Microscopic Model for Photoinduced Magnetism in the Molecular Complex [Mo(IV)(CN)2(CN−CuL)6]8+[Mo(IV)(CN)_2(CN-CuL)_6]^{8+} Perchlorate

A theoretical model for understanding photomagnetism in the heptanuclear complex $[Mo(IV)(CN)_2(CN-CuL)_6]^{8+}$ perchlorate is developed. It is a many-body model involving the active orbitals on the transition metal ions. The model is exactly solved using a valence bond approach. The ground state solution of the model is highly degenerate and is spanned by five S=0 states, nine S=1 states, five S=2 states and one S=3 state. The orbital occupancies in all these states correspond to six $Cu(II)$ ions and one diamagnetic $Mo(IV)$ ion. The optically excited charge-transfer (CT) state in each spin sector occur at nearly the same excitation energy of 2.993 eV for the physically reasonable parameter values. The degeneracy of the CT states is largest in the S=3 sector and so is the transition dipole moment from the ground state to these excited states. Thus laser irradiation with light of this energy results in most intense absorption in the S=3 sector. The life-time of the S=3 excited states is also expected to be the largest as the number of states below that energy is very sparse in this spin sector when compared to other spin sectors. These twin features of our model explain the observed photomagnetism in the $[Mo(IV)(CN)_2(CN-CuL)_6]^{8+}$ complex.Comment: 8 pages, 6 figures and 1 tabl

Weak coupling d-wave BCS superconductivity and unpaired electrons in overdoped La_{2-x}Sr_{x}CuO_{4} single crystals

The low-temperature specific heat (SH) of overdoped La_{2-x}Sr_{x}CuO_{4} single crystals (0.178=<x=<0.290) has been measured. For the superconducting samples (0.178=<x=<0.238), the derived gap values (without any adjusting parameters) approach closely onto the theoretical prediction \Delta_{0}=2.14k_{B}T_{c} for the weak-coupling d-wave BCS superconductivity. In addition, the residual term \gamma(0) of SH at H=0 increases with x dramatically when beyond x~0.22, and finally evolves into the value of a complete normal metallic state at higher doping levels, indicating growing amount of unpaired electrons. We argue that this large \gamma(0) cannot be simply attributed to the pair breaking induced by the impurity scattering, instead the phase separation is possible.Comment: 6 pages, 6 figures; Contents added; Accepted for publication in Phys. Rev.

Flavor Mixing in the Gauge-Higgs Unification

Gauge-Higgs unification is the fascinating scenario solving the hierarchy problem without supersymmetry. In this scenario, the Standard Model (SM) Higgs doublet is identified with extra component of the gauge field in higher dimensions and its mass becomes finite and stable under quantum corrections due to the higher dimensional gauge symmetry. On the other hand, Yukawa coupling is provided by the gauge coupling, which seems to mean that the flavor mixing and CP violation do not arise at it stands. In this talk, we discuss that the flavor mixing is originated from simultaneously non-diagonalizable bulk and brane mass matrices. Then, this mechanism is applied to various flavor changing neutral current (FCNC) processes via Kaluza-Klein (KK) gauge boson exchange at tree level and constraints for compactification scale are obtained.Comment: 5 pages, prepared for the proceedings of the International Workshop on Grand Unified Theories (GUT2012) held at Yukawa Institute for Theoretical Physics, March 15-17 2012, Kyoto, Japa

Evolution from Non-Fermi to Fermi Liquid Transport Properties by Isovalent Doping in BaFe2(As1-xPx)2 Superconductors

The normal-state charge transport is studied systematically in high-quality single crystals of BaFe$_2$(As$_{1-x}$P$_x$)$_2$ ($0 \leq x \leq 0.71$). By substituting isovalent P for As, the spin-density-wave (SDW) state is suppressed and the dome-shaped superconducting phase ($T_c \lesssim 31$ K) appears. Near the SDW end point ($x\approx0.3$), we observe striking linear temperature ($T$) dependence of resistivity in a wide $T$-range, and remarkable low-$T$ enhancement of Hall coefficient magnitude from the carrier number estimates. We also find that the magnetoresistance apparently violates the Kohler's rule and is well scaled by the Hall angle $\Theta_H$ as $\Delta\rho_{xx}/\rho_{xx} \propto \tan^2\Theta_H$. These non-Fermi liquid transport anomalies cannot be attributed to the simple multiband effects. These results capture universal features of correlated electron systems in the presence of strong antiferromagnetic fluctuations.Comment: 4 pages, 4 figure

Cu-spin dynamics in the overdoped regime of La_2-x_Sr_x_Cu_1-y_Zn_y_O_4_ probed by muon spin relaxation

Muon-spin-relaxation measurements have been performed for the partially Zn-substituted La_2-x_Sr_x_Cu_1-y_Zn_y_O_4_ with y=0-0.10 in the overdoped regime up to x=0.30. In the 3 % Zn-substituted samples up to x=0.27, exponential-like depolarization of muon spins has been observed at low temperatures, indicating Zn-induced slowing-down of the Cu-spin fluctuations. The depolarization rate decreases with increasing x and almost no fast depolarization of muon spins has been observed for x=0.30 where superconductivity disappears. The present results suggest that the dynamical stripe correlations exist in the whole superconducting regime of La_2-x_Sr_x_CuO_4_ and that there is no quantum critical point at x~0.19.Comment: 6 pages, 5 figure

Distinct Fe-induced magnetic states in the underdoped and overdoped regimes of La2-xSrxCu1-yFeyO4 revealed by muon spin relaxation

Zero-field and longitudinal-field muon-spin-relaxation measurements have been performed in partially Fe-substituted La2-xSrxCu1-yFeyO4 in a wide range of hole concentration, to investigate the magnetic state induced by the Fe substitution recently suggested from the neutron-scattering measurements [Phys. Rev. Lett. 107, 127002 (2011)]. It has been found that the magnetic transition temperature is notably enhanced through the 1% Fe substitution in a wide range of hole concentration where superconductivity appears in Fe-free La2-xSrxCuO4. In the underdoped regime, the Fe-induced magnetic order can be understood in terms of the concept of stripe pinning by Fe as in the case of the Zn-induced one in La2-xSrxCu1-yZnyO4. In the overdoped regime, on the other hand, the Fe-induced magnetic order is short-ranged, which is distinct from the stripes. It is plausible that a spin-glass state of Fe spins derived from the Ruderman-Kittel-Kasuya-Yosida interaction is realized in the overdoped regime, suggesting a change of the ground state from the strongly correlated state to the Fermi-liquid state with hole doping in La-214 high-Tc cuprates.Comment: 10 pages, 6 figures, accepted for publication in Phys. Rev.

Hole-trapping by Ni, Kondo effect and electronic phase diagram in non-superconducting Ni-substituted La2-xSrxCu1-yNiyO4

In order to investigate the electronic state in the normal state of high-Tc cuprates in a wide range of temperature and hole-concentration, specific-heat, electrical-resistivity, magnetization and muon-spin-relaxation (muSR) measurements have been performed in non-superconducting Ni-substituted La2-xSrxCu1-yNiyO4 where the superconductivity is suppressed through the partial substitution of Ni for Cu without disturbing the Cu-spin correlation in the CuO2 plane so much. In the underdoped regime, it has been found that there exist both weakly localized holes around Ni and itinerant holes at high temperatures. With decreasing temperature, all holes tend to be localized, followed by the occurrence of variable-range hopping conduction at low temperatures. Finally, in the ground state, it has been found that each Ni2+ ion traps a hole strongly and that a magnetically ordered state appears. In the overdoped regime, on the other hand, it has been found that a Kondo-like state is formed around each Ni2+ spin at low temperatures. In conclusion, the ground state of non-superconducting La2-xSrxCu1-yNiyO4 changes upon hole doping from a magnetically ordered state with the strong hole-trapping by Ni2+ to a metallic state with Kondo-like behavior due to Ni2+ spins, and the quantum phase transition is crossover-like due to the phase separation into short-range magnetically ordered and metallic regions.Comment: 9 pages, 8 figures, accepted for publication in Phys. Rev.