5,284 research outputs found

    Electron-Phonon Interactions in C28_{28}-derived Molecular Solids

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    We present {\it ab initio} density-functional calculations of molecular solids formed from C28_{28}-derived closed-shell fullerenes. Solid C28_{28}H4_4 is found to bind weakly and exhibits many of the electronic structure features of solid C60_{60} with an enhanced electron-phonon interaction potential. We show that chemical doping of this structure is feasible, albeit more restrictive than its C60_{60} counterpart, with an estimated superconducting transition temperature exceeding those of the alkali-doped C60_{60} solids.Comment: Lower quality postscript file for Figure 1 is used in the manuscript in order to meet submission quota for pre-print server. Higher quality postscript file available from author: [email protected] This article has been updated to reflect changes incorporated during the peer review process. It is published in PRB 70, 140504(R) 200

    Analysis of architectural geometries affecting stress distributions of gothic flying buttresses

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    Master of ScienceDepartment of Architectural Engineering and Construction ScienceKimberly KramerThe flying buttress is one of the most prominent characteristics of Gothic architecture. Understanding stress distribution from the upper vaulted nave (high vault) to the flying buttress system would contribute greatly to preservation efforts of such iconic structures. Many investigations have emphasized structural analysis of Gothic flying buttresses, but only limited research how architectural design affects load distribution throughout the Gothic members exist. The objective of this investigation was to inspire engineers and architectural preservationists to develop further research in Gothic structural analysis and restoration by increasing understanding how architectural design of flying buttresses affects the load path being transmitted from the main superstructure to the lateral force resisting system. Several flying buttress designs under similar analytical parameters were compared in order to understand how member geometries affect stress distribution. Because Gothic design is architecturally complex, finite element analysis method was used to obtain member stress distribution (regions of compressive and tensile stresses). Architectural elevation schematics of the flying buttresses of prominent Gothic cathedrals were referenced when modeling the structural members to a computer software program (RAM Elements)

    Selfduality for coupled Potts models on the triangular lattice

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    We present selfdual manifolds for coupled Potts models on the triangular lattice. We exploit two different techniques: duality followed by decimation, and mapping to a related loop model. The latter technique is found to be superior, and it allows to include three-spin couplings. Starting from three coupled models, such couplings are necessary for generating selfdual solutions. A numerical study of the case of two coupled models leads to the identification of novel critical points

    Severity of disease and mortality for hospitalized patients with community-acquired viral pneumonia compared to patients with community-acquired bacterial pneumonia

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    Background: There exists a large body of literature to help identify, diagnose, treat, and manage community-acquired pneumonia (CAP). Despite this, there is little data that directly compares the clinical syndromes and complications of pure bacterial pneumonia to pure viral pneumonia. Our study compares the clinical presentation, morbidity and mortality of viral vs. bacterial etiologies of CAP. Methods: This was a secondary data analysis of the Community-Acquired Pneumonia Organization (CAPO) international study database. Data was collected concerning patient demographics, physical examination findings, laboratory findings, radiological findings, severity of illness, and clinical outcomes and stratified according to the two study groups, CAVP and CABP. A microbiological diagnosis of CABP was based on the isolation of a bacterium from a respiratory sample, blood culture and/or identification of a urinary antigen for Streptococcus or Legionella; microbiological diagnosis of CAVP was based on polymerase chain reaction or antigen detection from respiratory samples. Results: Our study included 1,913 patients. Of these, 286 (15.0%) had viral infection, while 1,627 (85.0%) had CAVP. We found that bacterial CAP patients are older, more frequently male, and suffer from a higher proportion of comorbidities when compared to viral CAP patients. Comparison of physical exam findings and laboratory values failed to find a clinically significant difference between bacterial and viral CAP patients. When comparing severity of illness, bacterial CAP patients had greater frequency of PSI ≥ class IV; however, viral CAP patients more frequently needed ICU admission, ventilator support, vasopressor support, and had higher rate of in hospital mortality. Conclusions: Our study confirms the extreme difficulty differentiating CABP from CAVP using demographics, physical exam, or x-ray findings. We found no major clinical or laboratory findings distinguishing CABP from CAVP. The increased severity of illness of CAVP compared to bacterial etiologies shows that PSI scores may not be an accurate indicator of severity of disease. More studies are needed to identify the best process of care for patients with CAP, including the potential benefits of routine respiratory viral panel testing and empiric antiviral therapy

    Comparison of Surface Area across the Allograft-Host Junction Site Using Conventional and Navigated Osteotomy Technique.

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    Bulk allograft reconstruction plays an important role in limb-salvage surgery; however, non-union has been reported in up to 27% of cases. The purpose of this study is to quantify average surface contact areas across simulated intraoperative osteotomies using both free-hand and computer-assisted navigation techniques. Pressure-sensitive paper was positioned between two cut ends of a validated composite sawbone and compression was applied using an eight-hole large fragment dynamic compression plate. Thirty-two samples were analyzed for surface area contact to determine osteotomy congruity. Mean contact area using the free-hand osteotomy technique was equal to 0.21 square inches. Compared with a control of 0.69 square inches, average contact area was found to be 30.5% of optimal surface contact. Mean contact area using computer-assisted navigation was equal to 0.33 square inches. Compared with a control of 0.76 square inches, average contact area was found to be 43.7% of optimal surface contact. Limited contact achieved using standard techniques may play a role in the high rate of observed non-union, and an increase in contact area using computer-assisted navigation may improve rates of bone healing. The development of an oncology software package and navigation hardware may serve an important role in decreasing non-union rates in limb salvage surgery
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