1 research outputs found
Encapsulation of Hemin in Metal–Organic Frameworks for Catalyzing the Chemiluminescence Reaction of the H<sub>2</sub>O<sub>2</sub>–Luminol System and Detecting Glucose in the Neutral Condition
Novel
metal–organic frameworks (MOFs) based solid catalysts have
been synthesized by encapsulating Hemin into the HKUST-1 MOF materials.
These have been first applied in the chemiluminescence field with
outstanding performance. The functionalized MOFs not only maintain
an excellent catalytic activity inheriting from Hemin but also can
be cyclically utilized as solid mimic peroxidases in the neutral condition.
The synthesized Hemin@HKUST-1 composites have been used to develop
practical sensors for H<sub>2</sub>O<sub>2</sub> and glucose with
wide response ranges and low detection limits. It was envisioned that
catalyst-functionalized MOFs for chemiluminescence sensing would have
promising applications in green, selective, and sensitive detection
of target analytes in the future