1,187 research outputs found
Mapping the magneto-structural quantum phases of Mn3O4
We present temperature-dependent x-ray diffraction and temperature- and
field-dependent Raman scattering studies of single crystal Mn3O4, which reveal
the novel magnetostructural phases that evolve in the spinels due to the
interplay between strong spin-orbital coupling, geometric frustration, and
applied magnetic field. We observe a structural transition from tetragonal to
monoclinic structures at the commensurate magnetic transition at T2=33K, show
that the onset and nature of this structural transition can be controlled with
an applied magnetic field, and find evidence for a field-tuned quantum phase
transition to a tetragonal incommensurate or spin glass phase.Comment: 5 pages, 3 figures, submitted to Phys. Rev. Lett; typos correcte
Molecular structure, vibrational spectral investigation and the confirmation analysis of 4-Methylesculetin molecule
WOS: 000333614200003In this work, FT-IR, FT-Raman, and FT-NMR spectra of 4-Methylesculetin molecule are presented for the first time. FT-IR, FT-Raman, and FT-NMR spectra of 4MEC have been recorded and analyzed. The FT-IR and FT-Raman spectra of this molecule are recorded at 4000-400 cm(-1) and 50-3500 cm(-1), respectively. The infrared vibrational frequencies, absolute intensities, potential energy profile, HOMO-LUMO plot and NBO analysis of the molecule have been also predicted using Becke's three-parameter hybrid B3LYP method in the density functional theory DFT method. Calculated and experimental data are in good agreement.Ahi Evran University Research FundAhi Evran University [FEN.4003.12.013]Y. Erdogdu would like to thank Ahi Evran University Research Fund for its financial support. Project Numbers: FEN.4003.12.013. Computing resources used in this work were provided by the National Center for High Performance Computing of Turkey (UYBHM)
Towards precision medicine for hypertension: a review of genomic, epigenomic, and microbiomic effects on blood pressure in experimental rat models and humans
Compelling evidence for the inherited nature of essential hypertension has led to extensive research in rats and humans. Rats have served as the primary model for research on the genetics of hypertension resulting in identification of genomic regions that are causally associated with hypertension. In more recent times, genome-wide studies in humans have also begun to improve our understanding of the inheritance of polygenic forms of hypertension. Based on the chronological progression of research into the genetics of hypertension as the "structural backbone," this review catalogs and discusses the rat and human genetic elements mapped and implicated in blood pressure regulation. Furthermore, the knowledge gained from these genetic studies that provide evidence to suggest that much of the genetic influence on hypertension residing within noncoding elements of our DNA and operating through pervasive epistasis or gene-gene interactions is highlighted. Lastly, perspectives on current thinking that the more complex "triad" of the genome, epigenome, and the microbiome operating to influence the inheritance of hypertension, is documented. Overall, the collective knowledge gained from rats and humans is disappointing in the sense that major hypertension-causing genes as targets for clinical management of essential hypertension may not be a clinical reality. On the other hand, the realization that the polygenic nature of hypertension prevents any single locus from being a relevant clinical target for all humans directs future studies on the genetics of hypertension towards an individualized genomic approach
The effective fine structure constant of freestanding graphene measured in graphite
Electrons in graphene behave like Dirac fermions, permitting phenomena from
high energy physics to be studied in a solid state setting. A key question is
whether or not these Fermions are critically influenced by Coulomb
correlations. We performed inelastic x-ray scattering experiments on crystals
of graphite, and applied reconstruction algorithms to image the dynamical
screening of charge in a freestanding, graphene sheet. We found that the
polarizability of the Dirac fermions is amplified by excitonic effects,
improving screening of interactions between quasiparticles. The strength of
interactions is characterized by a scale-dependent, effective fine structure
constant, \alpha *(k,\omega), whose value approaches \alpha * ~ 1/7 at low
energy and large distances. This value is substantially smaller than the
nominal \alpha = 2.2, suggesting that, on the whole, graphene is more weakly
interacting than previously believed.Comment: 28 pages, 10 figures, 2 animation
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