Effects of zinc oxide filler on the curing and mechanical response of alkyd coatings

The mechanical properties of an alkyd resin filled with zinc oxide pigment were studied at different concentrations over a wide range of time scales using dynamic mechanical analysis, quartz crystal rheometry and nanoindentation. The motivation for this work stems from the interest in accessing the long-term properties of paint coatings by studying the mechanical properties of historic paints. In this foundational work, we compare three different modalities of mechanical measurements and systematically determine the effect of pigment filler loading on the measured properties. Quantitative agreement between the methods is obtained when the characteristic time scales of each of the methods is taken into account. While nanoindentation is the technique most readily applied to historic paint samples, the rheometric quartz crystal microbalance (rheo-QCM) is the best suited for obtaining mechanistic information from measurements of paint properties over time, provided that appropriate thin-film samples can be produced. In these studies we find that ZnO increases the rate of oxidation of the alkyd during the initial stages of cure by an amount that depends on the ZnO content

Alternating-Spin Ladders

We investigate a two-leg spin ladder system composed of alternating-spin chains with two-different kind of spins. The fixed point properties are discussed by using spin-wave analysis and non-linear sigma model techniques. The model contains various massive phases, reflecting the interplay between the bond-alternation and the spin-alternation.Comment: 6 pages, revtex, to appear in PR

Temperature Dependence of Extended and Fractional SU(3) Monopole Currents

We examine in pure SU(3) the dependence of extended monopole current k and cross-species extended monopole current k^{cross} on temperature t, monopole size L, and fractional monopole charge 1/q. We find that features of both k and k^{cross} are sensitive to t for a range of L and q. In particular, the spatial-temporal asymmetry ratios of both k and k^{cross} are sensitive over a range of L and q to the SU(3) deconfinement transition. The motivation for studying cross, extended, and fractional monopoles in SU(3) is given.Comment: 15 pages (archiving final publication version; very minor revisions

Towards an Abelian Formulation of Lattice QCD Confinement

We probe for operators occurring in the APQCD(``abelian-projected QCD'') action by evaluating abelian-projected $1$-plaquette spectral densities in pure gauge $SU(3)$ fixed to maximal abelian gauge. Couplings $B_{APQCD}(q,L)$ are extracted from the spectral densities for each representation $q$, $L\times L$ plaquette. While APQCD is dominated by a $q=L=1$ resonance, we also find evidence for weakly coupled $L=2$ plaquettes. Moreover, since $B_{APQCD}(1,1) > B_{QED}(1,1)$ even if $\beta_{QED} > \beta_c$, $L>1$ plaquettes must be significant since APQCD is confining.Comment: 1+11 pages, fixed minor postscript erro

Zero mode in the time-dependent symmetry breaking of λϕ4\lambda\phi^4 theory

We apply the quartic exponential variational approximation to the symmetry breaking phenomena of scalar field in three and four dimensions. We calculate effective potential and effective action for the time-dependent system by separating the zero mode from other non-zero modes of the scalar field and treating the zero mode quantum mechanically. It is shown that the quantum mechanical properties of the zero mode play a non-trivial role in the symmetry breaking of the scalar $\lambda \phi^4$ theory.Comment: 10 pages, 3 figure

A canonical FtsZ protein in Verrucomicrobium spinosum, a member of the Bacterial phylum Verrucomicrobia that also includes tubulin-producing Prosthecobacter species

BACKGROUND: The origin and evolution of the homologous GTP-binding cytoskeletal proteins FtsZ typical of Bacteria and tubulin characteristic of eukaryotes is a major question in molecular evolutionary biology. Both FtsZ and tubulin are central to key cell biology processes – bacterial septation and cell division in the case of FtsZ and in the case of tubulins the function of microtubules necessary for mitosis and other key cytoskeleton-dependent processes in eukaryotes. The origin of tubulin in particular is of significance to models for eukaryote origins. Most members of domain Bacteria possess FtsZ, but bacteria in genus Prosthecobacter of the phylum Verrucomicrobia form a key exception, possessing tubulin homologs BtubA and BtubB. It is therefore of interest to know whether other members of phylum Verrucomicrobia possess FtsZ or tubulin as their FtsZ-tubulin gene family representative. RESULTS: Verrucomicrobium spinosum, a member of Phylum Verrucomicrobia of domain Bacteria, has been found to possess a gene for a protein homologous to the cytoskeletal protein FtsZ. The deduced amino acid sequence has sequence signatures and predicted secondary structure characteristic for FtsZ rather than tubulin, but phylogenetic trees and sequence analysis indicate that it is divergent from all other known FtsZ sequences in members of domain Bacteria. The FtsZ gene of V. spinosum is located within a dcw gene cluster exhibiting gene order conservation known to contribute to the divisome in other Bacteria and comparable to these clusters in other Bacteria, suggesting a similar functional role. CONCLUSION: Verrucomicrobium spinosum has been found to possess a gene for a protein homologous to the cytoskeletal protein FtsZ. The results suggest the functional as well as structural homology of the V. spinosum FtsZ to the FtsZs of other Bacteria implying its involvement in cell septum formation during division. Thus, both bacteria-like FtsZ and eukaryote-like tubulin cytoskeletal homologs occur in different species of the phylum Verrucomicrobia of domain Bacteria, a result with potential major implications for understanding evolution of tubulin-like cytoskeletal proteins and the origin of eukaryote tubulins

The level of Marzano higher-order thinking skills among polytechnic students

This study aims to identify polytechnic students' level of Marzano Higher-Order Thinking Skills (HOTS) based on two dimensions, 'Extension and Refinement of Knowledge' and 'Meaningful Use of Knowledge,' and to analyze the difference in the students' level of Marzano HOTS based on these two dimensions depending on the students' demographic factors. This study design was a survey using quantitative methods. A total of 313 students were randomly selected as the survey sample. A questionnaire in the form of closed-ended questions was used as the research instrument. Data were analyzed using frequency percentage and MANOVA test. The findings showed no significant differences in the eight HOTS in the dimension of 'Extension and Refinement of Knowledge' with the gender and socio-economic status (SES) factors. However, there were significant differences in the eight HOTS with the academic achievement factor. Meanwhile, based on the dimension of 'Meaningful Use of Knowledge,' the findings showed no significant differences in the five HOTS in this dimension with the gender and academic achievement factors. The paper includes implications of the Higher-Order Thinking Skills (HOTS) for students to improve their academic performance. In future research, the authors can further identify university students' HOTS levels in the technical area

Monoclinic and Correlated Metal Phase in VO_2 as Evidence of the Mott Transition: Coherent Phonon Analysis

In femtosecond pump-probe measurements, the appearance of coherent phonon oscillations at 4.5 THz and 6.0 THz indicating the rutile metal phase of VO_2 does not occur simultaneously with the first-order metal-insulator transition (MIT) near 68^oC. The monoclinic and correlated metal(MCM) phase between the MIT and the structural phase transition (SPT) is generated by a photo-assisted hole excitation which is evidence of the Mott transition. The SPT between the MCM phase and the rutile metal phase occurs due to subsequent Joule heating. The MCM phase can be regarded as an intermediate non-equilibrium state.Comment: 4 pages, 2 figure

Effects of zinc oxide filler on the curing and mechanical response of alkyd coatings

The mechanical properties of an alkyd resin filled with zinc oxide pigment were studied at different concentrations over a wide range of time scales using dynamic mechanical analysis, quartz crystal rheometry and nanoindentation. The motivation for this work stems from the interest in accessing the long-term properties of paint coatings by studying the mechanical properties of historic paints. In this foundational work, we compare three different modalities of mechanical measurements and systematically determine the effect of pigment filler loading on the measured properties. Quantitative agreement between the methods is obtained when the characteristic time scales of each of the methods is taken into account. While nanoindentation is the technique most readily applied to historic paint samples, the rheometric quartz crystal microbalance (rheo-QCM) is the best suited for obtaining mechanistic information from measurements of paint properties over time, provided that appropriate thin-film samples can be produced. In these studies we find that ZnO increases the rate of oxidation of the alkyd during the initial stages of cure by an amount that depends on the ZnO content