The role of triplet excitons in enhancing polymer solar cell efficiency: a photo-induced absorption study

Inclusion of heavy metal atoms in a polymer backbone allows transitions between the singlet and triplet manifolds. Interfacial dissociation of triplet excitons constitutes a viable mechanism for enhancing photovoltaic (PV) efficiencies in polymer heterojunction-based solar cells. The PV efficiency from polymer solar cells utilizing a ladder-type poly (para-phenylene) polymer (PhLPPP) with trace quantity of Pd atoms and a fullerene derivative (PCBM) is much higher than its counterpart (MeLPPP) with no Pd atom. Evidence is presented for the formation of a weak ground-state charge-transfer complex (CTC) in the blended films of the polymer and PCBM, using photo-induced absorption (PIA) spectroscopy. The CTC state in MeLPPP:PCBM has a singlet character to it, resulting in a radiative recombination. In contrast, the CTC states in PhLPPP:PCBM are more localized with a triplet character. An absorption peak at 1.65 eV is observed in PhLPPP:PCBM blend in the PIA, which may be converted to weakly-bound polaron-pairs, contributing to the enhancement of PV efficiency.Comment: 19 pages, 11 figure

Spatial Distribution of Metal Emissions in SNR 3C 397 Viewed with Chandra and XMM

We present X-ray equivalent width imaging of the supernova remnant (SNR) 3C 397 for Mg He\alpha, Si He\alpha, S He\alpha, and Fe K\alpha complex lines with the Chandra and XMM-Newton observations. The images reveal that the heavier the element is, the smaller the extent of the element distribution is. The Mg emission is evidently enhanced in the southeastern blow-out region, well along the radio boundary there, and appears to partially envelope the eastern Fe knot. Two bilateral hat-like Si line-emitting structures are along the northern and southern borders, roughly symmetric with respect to the southeast-northwest elongation axis. An S line-emitting shell is located just inner to the northern radio and IR shell, indicating of a layer of reversely shocked sulphur in the ejecta. A few enhanced Fe features are basically aligned along the diagonal of the rectangular shape of the SNR, which implicates an early asymmetric SN explosion.Comment: 4 pages, 4 figures, appears in Science China Physics, Mechanics & Astronomy, 2010, 53 (Suppl.1), 267-27

Quantum Phase Transition, O(3) Universality Class and Phase Diagram of Spin-1/2 Heisenberg Antiferromagnet on Distorted Honeycomb Lattice: A Tensor Renormalization Group Study

The spin-1/2 Heisenberg antiferromagnet on the distorted honeycomb (DHC) lattice is studied by means of the tensor renormalization group method. It is unveiled that the system has a quantum phase transition of second-order between the gapped quantum dimer phase and a collinear Neel phase at the critical point of coupling ratio \alpha_{c} = 0.54, where the quantum critical exponents \nu = 0.69(2) and \gamma = 1.363(8) are obtained. The quantum criticality is found to fall into the O(3) universality class. A ground-state phase diagram in the field-coupling ratio plane is proposed, where the phases such as the dimer, semi-classical Neel, and polarized phases are identified. A link between the present spin system to the boson Hubbard model on the DHC lattice is also discussed.Comment: 6 pages, 5 figures, published in Phys. Rev.

Higher Twist, ξw\xi_w Scaling, and Effective LOPDFsLO PDFs for Lepton Scattering in the Few GeV Region

We use a new scaling variable $\xi_w$, and add low $Q^2$ modifications to GRV98 leading order parton distribution functions such that they can be used to model electron, muon and neutrino inelastic scattering cross sections (and also photoproduction) at both very low and high energies.Comment: 6 pages, 3 figures. To be published in J. Phys. G (Conf. Proceedings) based on two talks by Arie Bodek at the NuFact$'02$ conference, Imperial College, London, England, July 200

s-Process Xe and Kr and Ne-E in a ^(13)C Rich Murchison Sample; Noble Gas Analysis by Stepped Combustion

Some of the more interesting isotopic anomalies in meteorites are located in minor phases that are extremely resistant to chemical treatments. Among these are Ne-E (Black and Pepin, 1969; Eberhardt, 1978; Alaerts et al., 1980) and s-process Kr and Xe (Srinivasan and Anders, 1978; Alaerts et al., 1980), which have been detected in samples that at the same time contain a carbon component enriched in ^(13)C by about a factor of two (Swart et al., 1983). Swart et al. (1983) have concluded that s-Xe and Ne-E (L)- that subcomponent of Ne-E that is released at low temperature in pyrolysis (Eberhardt, 1978)- are related to isotopically heavy carbon. Their argument involved a comparison of stability in pyrolysis (for noble gas retention) and combustion (carbon). Since it is preferrable to compare stability under identical conditions, we have analyzed for its noble gases by stepped combustion Murchison sample CFP. This sample had been prepared using HF/HC1 and HC10_4 and analyzed for carbon by Yang and Epstein (1984), who found a δ^(13)C of + 977‰ in the highest temperature step. We followed their schedule except for an intermediate combustion step at 1000°C

An exact equilibrium reduced density matrix formulation I: The influence of noise, disorder, and temperature on localization in excitonic systems

An exact method to compute the entire equilibrium reduced density matrix for systems characterized by a system-bath Hamiltonian is presented. The approach is based upon a stochastic unraveling of the influence functional that appears in the imaginary time path integral formalism of quantum statistical mechanics. This method is then applied to study the effects of thermal noise, static disorder, and temperature on the coherence length in excitonic systems. As representative examples of biased and unbiased systems, attention is focused on the well-characterized light harvesting complexes of FMO and LH2, respectively. Due to the bias, FMO is completely localized in the site basis at low temperatures, whereas LH2 is completely delocalized. In the latter, the presence of static disorder leads to a plateau in the coherence length at low temperature that becomes increasingly pronounced with increasing strength of the disorder. The introduction of noise, however, precludes this effect. In biased systems, it is shown that the environment may increase the coherence length, but only decrease that of unbiased systems. Finally it is emphasized that for typical values of the environmental parameters in light harvesting systems, the system and bath are entangled at equilibrium in the single excitation manifold. That is, the density matrix cannot be described as a product state as is often assumed, even at room temperature. The reduced density matrix of LH2 is shown to be in precise agreement with the steady state limit of previous exact quantum dynamics calculations.Comment: 37 pages, 12 figures. To appear in Phys. Rev.

Kinetic stabilization of Fe film on (4 by 2)-GaAs(100)

We grow Fe film on (4 by 2)-GaAs(100) at low temperature, (~ 130 K) and study their chemical structure by photoelectron spectroscopy using synchrotron radiation. We observe the effective suppression of As segregation and remarkable reduction of alloy formation near the interface between Fe and substrate. Hence, this should be a way to grow virtually pristine Fe film on GaAs(100). Further, the Fe film is found stable against As segregation even after warmed up to room temperature. There only forms very thin, ~ 8 angstrom thick interface alloy. It is speculated that the interface alloy forms via surface diffusion mediated by interface defects formed during the low temperature growth of the Fe film. Further out-diffusion of both Ga and As are suppressed because it should then proceed via inefficient bulk diffusion.Comment: 4 figure

Narrow Band Chandra X-ray Analysis of Supernova Remnant 3C391

We present the narrow-band and the equivalent width (EW) images of the thermal composite supernova remnant (SNR) 3C391 for the X-ray emission lines of elements Mg, Si, & S using the Chandra ACIS Observational data. These EW images reveal the spatial distribution of the emission of the metal species Mg, Si, & S in the remnant. They have clumpy structure similar to that seen from the broadband diffuse emission, suggesting that they are largely of interstellar origin. We find an interesting finger-like feature protruding outside the southwestern radio border of the remnant, which is somewhat similar to the jet-like Si structure found in the famous SNR Cas A. This feature may possibly be the debris of the jet of ejecta which implies an asymmetrical supernova explosion of a massive progenitor star.Comment: 9 pages, 4 embedded figures, Chinese Journal of Astronomy and Astrophysics (ChJAA), in pres