2,523 research outputs found
Efficient Hole Trapping in Carbon Dot/Oxygen-Modified Carbon Nitride Heterojunction Photocatalysts for Enhanced Methanol Production from COâ‚‚ under Neutral Conditions
Artificial photosynthesis of alcohols from CO 2 is a promising route to provide sustainable fuels. The performance is still unsatisfactory mainly due to the rapid charge relaxation compared to the sluggish photoreactions and the oxidation of alcohol products. Here, we demonstrate that CO 2 is reduced to methanol with 100% selectivity using water as the only electron donor on a carbon nitride-like polymer (FAT) decorated with carbon dots. The quantum efficiency of 5.9% (λ = 420 nm) is 300% higher than the previously reported carbon nitride junction. Using transient absorption spectroscopy, we observed that holes in FAT can be extracted by the carbon dots with nearly 75% efficiency before they become unreactive by trapping. Extraction of holes resulted in a greater density of photoelectrons, indicative of reduced recombination of shorter-lived reactive electrons. This work offers a unique strategy to promote photocatalysis by increasing the amount of reactive photogenerated charges via structure engineering and extraction before energy losses by deep trapping
Distributed Formal Concept Analysis Algorithms Based on an Iterative MapReduce Framework
While many existing formal concept analysis algorithms are efficient, they
are typically unsuitable for distributed implementation. Taking the MapReduce
(MR) framework as our inspiration we introduce a distributed approach for
performing formal concept mining. Our method has its novelty in that we use a
light-weight MapReduce runtime called Twister which is better suited to
iterative algorithms than recent distributed approaches. First, we describe the
theoretical foundations underpinning our distributed formal concept analysis
approach. Second, we provide a representative exemplar of how a classic
centralized algorithm can be implemented in a distributed fashion using our
methodology: we modify Ganter's classic algorithm by introducing a family of
MR* algorithms, namely MRGanter and MRGanter+ where the prefix denotes the
algorithm's lineage. To evaluate the factors that impact distributed algorithm
performance, we compare our MR* algorithms with the state-of-the-art.
Experiments conducted on real datasets demonstrate that MRGanter+ is efficient,
scalable and an appealing algorithm for distributed problems.Comment: 17 pages, ICFCA 201, Formal Concept Analysis 201
Algorithmic decidability of Engel's property for automaton groups
We consider decidability problems associated with Engel's identity
( for a long enough commutator sequence) in groups
generated by an automaton. We give a partial algorithm that decides, given
, whether an Engel identity is satisfied. It succeeds, importantly, in
proving that Grigorchuk's -group is not Engel. We consider next the problem
of recognizing Engel elements, namely elements such that the map
attracts to . Although this problem seems intractable in
general, we prove that it is decidable for Grigorchuk's group: Engel elements
are precisely those of order at most . Our computations were implemented
using the package FR within the computer algebra system GAP
Radiopaque Nanoparticle and Dipyridamole-loaded Electrospun Polymeric Scaffold as Bioresorbable Drug-Eluting Vascular Graft
https://openworks.mdanderson.org/sumexp22/1080/thumbnail.jp
Lyapunov exponent of the random Schr\"{o}dinger operator with short-range correlated noise potential
We study the influence of disorder on propagation of waves in one-dimensional
structures. Transmission properties of the process governed by the
Schr\"{o}dinger equation with the white noise potential can be expressed
through the Lyapunov exponent which we determine explicitly as a
function of the noise intensity \sigma and the frequency \omega. We find
uniform two-parameter asymptotic expressions for which allow us to
evaluate for different relations between \sigma and \omega. The value
of the Lyapunov exponent is also obtained in the case of a short-range
correlated noise, which is shown to be less than its white noise counterpart.Comment: 20 pages, 4 figure
Ozone, aerosols and polar stratospheric clouds measurements during the EASOE Campaign
Preliminary results are presented of observations obtained during the EASOE campaign, with an airborne backscatter lidar and a ground-based DIAL ozone lidar system. Although the main signature observed on the lidar signals was due to the Pinatubo cloud which erupted in June 1991, distinct PSC events were detected on several occasions by the airborne lidar often in relation with orographic wave activity over the norvegian mountains. The ozone profiles obtained in Sodankyla with the ground based lidar are locally perturbed by the presence of the volcanic cloud. After a first correction of the aerosols effect, they present however a reasonably good agreement with the ozone sondes profiles performed on the same site
Extended states in 1D lattices: application to quasiperiodic copper-mean chain
The question of the conditions under which 1D systems support extended
electronic eigenstates is addressed in a very general context. Using real space
renormalisation group arguments we discuss the precise criteria for determining
the entire spertrum of extended eigenstates and the corresponding
eigenfunctions in disordered as well as quasiperiodic systems. For purposes of
illustration we calculate a few selected eigenvalues and the corresponding
extended eigenfunctions for the quasiperiodic copper-mean chain. So far, for
the infinite copper-mean chain, only a single energy has been numerically shown
to support an extended eigenstate [ You et al. (1991)] : we show analytically
that there is in fact an infinite number of extended eigenstates in this
lattice which form fragmented minibands.Comment: 10 pages + 2 figures available on request; LaTeX version 2.0
Ptch2/Gas1 and Ptch1/Boc differentially regulate Hedgehog signalling in murine primordial germ cell migration.
Gas1 and Boc/Cdon act as co-receptors in the vertebrate Hedgehog signalling pathway, but the nature of their interaction with the primary Ptch1/2 receptors remains unclear. Here we demonstrate, using primordial germ cell migration in mouse as a developmental model, that specific hetero-complexes of Ptch2/Gas1 and Ptch1/Boc mediate the process of Smo de-repression with different kinetics, through distinct modes of Hedgehog ligand reception. Moreover, Ptch2-mediated Hedgehog signalling induces the phosphorylation of Creb and Src proteins in parallel to Gli induction, identifying a previously unknown Ptch2-specific signal pathway. We propose that although Ptch1 and Ptch2 functionally overlap in the sequestration of Smo, the spatiotemporal expression of Boc and Gas1 may determine the outcome of Hedgehog signalling through compartmentalisation and modulation of Smo-downstream signalling. Our study identifies the existence of a divergent Hedgehog signal pathway mediated by Ptch2 and provides a mechanism for differential interpretation of Hedgehog signalling in the germ cell niche
Hotspots of Large Rare Deletions in the Human Genome
Background: We have examined the genomic distribution of large rare autosomal deletions in a sample of 440 parentparent-child trios from the Quebec founder population (QFP) which was recruited for a study of Attention Deficit Hyperactivity Disorder. Methodology/Principal Findings: DNA isolated from blood was genotyped on Illumina Hap300 arrays. PennCNV combined with visual evaluation of images generated by the Beadstudio program was used to determine deletion boundary definition of sufficient precision to discern independent events, with near-perfect concordance between parent and child in about 98 % of the 399 events detected in the offspring; the remaining 7 deletions were considered de novo. We defined several genomic regions of very high deletion frequency (‘hotspots’), usually of 0.4–0.6 Mb in length where independent rare deletions were found at frequencies of up to 100 fold higher than the average for the genome as a whole. Five of the 7 de novo deletions were in these hotspots. The same hotspots were also observed in three other studies on members of the QFP, those with schizophrenia, with endometriosis and those from a longevity cohort. Conclusions/Significance: Nine of the 13 hotspots carry one gene (7 of which are very long), while the rest contain no known genes. All nine genes have been implicated in disease. The patterns of exon deletions support the proposed roles for some of these genes in human disease, such as NRXN1 and PARKIN, and suggest limited roles or no role at all, for others
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