Interplay between Defects and Short-Range Disorder Manipulating the Oxygen Evolution Reaction on a Layered Double Hydroxide Electrocatalyst

Improving the efficiency of the oxygen evolution reaction (OER) is crucial for advancing sustainable and environmentally friendly hydrogen energy. Layered double hydroxides (LDHs) have emerged as promising electrocatalysts for the OER. However, a thorough understanding of the impact of structural disorder and defects on the catalytic activity of LDHs remains limited. In this work, a series of NiAl-LDH models are systematically constructed, and their OER performance is rigorously screened through theoretical density functional theory. The acquired results unequivocally reveal that the energy increase induced by structural disorder is effectively counteracted at the defect surface, indicating the coexistence of defects and disorder. Notably, it is ascertained that the simultaneous presence of defects and disorder synergistically augments the catalytic activity of LDHs in the context of the OER. These theoretical findings offer valuable insights into the design of highly efficient OER catalysts while also shedding light on the efficacy of LDH electrocatalysts

Ⅰ-Ⅱ MIXED-MODE FRACTURE PROPERTY OF 2D-C/SIC COMPOSITES (MT)

In order to characterize the Ⅰ-Ⅱ mixed-mode fracture performance of 2D-C/SiC composites, Arcan butterfly specimens with unilateral cracks were used, and the mode-Ⅰ and mode-Ⅱ fracture shape factors of the specimen were calibrated through finite element model. The Arcan disc device was used to carry out mode-Ⅰ, mode-Ⅱ and Ⅰ-Ⅱ mixed-mode fracture tests upon 2D-C/SiC butterfly specimens, and the macroscopic and microscopic fracture modes and strength properties of the specimens under different loading paths were investigated. The results show that the fracture toughness of mode-II of 2D-C/SiC material is higher than that of mode-I. With increasing of the loading angle, the influence of shear stress on the crack propagation path increases, and meanwhile the fracture resistance of the specimens presents a tendency to increase. The applicability of several fracture criteria is demonstrated, and an Ⅰ-Ⅱ mixed-mode fracture criterion for 2D-C/SiC composites is suggested

Dynamic Response and Failure Characteristics of Slope with Weak Interlayer under Action of Near-Fault Ground Motion

Investigations into the Wenchuan earthquake (2008, China) demonstrated that landslides were concentrated in the near-fault areas, and numerous large-scale landslides occurred in slopes with weak interlayers. A mathematical model was established based on the shear beam theory, while a numerical model was developed based on the discrete element method which perfectly matched layer boundary theory. Through a theoretical analysis and numerical simulation, the dynamic response and failure modes of the slope with a weak interlayer under the near-fault ground motion were studied. It was found that a combined effect took place between the near-fault ground motion and the weak interlayer, causing the slope near a fault to be destroyed more easily. The coupling between the near-fault ground motion and the weak interlayer leads to a maximum amplification effect of the slope. The existence of a weak interlayer induces nonconforming vibration between the upper and the lower rock masses of the interlayer. The variation in the amplification effect along the slope elevation is related to the ratio of the input seismic period to the natural slope period. Under horizontal ground motion, weak interlayers will be subjected to impacting and shearing action. The failure mode of the slope with a weak interlayer under near-fault ground motion can be expressed as a trailing edge tension crack, as well as weak interlayer impacting and shearing failure

Completed plastome sequence of Sophora moorcroftiana, an endemic shrub to the Qinghai-Tibet Plateau, China

Sophora moorcroftiana, an endemic Fabaceae species occurred in the Qinghai-Tibet plateau, China, has important economic value in local. Its completed plastome sequence is 148,930 bp in size, and comprises a pair of inverted repeat (IR) regions of 23,787 bp each, a large single-copy region of 83,342 bp and a small single-copy region of 18,014 bp. The GC content of the plastome was 30.2%. A total of 124 genes were identified, comprising 80 protein-coding genes, 36 tRNA genes and eight rRNA genes. There are 94 unique genes, with 15 genes duplicated in the IR regions. Phylogenetic tree shows that plastome of S. moorcroftiana is most related to that of S. alopecuroides. This plastome would be helpful for the study of molecular mechanism of photosynthesis, sustainable conservation, genetic improvement of S. moorcroftiana

Genetic Diversity Analysis and Potential Distribution Prediction of Sophora moorcroftiana Endemic to Qinghai–Tibet Plateau, China

Sophora moorcroftiana (Benth.) Baker is an endemic woody species distributed in the Qinghai–Tibet Plateau (QTP), a part of the world characterized by high altitude and cold weather. In this study, the genetic diversity of S. moorcroftiana was evaluated based on 300 representative samples of 15 populations using 20 polymorphic SSR markers, and its potential distribution was predicted according to 19 bioclimatic factors using MaxEnt modeling. Results showed the population genetic diversity of S. moorcroftiana was generally not high (around 0.5), and the range of variation was small (0.437–0.539). Altitude, rather than other environmental factors, was the key factor affecting the present genetic diversity. Moreover, due to climate change in the QTP, the suitable area is increasing and will continue to increase by 48.35%, 84.44%, 101.98%, and 107.30% in the four future periods of 2030s, 2050s, 2070s, and 2090s, respectively, compared to the present, which is beneficial for S. moorcroftiana. These results will provide a theoretical basis for the development of germplasm conservation strategies for S. moorcroftiana and enrich information on the impacts of climate change on plants in the QTP

The Role of EjSVPs in Flower Initiation in Eriobotrya japonica

Flowering plants have evolved different flowering habits to sustain long-term reproduction. Most woody trees experience dormancy and then bloom in the warm spring, but loquat blooms in the cold autumn and winter. To explore its mechanism of flowering regulation, we cloned two SHORT VEGETATIVE PHASE (SVP) homologous genes from ‘Jiefanzhong’ loquat (Eriobotrya japonica Lindl.), namely, EjSVP1 and EjSVP2. Sequence analysis revealed that the EjSVPs were typical MADS-box transcription factors and exhibited a close genetic relationship with other plant SVP/DORMANCY-ASSOCIATED MADS-BOX (DAM) proteins. The temporal and spatial expression patterns showed that EjSVP1 and EjSVP2 were mainly expressed in the shoot apical meristem (SAM) after the initiation of flowering; after reaching their highest level, they gradually decreased with the development of the flower until they could not be detected. EjSVP1 expression levels were relatively high in young tissues, and EjSVP2 expression levels were relatively high in young to mature transformed tissues. Interestingly, EjSVP2 showed relatively high expression levels in various flower tissues. We analyzed the EjSVP promoter regions and found that they did not contain the C-repeat/dehydration-responsive element. Finally, we overexpressed the EjSVPs in wild-type Arabidopsis thaliana Col-0 and found no significant changes in the number of rosette leaves of Arabidopsis thaliana; however, overexpression of EjSVP2 affected the formation of Arabidopsis thaliana flower organs. In conclusion, EjSVPs were found to play an active role in the development of loquat flowering. These findings may provide a reference for exploring the regulation mechanisms of loquat flowering and the dormancy mechanisms of other plants

Formation and Elimination of Satellite Droplets during Monodisperse Droplet Generation by Using Piezoelectric Method

One of the key questions in the generation of monodisperse droplets is how to eliminate satellite droplets. This paper investigates the formation and elimination of satellite droplets during the generation of monodisperse deionized water droplets based on a piezoelectric method. We estimated the effects of two crucial parameters—the pulse frequency for driving the piezoelectric transducer (PZT) tube and the volume flow rate of the pumping liquid—on the generation of monodisperse droplets of the expected size. It was found that by adjusting the pulse frequency to harmonize with the volume flow rate, the satellite droplets can be eliminated through their coalescence with the subsequent mother droplets. An increase in the tuning pulse frequency led to a decrease in the size of the monodisperse droplets generated. Among three optimum conditions (OCs) (OC1: 20 mL/h, 20 kHz; OC2: 30 mL/h, 30 kHz; and OC3: 40 mL/h, 40 kHz), the sizes of the generated monodisperse deionized water droplets followed a bimodal distribution in OC1 and OC2, whereas they followed a Gaussian distribution in OC3. The average diameters were 87.8 μm (OC1), 85.9 μm (OC2), and 84.8 μm (OC3), which were 8.46%, 6.14%, and 4.69% greater than the theoretical one (81.0 μm), respectively. This monodisperse droplet generation technology is a promising step in the production of monodisperse aerosols for engineering applications