The vibrational predissociation spectroscopy of hydrogen cluster ions

The first infrared spectra of protonated hydrogen clusters in the gas phase have been observed. Predissociation spectra were taken with a tandem mass spectrometer: mass selected hydrogen cluster ions were irradiated inside a rf ion trap by a tunable infrared laser, and the fragment ions created by photodissociation of the clusters were mass selected and detected. Spectra for each product channel were measured by counting fragment ions as a function of laser frequency. Low resolution spectra (Deltanu=10 cm^−1) in the region from 3800 to 4200 cm^−1 were observed for the ions H + 5, H + 7, and H + 9 at 3910, 3980, and 4020 cm−1, respectively. A band was also observed for H + 5 at 3532 cm^−1. No rotational structure was resolved. The frequencies of the band maxima agree well with the frequencies predicted by previous ab initio calculations for the highest modes

Infrared spectra of the cluster ions H7O⁺₃·H2 and H9O⁺₄·H2

Infrared spectra of hydrated hydronium ions weakly bound to an H2 molecule, specifically H7O + 3 ·H2 and H9O + 4 ·H2, have been observed. Mass-selected parent ions, trapped in a radio frequency ion trap, are excited by a tunable infrared laser; following absorption, the complex predissociates with loss of the H2, and the resulting fragment ions are detected. Spectra have been taken from 3000 to 4000 cm^−1, with a resolution of 1.2 cm^−1. They are compared to recent theoretical and experimental spectra of the hydronium ion hydrates alone. Binding an H2 molecule to these clusters should only weakly perturb their vibrations; if so, our spectra should be similar to spectra of the hydrated hydronium ions H7O + 3 and H9O + 4

Infrared spectroscopy of the cluster ions H⁺₃·(H2)n

The vibrational spectra of the clusters H + 3(H2)n were observed near 4000 cm−1 by vibrational predissociation spectroscopy. Spectra of mass-selected clusters were obtained by trapping the ions in a radio frequency ion trap, exciting vibrational transitions of the cluster ions to predissociating levels, and detecting the fragment ions with a mass spectrometer. Low resolution bands of the solvent H2 stretches were observed for the clusters of one to six H2 coordinated to an H + 3 ion. The red shift of these vibrations relative to the monomer H2 frequency supported the model of H + 9 as an H + 3 with a complete inner solvation shell of three H2, one bound to each corner of the ion. Two additional bands of H + 5 were observed, one assigned as the H + 3 symmetric stretch, and the other as a combination or overtone band. High-resolution scans (0.5 and 0.08 cm−1) of H + n, n=5, 7, and 9 yielded no observable rotational structure, a result of either spectral congestion or rapid cluster dissociation. The band contour of the H + 5 band changed upon cooling the internal degrees of freedom, but the peaks remained featureless. The observed frequencies of H + 7 and H + 9 agreed well with ab initio predictions, but those of H + 5 did not. This deviation is discussed in terms of the large expected anharmonicity of the proton bound dimer H + 5

Two-stage composite megathrust rupture of the 2015 M(w)8.4 Illapel, Chile, earthquake identified by spectral-element inversion of teleseismic waves

The Mw8.4 Illapel earthquake occurred on 16 September was the largest global event in 2015. This earthquake was not unexpected because the hypocenter was located in a seismic gap of the Peru-Chile subduction zone. However, the source model derived from 3-D spectral-element inversion of teleseismic waves reveals a distinct two-stage rupture process with completely different slip characteristics as a composite megathrust event. The two stages were temporally separated. Rupture in the first stage, with a moment magnitude of Mw8.32, built up energetically from the deeper locked zone and propagated in the updip direction toward the trench. Subsequently, the rupture of the second stage, with a magnitude of Mw8.08, mainly occurred in the shallow subduction zone with atypical repeating slip behavior. The unique spatial-temporal rupture evolution presented in this source model is key to further in-depth studies of earthquake physics and source dynamics in subduction systems

Evolution of superconductivity by oxygen annealing in FeTe0.8S0.2

Oxygen annealing dramatically improved the superconducting properties of solid-state-reacted FeTe0.8S0.2, which showed only a broad onset of superconducting transition just after the synthesis. The zero resistivity appeared and reached 8.5 K by the oxygen annealing at 200\degree C. The superconducting volume fraction was also enhanced from 0 to almost 100%. The lattice constants were compressed by the oxygen annealing, indicating that the evolution of bulk superconductivity in FeTe0.8S0.2 was correlated to the shrinkage of lattice.Comment: 13 pages, 6 figure