Direct Visualisation of the Depth-Dependent Mechanical Properties of Full-Thickness Articular Cartilage.

The structural anisotropy of articular cartilage controls its deformation response. As proteoglycans and collagen vary with depth, simple uniaxial compression results in inhomogeneous deformation with distinct depth-dependent mechanical properties. Investigations into depth-dependent mechanical properties of articular cartilage have previously required tissue modification after specimen isolation. Such modifications include histological processes, freezing, subchondral bone removal, and fluorescent staining that may alter the tissue, limiting in vivo applicability

Analytic Spectra of CMB Anisotropies and Polarization Generated by Relic Gravitational Waves with Modification due to Neutrino Free-Streaming

We present an analytical calculation of the spectra of CMB anisotropies and polarizations generated by relic gravitational waves (RGWs). As a substantial extension to the previous studies, three new ingredients are included in this work. Firstly, the analytic $C_l^{TT}$ and $C_l^{TE}$ are given; especially the latter can be useful to extract signal of RGWs from the observed data in the zero multipole method. Secondly, a fitting formula of the decaying factor on small scales is given, coming from the visibility function around the photon decoupling. Thirdly, the impacts by the neutrino free-streaming (NFS) is examined, a process that occurred in the early universe and leaves observable imprints on CMB via RGWs. It is found that the analytic $C_l^{TT}$ and $C_l^{TE}$ have profiles agreeing with the numeric ones, except that $C^{TT}_l$ in a range $l \le 10$ and the $1^{st}$ trough of $C_l^{TE}$ around $l \sim 75$ have some deviations. With the new damping factor, the analytic $C^{EE}_l$ and $C^{BB}_l$ match with the numeric ones with the maximum errors only $\sim 3$ up to the first three peaks for $l\le 600$, improving the previous studies substantially. The correspondence of the positions of peaks of $C^{XX}_l$ and those of RGWs are also demonstrated explicitly. We also find that NFS reduces the amplitudes of $C^{XX}_l$ by $(20$ for $l\simeq(100\sim 600)$ and shifts slightly their peaks to smaller angles. Detailed analyses show that the zero multipoles $l_0$, where $C_l^{TE}$ crosses 0, are shifted to larger values by NFS. This shifting effect is as important as those causedby different inflation models and different baryon fractions.Comment: 17 pages, 7 figures. accepted by PR

The Physical Connections Among IR QSOs, PG QSOs and Narrow-Line Seyfert 1 Galaxies

We study the properties of infrared-selected QSOs (IR QSOs), optically-selected QSOs (PG QSOs) and Narrow Line Seyfert 1 galaxies (NLS1s). We compare their properties from the infrared to the optical and examine various correlations among the black hole mass, accretion rate, star formation rate and optical and infrared luminosities. We find that the infrared excess in IR QSOs is mostly in the far infrared, and their infrared spectral indices suggest that the excess emission is from low temperature dust heated by starbursts rather than AGNs. The infrared excess is therefore a useful criterion to separate the relative contributions of starbursts and AGNs. We further find a tight correlation between the star formation rate and the accretion rate of central AGNs for IR QSOs. The ratio of the star formation rate and the accretion rate is about several hundred for IR QSOs, but decreases with the central black hole mass. This shows that the tight correlation between the stellar mass and the central black hole mass is preserved in massive starbursts during violent mergers. We suggest that the higher Eddington ratios of NLS1s and IR QSOs imply that they are in the early stage of evolution toward classical Seyfert 1's and QSOs, respectively.Comment: 32 pages, 6 figures, accepted by Ap

Metal-organic-frameworks derived cobalt embedded in various carbon structures as bifunctional electrocatalysts for oxygen reduction and evolution reactions

This is the final version of the article. Available from Springer Nature via the DOI in this record.A series of nanocomposites of cobalt embedded in N-doped nanoporous carbons, carbon nanotubes or hollow carbon onions have been synthesized by a one-step carbonization of metal-organic-framework ZIF-67. The effect of the carbonization temperature on the structural evolution of the resulting nanocomposites has been investigated in detail. Among the as-synthesized materials, the cobalt/nanoporous N-doped carbon composites have demonstrated excellent electrocatalytic activities and durability towards oxygen reduction reaction in alkaline medium. Compared to the benchmark Pt/C catalyst, the optimized Co@C-800 (carbonized at 800 °C) exhibited high oxygen reduction reaction activity with an onset potential of 0.92 V, and a half-wave potential of 0.82 V. Moreover, the optimized Co@C-800 also showed enhanced electrocatalytic activity towards oxygen evolution reaction from water splitting, with a low onset potential of 1.43 V and a potential of 1.61 V at 10 mA cm−2 current density. This work offered a simple solution to develop metal-organic-framework-derived materials for highly efficient electrochemical applications.The financial support by the EPSRC (EP/N034627/1), Royal Society and University of Exeter is greatly acknowledged

Droplet size and velocity characteristics of water-air impinging jet atomizer

A water-air impinging jets atomizer is investigated in this study, which consists of flow visualization using high speed photography and mean droplet size and velocity distribution measurements of the spray using Phase Doppler Anemometry (PDA). Topological structures and break up details of the generated spray in the far and near fields are presented with and without air jet and for an impinging angle of 90°. Spray angle increases with the water jet velocity, air flow rate and impinging angle. PDA results indicate that droplet size is smallest in the spray center, with minimum value of Sauter mean diameter (SMD) of 50 µm at the air flow rate of Qm = 13.50 g/min. SMD of droplets increases towards the spray outer region gradually to about 120 µm. The mean droplet velocity component W along the air-jet axis is highest in the spray center and decreases gradually with increasing distance from the spray center. SMD normalized by the air nozzle diameter is found firstly to decrease with gas-to-liquid mass ratio (GLR) and air-to-liquid momentum ratio (ALMR) and then remain almost constant. Its increasing with aerodynamic Weber number indicates an exponential variation. The study sheds light on the performance of water-air impinging jets atomizers providing useful information for future CFD simulation works