843 research outputs found
Benzyl 2-ethylhexyl sulfoxide
The molecule of the title compound, C15H24OS, shows S conformations for the S atom and the asymmetric C atom of the isooctyl group. The long axes of the molecules are directed along the c axis. In the crystal structure, the molecules are linked by weak intermolecular bifurcated C—H⋯O hydrogen bonds
1-Butyl-3-(1-naphthylmethyl)benzimidazolium hemi{di-μ-iodido-bis[diiodidomercurate(II)]} dimethyl sulfoxide monosolvate
In the title compound, (C22H23N2)[Hg2I6]0.5·(CH3)2SO, the 1-butyl-3-(1-naphthylmethyl)benzimidazolium anion lies across a centre of inversion. The dihedral angle between the benzimidazolium and naphthalene ring systems is 81.9 (3)°. In the crystal structure, π–π stacking interactions are observed between the imidazolium ring and the unsubstituted benzene ring of the naphthalene ring system, with a centroid–centroid separation of 3.510 (5) Å. In the centrosymmetric anion, the Hg(II) atoms are in a distorted tetrahedral coordination. The dimethyl sulfoxide solvent molecule is disordered over two sites with occupancies of 0.615 (9) and 0.385 (9)
Magnetotransport properties of Cd3As2 nanostructures
Three-dimensional (3D) topological Dirac semimetal is a new kind of material
that has a linear energy dispersion in 3D momentum space and can be viewed as
an analog of graphene. Extensive efforts have been devoted to the understanding
of bulk materials, but yet it remains a challenge to explore the intriguing
physics in low-dimensional Dirac semimetals. Here, we report on the synthesis
of Cd3As2 nanowires and nanobelts and a systematic investigation of their
magnetotransport properties. Temperature-dependent ambipolar behavior is
evidently demonstrated, suggesting the presence of finite-size of bandgap in
nanowires. Cd3As2 nanobelts, however, exhibit metallic characteristics with a
high carrier mobility exceeding 32,000 cm2V-1s-1 and pronounced anomalous
double-period Shubnikov-de Haas (SdH) oscillations. Unlike the bulk
counterpart, the Cd3As2 nanobelts reveal the possibility of unusual change of
the Fermi sphere owing to the suppression of the dimensionality. More
importantly, their SdH oscillations can be effectively tuned by the gate
voltage. The successful synthesis of Cd3As2 nanostructures and their rich
physics open up exciting nanoelectronic applications of 3D Dirac semimetals.Comment: 18 pages, 5 figure
Poly[dichloridobis[μ-1-(4-pyridylmethyl)-1H-1,2,4-triazole]copper(II)]
The title coordination polymer, [CuCl2(C8H8N4)2]n, arose from a layer-separated diffusion synthesis at room temperature. The Cu atom (site symmetry ) is coordinated by two chloride ions and four N atoms (two from triazole rings and two from pyridyl rings) in a distorted trans-CuCl2N4 octahedral arrangement. The bridging 1-(4-pyridylmethyl)-1H-1,2,4-triazole ligands [dihedral angle between the triazole and pyridine rings = 68.08 (8)°] result in a two-dimensional 44 sheet structure in the crystal
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