Infrared study of spin crossover Fe-picolylamine complex

Infrared (IR) absorption spectroscopy has been used to probe the evolution of microscopic vibrational states upon the temperature- and photo-induced spin crossovers in [Fe(2-picolylamine)3]Cl2EtOH (Fe-pic). To overcome the small sizes and the strong IR absorption of the crystal samples used, an IR synchrotron radiation source and an IR microscope have been used. The obtained IR spectra of Fe-pic show large changes between high-spin and low-spin states for both the temperature- and the photo- induced spin crossovers. Although the spectra in the temperature- and photo-induced high-spin states are relatively similar to each other, they show distinct differences below 750 cm-1. This demonstrates that the photo-induced high-spin state involves microscopically different characters from those of the temperature-induced high-spin state. The results are discussed in terms of local pressure and structural deformations within the picolylamine ligands, and in terms of their possible relevance to the development of macroscopic photo-induced phase in Fe-pic.Comment: 6 pages (text) and 6 figures,submitted to J. Phys. Soc. Jp

Langevin simulation of the full QCD hadron mass spectrum on a lattice

Langevin simulation of quantum chromodynamics (QCD) on a lattice is carried out fully taking into account the effect of the quark vacuum polarization. It is shown that the Langevin method works well for full QCD and that simulation on a large lattice is practically feasible. A careful study is made of systematic errors arising from a finite Langevin time-step size. The magnitude of the error is found to be significant for light quarks, but the well-controlled extrapolation allows a separation of the values at the vanishing time-step size. As another important ingredient for the feasibility of Langevin simulation the advantage of the matrix inversion algorithm of the preconditioned conjugate residual method is described, as compared with various other algorithms. The results of a hadron-mass-spectrum calculation on a 93×18 lattice at β=5.5 with the Wilson quark action having two flavors are presented. It is shown that the contribution of vacuum quark loops significantly modifies the hadron masses in lattice units, but that the dominant part can be absorbed into a shift of the gauge coupling constant at least for the ground-state hadrons. Some suggestion is also presented for the physical effect of vacuum quark loops for excited hadrons

Hadron Mass Predictions of the Valence Approximation to Lattice QCD

We evaluate the infinite volume, continuum limits of eight hadron mass ratios predicted by lattice QCD with Wilson quarks in the valence (quenched) approximation. Each predicted ratio differs from the corresponding observed value by less than 6\%.Comment: 13 pages of Latex + 2 PostScript files attached, IBM/HET 92-

SET based experiments for HTSC materials: II

The cuprates seem to exhibit statistics, dimensionality and phase transitions in novel ways. The nature of excitations [i.e. quasiparticle or collective], spin-charge separation, stripes [static and dynamics], inhomogeneities, psuedogap, effect of impurity dopings [e.g. Zn, Ni] and any other phenomenon in these materials must be consistently understood. In this note we further discuss our original suggestion of using Single Electron Tunneling Transistor [SET] based experiments to understand the role of charge dynamics in these systems. Assuming that SET operates as an efficient charge detection system we can expect to understand the underlying physics of charge transport and charge fluctuations in these materials for a range of doping. Experiments such as these can be classed in a general sense as mesoscopic and nano characterization of cuprates and related materials. In principle such experiments can show if electron is fractionalized in cuprates as indicated by ARPES data. In contrast to flux trapping experiments SET based experiments are more direct in providing evidence about spin-charge separation. In addition a detailed picture of nano charge dynamics in cuprates may be obtained.Comment: 10 pages revtex plus four figures; ICMAT 2001 Conference Symposium P: P10-0

Lattice QCD Calculation of Hadron Scattering Lengths

Method of calculating hadron multi-point functions and disconnected quark loop contributions which are not readily accessible through conventional techniques is proposed. Results are reported for pion-pion, pion-nucleon and nucleon-nucleon scattering lengths and the flavor singlet-non singlet meson mass splitting estimated in quenched QCD.Comment: 6 pages. Contribution to Lattice '93. Latex file, style file espcrc2.sty needed.(appended at the end) Figures are also included as epsf file

Finite Temperature Transitions in Lattice QCD with Wilson Quarks --- Chiral Transitions and the Influence of the Strange Quark ---

The nature of finite temperature transitions in lattice QCD with Wilson quarks is studied near the chiral limit for the cases of 2, 3, and 6 flavors of degenerate quarks ($N_F=2$, 3, and 6) and also for the case of massless up and down quarks and a light strange quark ($N_F=2+1$). Our simulations mainly performed on lattices with the temporal direction extension $N_t=4$ indicate that the finite temperature transition in the chiral limit (chiral transition) is continuous for $N_F=2$, while it is of first order for $N_F=3$ and 6. We find that the transition is of first order for the case of massless up and down quarks and the physical strange quark where we obtain a value of $m_\phi/m_\rho$ consistent with the physical value. We also discuss the phase structure at zero temperature as well as that at finite temperatures.Comment: uuencoded compressed tar file, 70 pages, 32 figure

High real-space resolution measurement of the local structure of Ga_1-xIn_xAs using x-ray diffraction

High real-space resolution atomic pair distribution functions (PDF)s from the alloy series Ga_1-xIn_xAs have been obtained using high-energy x-ray diffraction. The first peak in the PDF is resolved as a doublet due to the presence of two nearest neighbor bond lengths, Ga-As and In-As, as previously observed using XAFS. The widths of nearest, and higher, neighbor pairs are analyzed by separating the strain broadening from the thermal motion. The strain broadening is five times larger for distant atomic neighbors as compared to nearest neighbors. The results are in agreement with model calculations.Comment: 4 pages, 5 figure