1 research outputs found
Carbon-Induced Generation of Hierarchical Structured Ni<sub>0.75</sub>Co<sub>0.25</sub>(CO<sub>3</sub>)<sub>0.125</sub>(OH)<sub>2</sub> for Enhanced Supercapacitor Performance
Hierarchical
nanostructures with heteroatom doping have been considered as an important
component in electrode materials for advanced supercapacitors. Herein, with
the aid of C, N, and S codoped Ni<sub>0.75</sub>Co<sub>0.25</sub>(CO<sub>3</sub>)<sub>0.125</sub>(OH)<sub>2</sub>/C (NSH) with a hierarchical
structure was synthesized through a facile one-step hydrothermal method.
Notably, it is the first report on a carbon precursor as a structure
inducer for designing a three-dimensional (3D) carnation-like hierarchical
structure. Thanks to the carbon induction effect and the introduction
of N/S dopants, the obtained NSH with a 3D architecture exhibits superior
performances as electrode materials for supercapacitors. For example,
NSH offers a high specific capacity of 277.3 mAh/g at 0.5 A/g. Moreover,
the assembled NSH//reduced graphene oxide hydrogel-based hybrid supercapacitor
exhibits high energy densities of 44.4 and 11.7 Wh/kg at power densities
of 460 W/kg and 9.8 kW/kg, respectively. This result opens up opportunities
for carbon-induced methods to control the morphology and structure
of other similar materials