Low-Temperature Solution-Processed Electron Transport Layers for Inverted Polymer Solar Cells

© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, WeinheimProcessing temperature is highlighted as a convenient means of controlling the optical and charge transport properties of solution processed electron transport layers (ETLs) in inverted polymer solar cells. Using the well-studied active layer – poly(3-hexylthiophene-2,5-diyl):indene-C60 bisadduct – the influence of ETL processing temperatures from 25 to 450 °C is shown, reporting the role of crystallinity, structure, charge transport, and Fermi level (EF) on numerous device performance characteristics. It has been determined that an exceptionally low temperature processed ETL (110 °C) increases device power conversion efficiency by a factor greater than 50% compared with a high temperature (450 °C) processed ETL. Modulations in device series and shunt resistance, induced by changes in the ETL transport properties, are observed in parallel to significant changes in device open circuit voltage attributed to changes on the EF of the ETLs. This work highlights the importance of interlayer control in multilayer photovoltaic devices and presents a convenient material compatible with future flexible and roll-to-roll processes

Energy quantization in solution-processed layers of indium oxide and their application in resonant tunneling diodes

\u3cp\u3eThe formation of quantized energy states in ultrathin layers of indium oxide (In\u3csub\u3e2\u3c/sub\u3eO\u3csub\u3e3\u3c/sub\u3e) grown via spin coating and thermally annealed at 200°C in air is studied. Optical absorption measurements reveal a characteristic widening of the optical band gap with reducing In\u3csub\u3e2\u3c/sub\u3eO\u3csub\u3e3\u3c/sub\u3e layer thickness from ≈43 to ≈3 nm in agreement with theoretical predictions for an infinite quantum well. Through sequential deposition of In\u3csub\u3e2\u3c/sub\u3eO\u3csub\u3e3\u3c/sub\u3e and gallium oxide (Ga\u3csub\u3e2\u3c/sub\u3eO\u3csub\u3e3\u3c/sub\u3e) layers, superlattice-like structures with controlled dimensionality and spatially varying conduction band characteristics are demonstrated. This simple method is then explored for the fabrication of functional double-barrier resonant tunneling diodes. Nanoscale current mapping analysis using conductive atomic force microscopy reveals that resonant tunneling is not uniform but localized in specific regions of the apparent device area. The latter observation is attributed to variation in the layer(s) thickness of the In\u3csub\u3e2\u3c/sub\u3eO\u3csub\u3e3\u3c/sub\u3e quantum well and/or the Ga\u3csub\u3e2\u3c/sub\u3eO\u3csub\u3e3\u3c/sub\u3e barrier layers. Despite the nonidealities, the tremendous potential of solution-processable oxide semiconductors for the development of quantum effect devices that have so far been demonstrated only via sophisticated growth techniques is demonstrated.\u3c/p\u3

Cosmology and Static Spherically Symmetric solutions in D-dimensional Scalar Tensor Theories: Some Novel Features

We consider scalar tensor theories in D-dimensional spacetime, D \ge 4. They consist of metric and a non minimally coupled scalar field, with its non minimal coupling characterised by a function. The probes couple minimally to the metric only. We obtain vacuum solutions - both cosmological and static spherically symmetric ones - and study their properties. We find that, as seen by the probes, there is no singularity in the cosmological solutions for a class of functions which obey certain constraints. It turns out that for the same class of functions, there are static spherically symmetric solutions which exhibit novel properties: {\em e.g.} near the ``horizon'', the gravitational force as seen by the probe becomes repulsive.Comment: Revtex. 21 pages. Version 2: More references added. Version 3: Issues raised by the referee are addressed. Results unchanged. Title modified; a new subsection and more references added. Verison to appear in Physical Review

The static potential in QED3_3 with non-minimal coupling

Here we study the effect of the non-minimal coupling j^{\mu}\eps \partial^{\nu} A^{\alpha} on the static potential in multiflavor QED$_3$. Both cases of four and two components fermions are studied separately at leading order in the $1/N$ expansion. Although a non-local Chern-Simons term appears, in the four components case the photon is still massless leading to a confining logarithmic potential similar to the classical one. In the two components case, as expected, the parity breaking fermion mass term generates a traditional Chern-Simons term which makes the photon massive and we have a screening potential which vanishes at large inter-charge distance. The extra non-minimal couplings have no important influence on the static potential at large inter-charge distances. However, interesting effects show up at finite distances. In particular, for strong enough non-minimal coupling we may have a new massive pole in the photon propagator while in the opposite limit there may be no poles at all in the irreducible case. We also found that, in general, the non-minimal couplings lead to a finite range {\bf repulsive} force between charges of opposite signs.Comment: 19 pages and 7 figure

Heterogeneity of monosomy 3 in fine needle aspiration biopsy of choroidal melanoma.

PurposeTo report on the heterogeneity of monosomy 3 in a fine needle aspiration biopsy obtained transsclerally from choroidal melanoma for prognosis.MethodsAll clinical records for patients who had been diagnosed with choroidal melanoma and underwent iodine-125 plaque brachytherapy with intraoperative transscleral fine needle aspiration biopsy from January 2005 to August 20, 2011, and who had a positive result for monosomy 3 according to fluorescence in situ hybridization as reported by clinical cytogenetics testing were collected. Patient age and sex, total number of cells evaluated and number of cells positive for monosomy 3, tumor size, and metastatic outcome were recorded for each patient.ResultsA positive result for monosomy 3 was reported in 93 patients who underwent transscleral fine needle aspiration biopsy. Two patients were lost to follow-up immediately post-operatively, and the remaining 91 patients were included in this study. The mean number of cells evaluated in the biopsy was 273 (range 28 to 520). The mean percentage of cells positive for monosomy 3 was 62.9% (range 4.7%-100%). The mean tumor height was 5.91 mm (range 1.99 to 10.85 mm). Larger tumors were associated with a higher percentage of cells positive for monosomy 3. During the average follow-up interval of 28.9 months (range 3-76 months), choroidal melanoma metastasis developed in 18 (20%) patients. Patients whose tumors had 1%-33% of cells positive for monosomy 3 had a significantly lower risk of metastasis-related death compared to patients whose tumors harbored a higher percentage of monosomy 3 (p = 0.04).ConclusionsCytogenetic heterogeneity of fluorescent in situ hybridization for monosomy 3 exists in a biopsy sample. Larger tumors were more likely to have a higher percentage of monosomy 3 positive cells in the sample. Furthermore, patients whose tumors had more than 33% of cells positive for monosomy 3 had a poorer prognosis than patients whose tumors had lower percentages of monosomy 3

HyRec: A fast and highly accurate primordial hydrogen and helium recombination code

We present a state-of-the-art primordial recombination code, HyRec, including all the physical effects that have been shown to significantly affect recombination. The computation of helium recombination includes simple analytic treatments of hydrogen continuum opacity in the He I 2 1P - 1 1S line, the He I] 2 3P - 1 1S line, and treats feedback between these lines within the on-the-spot approximation. Hydrogen recombination is computed using the effective multilevel atom method, virtually accounting for an infinite number of excited states. We account for two-photon transitions from 2s and higher levels as well as frequency diffusion in Lyman-alpha with a full radiative transfer calculation. We present a new method to evolve the radiation field simultaneously with the level populations and the free electron fraction. These computations are sped up by taking advantage of the particular sparseness pattern of the equations describing the radiative transfer. The computation time for a full recombination history is ~2 seconds. This makes our code well suited for inclusion in Monte Carlo Markov chains for cosmological parameter estimation from upcoming high-precision cosmic microwave background anisotropy measurements.Comment: Version accepted by PRD. Numerical integration switches adapted to be well behaved for a wide range of cosmologies (Sec. V E). HyRec is available at http://www.tapir.caltech.edu/~yacine/hyrec/hyrec.htm

Duality and Non-linear Response for Quantum Hall Systems

We derive the implications of particle-vortex duality for the electromagnetic response of Quantum Hall systems beyond the linear-response regime. This provides a first theoretical explanation of the remarkable duality which has been observed in the nonlinear regime for the electromagnetic response of Quantum Hall systems.Comment: 7 pages, 1 figure, typeset in LaTe

Effective Actions, Boundaries and Precision Calculations of Casimir Energies

We perform the matching required to compute the leading effective boundary contribution to the QED lagrangian in the presence of a conducting surface, once the electron is integrated out. Our result resolves a confusion in the literature concerning the interpretation of the leading such correction to the Casimir energy. It also provides a useful theoretical laboratory for brane-world calculations in which kinetic terms are generated on the brane, since a lot is known about QED near boundaries.Comment: 5 pages. revtex; Added paragraphs describing finite-conductivity effects and effects due to curvatur

A model of head direction and landmark coding in complex environments

Environmental information is required to stabilize estimates of head direction (HD) based on angular path integration. However, it is unclear how this happens in real-world (visually complex) environments. We present a computational model of how visual feedback can stabilize HD information in environments that contain multiple cues of varying stability and directional specificity. We show how combinations of feature-specific visual inputs can generate a stable unimodal landmark bearing signal, even in the presence of multiple cues and ambiguous directional specificity. This signal is associated with the retrosplenial HD signal (inherited from thalamic HD cells) and conveys feedback to the subcortical HD circuitry. The model predicts neurons with a unimodal encoding of the egocentric orientation of the array of landmarks, rather than any one particular landmark. The relationship between these abstract landmark bearing neurons and head direction cells is reminiscent of the relationship between place cells and grid cells. Their unimodal encoding is formed from visual inputs via a modified version of Oja's Subspace Algorithm. The rule allows the landmark bearing signal to disconnect from directionally unstable or ephemeral cues, incorporate newly added stable cues, support orientation across many different environments (high memory capacity), and is consistent with recent empirical findings on bidirectional HD firing reported in the retrosplenial cortex. Our account of visual feedback for HD stabilization provides a novel perspective on neural mechanisms of spatial navigation within richer sensory environments, and makes experimentally testable predictions