pages, 5figure

Phase Diagram of Lattice-Spin System RbCoBr3_3

We study the lattice-spin model of RbCoBr$_3$ which is proposed by Shirahata and Nakamura, by mean field approximation. This model is an Ising spin system on a distorted triangular lattice. There are two kinds of frustrated variables, that is, the lattice and spin. We obtain a phase diagram of which phase boundary is drawn continuously in a whole region. Intermediate phases that include a partial disordered state appear. The model has the first-order phase transitions in addition to the second-order phase transitions. We find a three-sublattice ferrimagnetic state in the phase diagram. The three-sublattice ferrimagnetic state does not appear when the lattice is not distorted.Comment: 5 pages, 4 figures, jpsj2.cls, to be published in J. Phys. Soc. Jpn. Vol.75 (2006) No.

Neutron structural studies on the superconducting (Nd1-xCax)(Ba1.6La0.4)Cu3Oz system

We have investigated the influence of Ca ions substitution on the structural and superconducting properties of (Nd1-xCax)(Ba1.6La0.4)Cu3Oz system. Magnetization, X-ray diffraction and neutron diffraction studies have been carried out on a series of compounds with x = 0.0 to 0.6. The superconducting transition temperature Tc, determined from magnetization measurements increases with increasing Ca2+ substitution. Neutron diffraction studies reveal that these compounds crystallize in a tetragonal structure (space group P4/mmm). A detailed analysis of the neutron diffraction data reveals that Ca and La ions are intermixed at the nominal Ba and Nd sites. While a major fraction of Ca ions occupy the usual Nd site, a small fraction occupies the Ba site. Consequently, the corresponding amount of La substitutes at the nominal Nd site. The intermixing of Ca and La sites randomizes the chain site oxygens leading to a tetragonal structure despite an oxygen content close to 7.0 for all the Ca doped samples. Further increase of Ca content lead to change in its co-ordination from six-fold to eight-fold at x >= 0.4.Comment: 13 Pages, 5 Figure