970 research outputs found
Extremely strong-coupling superconductivity and anomalous lattice properties in the beta-pyrochlore oxide KOs2O6
Superconducting and normal-state properties of the beta-pyrochlore oxide
KOs2O6 are studied by means of thermodynamic and transport measurements. It is
shown that the superconductivity is of conventional s-wave type and lies in the
extremely strong-coupling regime. Specific heat and resistivity measurements
reveal that there are characteristic low-energy phonons that give rise to
unusual scattering of carriers due to strong electron-phonon interactions. The
entity of the low-energy phonons is ascribed to the heavy rattling of the K ion
confined in an oversized cage made of OsO6 octahedra. It is suggested that this
electron-rattler coupling mediates the Cooper pairing, resulting in the
extremely strong-coupling superconductivity.Comment: 17 pages (only 4 pages included here. go to
http://hiroi.issp.u-tokyo.ac.jp/Published%20papers/K-SC6.pdf for full pages),
to be published in PR
Synthesis of SmFeAsO by an Easy and Versatile Route and its Physical Property Characterization
We report synthesis, structure, electrical transport and heat capacity of
SmFeAsO. The title compound is synthesized by one-step encapsulation of
stoichiometric FeAs, Sm, and Sm2O3 in an evacuated (10-5 Torr) quartz tube by
prolong (72 hours) annealing at 1100oC. The as synthesized compound is
crystallized in tetragonal structure with P4/nmm space group having lattice
parameters a = 3.93726(33) A and c = 8.49802(07) A. The resistance (R-T)
measurements on the compound exhibited ground state spin-density-wave
(SDW)-like metallic steps below 140 K. Heat capacity CP(T) measurements on the
title compound, showed an anomaly at around 140 K, which is reminiscent of the
SDW ordering of the compound. At lower temperatures the CP(T) shows a clear
peak at around 4.5 K. At lower temperature below 20 K, Cp(T) is also measured
under an applied field of 7 Tesla. It is concluded that the CP(T) peak at 4.5 K
is due to the anti-ferromagnetic(AFM) ordering of Sm3+ spins. These results are
in confirmation with ordering of Sm in Sm2-xCexCuO4.Comment: 9 pages Text + Figs Contact Author ([email protected]
Investigation of the ferromagnetic transition in the correlated 4d perovskites SrRuRhO
The solid-solution SrRuRhO () is a
variable-electron-configuration system forming in the nearly-cubic-perovskite
basis, ranging from the ferromagnetic 4 to the enhanced paramagnetic
4. Polycrystalline single-phase samples were obtained over the whole
composition range by a high-pressure-heating technique, followed by
measurements of magnetic susceptibility, magnetization, specific heat,
thermopower, and electrical resistivity. The ferromagnetic order in long range
is gradually suppressed by the Rh substitution and vanishes at .
The electronic term of specific-heat shows unusual behavior near the critical
Rh concentration; the feature does not match even qualitatively with what was
reported for the related perovskites (Sr,Ca)RuO. Furthermore, another
anomaly in the specific heat was observed at .Comment: Accepted for publication in PR
Crystal growth, structural studies and superconducting properties of beta-pyrochlore KOs2O6
Single crystals of KOs2O6 have been grown in a sealed quartz ampoule.
Detailed single crystal X-ray diffraction studies at room temperature show
Bragg peaks that violate Fd-3m symmetry. With a comparative structure
refinement the structure is identified as non-centrosymmetric (F-43m). Compared
to the ideal beta-pyrochlore lattice (Fd-3m), both Os tetrahedral and O
octahedral network exhibit breathing mode like volume changes accompanied by
strong anisotropic character of the K channels. The crystals show metallic
conductivity and a sharp transition to the superconducting state at Tc = 9.65
K. Superconducting properties have been investigated by magnetization
measurements performed in a temperature range from 2 to 12 K and in magnetic
fields from 0 to 60 kOe. The temperature dependence of the upper critical field
Hc2(T) has been determined and the initial slope (dHc2/dT)Tc = -33.3 kOe/K has
been obtained near Tc. The upper critical field at zero temperature was
estimated to be Hc2(0) \cong 230 kOe, which is a value close to the Pauli
paramagnetic limiting field Hp(0)\cong 250 kOe. Then, the Ginzburg-Landau (GL)
coherence length xi GL(0) \approx 3.8 nm was calculated, and the Maki parameter
alpha \approx \sqrt 2 was obtained, suggesting the possibility that KOs2O6
might behave unconventionally at low temperatures and high magnetic fields
NaV2O4: a Quasi-1D Metallic Antiferromagnet with Half-Metallic Chains
NaV2O4 crystals were grown under high pressure using a NaCl flux, and the
crystals were characterized with X-ray diffraction, electrical resistivity,
heat capacity, and magnetization. The structure of NaV2O4 consists of double
chains of edge-sharing VO6 octahedra. The resistivity is highly anisotropic,
with the resistivity perpendicular to the chains more than 20 times greater
than that parallel to the chains. Magnetically, the intrachain interactions are
ferromagnetic and the interchain interactions are antiferromagnetic; 3D
antiferromagnetic order is established at 140 K. First principles electronic
structure calculations indicate that the chains are half metallic.
Interestingly, the case of NaV2O4 seems to be a quasi-1D analogue of what was
found for half-metallic materials.Comment: 14 pages, including 4 figures and 1 table, accepted for publication
in PR
Upper critical field and de Haas-van Alphen oscillations in KOsO measured in a hybrid magnet
Magnetic torque measurements have been performed on a KOsO single
crystal in magnetic fields up to 35.3 T and at temperatures down to 0.6 K. The
upper critical field is determined to be 30 T. De Haas-van Alphen
oscillations are observed. A large mass enhancement of (1+) = = 7.6 is found. It is suggested that, for the large upper critical
field to be reconciled with Pauli paramagnetic limiting, the observed mass
enhancement must be of electron-phonon origin for the most part.Comment: 4 pages, 4 figures, published versio
Local spin and charge properties of beta-Ag0.33V2O5 studied by 51V NMR
Local spin and charge properties were studied on beta-Ag0.33V2O5, a
pressure-induced superconductor, at ambient pressure using 51V-NMR and
zero-field-resonance (ZFR) techniques. Three inequivalent Vi sites (i=1, 2, and
3) were identified from 51V-NMR spectra and the principal axes of the
electric-field-gradient (EFG) tensor were determined in a metallic phase and
the following charge-ordering phase. We found from the EFG analysis that the V1
sites are in a similar local environment to the V3 sites. This was also
observed in ZFR spectra as pairs of signals closely located with each other.
These results are well explained by a charge-sharing model where a 3d1 electron
is shared within a rung in both V1-V3 and V2-V2 two-leg ladders.Comment: 12pages, 16figure
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